Nonlinear Absorption and Low-threshold Two-photon Pumped Amplified Stimulated Emission from FAPbBr_(3) Nanocrystals

Formamidinium lead bromide(FAPbBr_(3))nanocrystals(NCs)have been considered to be a good optoelectronic material due to their pure green emission,excellent stability and superior carrier transport characteristics.However,two-photon pumped amplified spontaneous emission(ASE)and the corresponding nonlinear optical properties of FAPbBr_(3) NCs are scarcely revealed.Herein,we synthesized colloidal FAPbBr_(3) NCs with different sizes by changing the molar ratio of FABr/PbBr_(2) in the precursor solution,using ligand assisted precipitation(LARP)technology at room temperature.Photoluminescence(PL)and time resolved photoluminescence(TRPL)spectroscopy were measured to characterize their ASE properties.And their nonlinear optical properties were studied through the Zscan technique and the two-photon excited fluorescence method.The stimulated emission properties including oneand two-photon pumped ASE have been realized from FAPbBr_(3) NCs.With large two-photon absorption coefficient(0.27 cm/GW)and high non-linear absorption cross-section(7.52×10^(5) GM),ASE with threshold as low as 9.8μJ/cm^(2) and 487μJ/cm^(2) have been obtained from colloidal FAPbBr_(3) NCs using one-and two-photon excitations.These results indicate that as a new possible green-emitting frequency-upconversion material with low thresholds,FAPbBr_(3) NCs hold great potential in the development of high-performance two-photon pump lasers.

Exploring the impact of economic growth and energy consumption on SO_(2) emissions in China based on the Environmental Kuznets Curve hypothesis

This study aims to analysis the influence of economic growth(EG)and energy consumption(EC)on sulfur dioxide emissions(SE)in China.Accordingly,this study explores the link between EG,EC,and SE for 30 provinces in China over the span of 2000-2019.This study also analyzes cross-sectional dependence tests,panel unit root tests,Westerlund panel cointegration tests,Dumitrescu-Hurlin(D-H)causality tests.According to the test results,there is an inverted U-shaped association between EG and SE,and the assumption of the Environmental Kuznets Curve(EKC)is verified.The signs of EG and EC in the fixed effect(FE)and random effect(RE)methods are in line with those in the dynamic ordinary least squares(DOLS),fully modified ordinary least squares(FMOLS)and autoregressive distributed lag(ARDL)estimators.Moreover,the results verified that EC can obviously positive impact the SE.To reduce SE in China,government and policymakers can improve air quality by developing cleaner energy sources and improving energy efficiency.This requires the comprehensive use of policies,regulations,economic incentives,and public participation to promote sustainable development.

Prospects for green steelmaking technology with low carbon emissions in China

The steel industry is a major source of CO_(2) emissions,and thus,the mitigation of carbon emissions is the most pressing challenge in this sector.In this paper,international environmental governance in the steel industry is reviewed,and the current state of development of low-carbon technologies is discussed.Additionally,low-carbon pathways for the steel industry at the current time are proposed,emphasizing prevention and treatment strategies.Furthermore,the prospects of low-carbon technologies are explored from the perspective of transitioning the energy structure to a“carbon-electricity-hydrogen”relationship.Overall,steel enterprises should adopt hydrogen-rich metallurgical technologies that are compatible with current needs and process flows in the short term,based on the carbon substitution with hydrogen(prevention)and the CCU(CO_(2) capture and utilization)concepts(treatment).Additionally,the capture and utilization of CO_(2) for steelmaking,which can assist in achieving short-term emission reduction targets but is not a long-term solution,is discussed.In conclusion,in the long term,the carbon metallurgical process should be gradually supplanted by a hydrogen-electric synergistic approach,thus transforming the energy structure of existing steelmaking processes and attaining near-zero carbon emission steelmaking technology.

Numerical modeling techniques for noise emission of free railway wheels

In this article,we consider the numerical prediction of the noise emission from a wheelset in laboratory conditions.We focus on the fluid-structure interaction leading to sound emission in the fluid domain by analyzing three different methods to account for acoustic sources.These are a discretized baffled piston using the discrete calculation method(DCM),a closed cylindrical volume using the boundary element method(BEM)and radiating elastic disks in a cubic enclosure solved with the finite element method(FEM).We provide the validation of the baffled piston and the BEM using measurements of the noise emission of a railway wheel by considering ground reflections in the numerical models.Selected space-resolved waveforms are compared with experimental results as well as with a fluid-structure interaction finite element model.The computational advantage of a discretized disk mounted on a baffle and BEM compared to FEM is highlighted,and the baffled pistons limitations caused by a lack of edge radiation effects are investigated.

Shear band evolution and acoustic emission characteristics of sandstone containing non-persistent flaws

Direct shear tests were conducted on sandstone specimens under different constant normal stresses to study the coalescence of cracks between non-persistent flaws and the shear sliding characteristics of the shear-formed fault.Digital image correlation and acoustic emission(AE)techniques were used to monitor the evolution of shear bands at the rock bridge area and microcracking behaviors.The experimental results revealed that the shear stresses corresponding to the peak and sub-peak in the stressdisplacement curve are significantly affected by the normal stress.Strain localization bands emerged at both the tip of joints and the rock bridge,and their extension and interaction near the peak stress caused a surge in the AE hit rate and a significant decrease in the AE b value.Short and curvilinear strain bands were detected at low normal stress,while high normal stress generally led to more microcracking events and longer coplanar cracks at the rock bridge area.Furthermore,an increase in normal stress resulted in a higher AE count rate and more energetic AE events during friction sliding along the shearformed fault.It was observed that the elastic energy released during the crack coalescence at the prepeak stage was much greater than that released during friction sliding at the post-peak stage.More than 75%of AE events were located in the low-frequency band(0e100 kHz),and this proportion continued to rise with increasing normal stress.Moreover,more AE events of low AF value and high RA value were observed in specimens subjected to high normal stress,indicating that greater normal stress led to more microcracks of shear nature.

Synergistic dance of digital economy and green finance on carbon emissions:Insights from China

China has recently implemented a dual-carbon strategy to combat climate change and other environmental issues and is committed to modernizing it sustainably.This paper supports these goals and explores how the digital economy and green finance intersect and impact carbon emissions.Using panel data from 30 Chinese provinces over the period 2011-2021,this paper finds that the digital economy and green finance can together reduce carbon emissions,and conducts several robustness tests supporting this conclusion.A heterogeneity analysis shows that these synergistic effects are more important in regions with low levels of social consumption Meanwhile,in the spatial dimension,the synergistic effect of the local digital economy and green finance adversely impacts the level of carbon emissions in surrounding areas.The findings of this paper provide insights for policymakers in guiding capital flow and implementing carbon-reduction policies while fostering the growth of China’s digital economy and environmental sustainability.

Carbon Monoxide Emission and Concentration Models for Chiang Mai Urban Area

An emission inventory containing emissions from traffic and other sources was complied. Based on the analysis, Carbon Monoxide （CO） emissions from traffic play a very important role in CO levels in Chiang Mai area. Analysis showed that CO emissions from traffic during rush hours contributed approximately 90% of total CO emissions. Regional Atmospheric Modeling System （RAMS） was applied to simulate wind fields and temperatures in the Chiang Mai area, and eight ca^es were selected to study annual variations in wind fields and temperatures. Model results can reflect major features of wind fields and diurnal variations in temperatures. For evaluating the model performance, model results were compared with observed wind speed, wind direction and temperature, which were monitored at a meteorological tower. Comparison showed that model results are in good agreement with observations, and the model captured many of the observed features. HYbrid Particle And Concentration Transport model （HYPACT） was used to simulate CO concentration in the Chiang Mai area. Model results generally agree well with observed CO concentrations at the air quality monitoring stations, and can explain observed CO diurnal variations.

Rim^(18)F-fluorodeoxyglucose uptake of hepatic cavernous hemangioma on positron emission tomography/computed tomography:A case report

BACKGROUND Peripheral FDG accumulation in a hepatic hemangioma presenting in a patient with prolonged fever is rare.Therefore,clinicians should pay close attention to patients with hepatic mass.CASE SUMMARY A 54-year-old woman with a 4-wk history of daily fevers was admitted to our hospital.A whole body^(18)-Fluordesoxyglucose(PET-FDG)positron emission tomography/computed tomography(PET/CT)was performed to elucidate the source of the fever.However,whole body^(18)-FDG PET/CT raised the suspicion of a malignant lesion because of peripheral FDG accumulation(SUVmax 3.5 g/mL)higher than that of the normal liver parenchyma(SUVmax 1.6 g/mL)surrounding a hypoactive area,and no other abnormalities were showed.Subsequently,the patient underwent liver mass resection.Histopathology showed a hepatic cavernous hemangioma with fatty infiltration around the lesion.The fever disappeared four days after surgery and the patient did not present any complications during follow-up.CONCLUSION Fatty infiltration in the peripheral parts of hepatic cavernous hemangioma may lead to subacute inflammation which further activate the Kupffer cells.This may cause prolonged fever and peripheral rim FDG accumulation on PET/CT.

Tuning field emission properties of boron nanocones with catalyst concentration

Single crystalline boron nanocones are prepared by using a simple spin spread method in which Fe3O4 nanoparticles are pre-manipulated on Si（lll） to form catalyst patterns of different densities. The density of boron nanocones can be tuned by changing the concentration of catalyst nanoparticles. High-resolution transmission electron microscopy analysis shows that the boron nanocone has a β-tetragonal structure with good crystallization. The field emission behaviour is optimal when the spacing distance is close to the nanocone length, which indicates that this simple spin spread method has great potential applications in electron emission nanodevices.

Advanced Technologies for Volatile Organic Compound (VOC) Emission Treatment: An Overview

This paper presents a comprehensive overview of various advanced technologies employed in the treatment of volatile organic compounds(VOCs),which are crucial pollutants in industrial emissions.The study explores different methods,including direct combustion,thermal combustion,catalytic combustion,low-temperature plasma purification,photocatalytic purification,membrane separation,and adsorption methods.Each technology is critically analyzed for its operational principles,efficiency,and applicability under different conditions.Special attention is given to adsorption concentration and catalytic combustion parallel method,highlighting its efficiency in treating low-concentration,high-volume VOC emissions.The paper also delves into the advantages and limitations of each method,providing insights into their effectiveness in various industrial scenarios.The study aims to offer a detailed guide for selecting appropriate VOC treatment technologies,contributing to enhanced environmental protection and sustainable industrial practices.

Effect of Light Quality and Intensity on N_2O and NO_X(NO, NO_2)Emissions from Rice Phyllosphere and Roots at Tillering Stage in a Liquid Culture Medium System

[Objective] N2Oand NOX（NO, NO2） are important nitrogen oxides gases（NOGs） in paddy fields, and rice plants play important roles in NOG emissions in paddy fields. However, the source of NOG emissions from rice phyllosphere and roots and their relationship to light quality and intensity still remain unclear. In this study, the relationship between light quality, intensity and N2 O, NOX（NO, NO2） emissions from rice phyllosphere and roots at tillering stage was investigated to clarify the contribution of rice plants to N2Oand NOX（NO, NO2） emissions and analyze the mechanism of light control, aiming at providing a scientific basis for revealing how light-control technology affects NOG emissions from rice at tillering stage in paddy fields. [Method] In this study, nitrogen content was controlled by a hydroponic system. A small electric incubator was used for light control. A simultaneous determination was designed to investigate the effect of different weak light qualities（yellow, green, white, red and blue lights） and intensities（dark, 0 lx; very weak, 2 000lx; weak, 4 000 lx; moderate, 6 000 lx; strong, 8 000 lx） on N2Oand NOXemissions from rice phyllosphere and roots at tillering stage in a liquid culture medium system. N2Oconcentration in air samples was determined by gas chromatography within 12 h, and NOX（NO, NO2） concentration was analyzed using 42 i NO- NO2-NOXgas analyzer. [Result] The results showed that：（1） Under a constant nitrogen condition（NH4NO3-N, 90 mg/L） when rice seedlings were treated with moderate（6 000lx） and strong（8 000 lx） light, the average emission rate of N2Oand NO from rice phyllosphere at tillering stage was 27.08, 32.33 μg/（pot·h） and 0.114, 0.057 μg/（pot·h）,respectively, accounting for 57.38%, 58.65% and 9.65%, 4.52% of the total release of N2Oand NO from the whole rice plant, respectively. It implicated that rice phyllosphere is an important source of N2Oemission at tillering stage in paddy fields.（2）When rice seedlings were treated with yellow, green, white, red and blue LED lights under a constant light intensity（1 600 lx）, the average emission rate of N2Ofrom rice phyllosphere was 6.83, 9.40, 9.73, 2.82 and 4.08 μg/（pot·h）, respectively. Compared with green and yellow LED lights, N2Oemission from rice phyllosphere and roots at tillering stage was inhibited markedly by red（3 000 lx） and blue（2 500 lx）LED lights（P0.01）. In addition, NO emission from rice phyllosphere was enhanced significantly by white and red LED lights, while NO emissions from rice phyllosphere and roots were inhibited by blue light synchronously. Nevertheless, no evident NO2 emission from rice phyllosphere and roots was detected under the same condition.（3） Within the range of 0-8 000 lx, NO and N2Oemissions from rice roots and N2Oemission from rice phyllosphere increased with the enhancement of light intensity. In contrast, NO emission from rice phyllosphere was inhibited remarkably by moderate（6 000 lx） and strong（8 000 lx） light（P〈 0.01）. [Conclusion] Rice seedlings mainly exhibited net emissions of NO2 from the phyllosphere and roots.N2Oand NOX（NO, NO2） emissions from rice phyllosphere and roots at tillering stage could be inhibited by adjusting the composition of visible light（synchronously increasing the proportions of red and blue lights） and appropriately controlling daytime light intensity.

Role of positron emission tomography-computed tomography in non-small cell lung cancer

Lung cancer is the leading cause of cancer-related mortality worldwide. Non-small cell carcinoma and small cell carcinoma are the main histological subtypes and constitutes around 85% and 15% of all lung cancer respectively. Multimodality treatment plays a key role in the successful management of lung cancer depending upon the histological subtype, stage of disease, and performance status. Imaging modalities play an important role in the diagnosis and accurate staging of the disease, in assessing the response to neoadjuvant therapy, and in the follow-up of the patients. Last decade has witnessed voluminous upsurge in the use of positron emission tomography-computed tomography(PET-CT); role of PET-CT has widened exponentially in the management of lung cancer. The present article reviews the role of 18-fluoro-deoxyglucose PET-CT in the management of non small cell lung cancer with emphasis on staging of the disease and the assessment of response to neoadjuvant therapy based on available literature.

A dual-route optical emission spectroscopy diagnostic with wide spectral range and high wavelength resolution on HL-2A tokamak

A dual-route optical emission spectroscopy(D-OES)diagnostic is newly developed to monitor the optical emission from the X-point plasma region on the HL-2 A tokamak.This diagnostic is composed of an imaging system,a beam-splitting system for dual-route measurements,fiber bundles,a spectrometer system,and a control and acquisition system.One route is used to obtain wide-spectral-range spectra,and the other route is used to acquire high-wavelengthresolution line shapes.The spectral resolution of the wide-range spectrometers is 0.8 nm with a coverage of 800 nm(@200-1000 nm).The spectral resolution of the high-resolution spectrometer is 0.01 nm with a coverage of 6 nm(@200-660 nm).The spatial resolution of each route of D-OES is about 4 cm with 11 channels.The temporal resolution is 16 ms at maximum in the single-channel mode.Wide-range spectra(containing Balmer series and a Fulcher band)and highly resolved Ha line shapes are obtained by D-OES in the hydrogen glow discharge in the lab.D-OES measurements are carried out in the high-density deuterium experiments of HL-2A.The electron density n_(e)and deuterium temperature T_(D) in the X-point multifaceted asymmetric radiation from the edge(MARFE)region are derived simultaneously by fitting the measured D_(a) shape.The density n_(e)is observed to increase from~8.7×10^(18)m^(-3)to~7.8×10^(19)m^(-3),and the temperature T_(D)drops from~14.4 eV to~2.3 eV after the onset of MARFE in the discharge#38260.

Performance and Emission Characteristics of a CRDI Diesel Engine Fuelled by SiO_(2) Nanoparticle-Waste Fat Biodiesel Blends

This study investigates the use of waste fat biodiesel(WFB)from the leather industry as a substitute for diesel fuel.Specifically,it examines the diesel engine performance of WFB,a blend of WFB and diesel(B50),and different blends of WFB and silicon dioxide(SiO_(2))nanoparticles(B50SiO_(2)40,B50SiO_(2)80,and B50SiO_(2)120μg/g).The results indicate that the B50SiO_(2)120 blend increases brake thermal efficiency by 10.03%compared to pure biodiesel but falls 1.93%short of neat diesel.Furthermore,the B50SiO_(2)120 mixture reduces smoke,hydrocarbon,and carbon monoxide emissions by 31.87%,34.14%,and 43.97%respectively,compared to diesel.However,the B50SiO_(2)120 blend shows a 4.91%increase in nitrogen oxide emissions compared to diesel.

Study on concentration distribution and detonation characteristics for non-axisymmetric fuel dispersal

The study of non-axisymmetric fuel dispersal and detonation can provide reference for the prevention of industrial cloud explosion accidents and the design of fuel air explosive(FAE).The concentration and detonation fields of 85 kg cylindrical and fan-shaped fuel are investigated by experiments and numerical simulations.A dynamic model of the whole process for fuel dispersal and detonation is built.The concentration distribution of fuel is used as the initial condition to calculate the detonation stage,thus solving the initial value problem of detonation field.The phase and component changes of fuel cloud at different locations are compared.The fuel cloud is divided into directions of 0°,90°,135°and 180°.The results show that the maximum cloud radius is 20.94 m in 135°and the minimum is 12.04 m in 0°.The diameter of the detonation fireball is 53.6 m,and the peak temperature is 3455 K.The highest peak overpressure is 3.44 MPa in 0°and the lowest is 2.97 MPa in 135°.The proportion of liquid phase in 0°is22.90%,and the fuel loss is 11.8% and 9% higher than that in 135°and cylindrical charge,respectively.The stable propagation distance of blast wave in 135°is 42.50% longer than 0°and 28.37% longer than cylindrical charge.

Non-cropping period accounting for over a half of annual nitric oxide releases from cultivated calcareous-soil alpine ecosystems with marginally low emission factors

Nitric oxide(NO)emissions from alpine ecosystems conventionally being long-term cultivated with feed crops are not well quantified.The authors attempted to address this knowledge gap by performing a year-round experimental campaign in the northeastern Tibetan Plateau.Fertilized(F)and unfertilized(UF)treatments were established within a flat calcareous-soil site for the long-term cultivation of feed oats.NO fluxes and five soil variables were simultaneously measured.A single plow tillage accounted for approximately 54%–73%of the NO releases during the cropping period(CP);and the non-cropping period(NCP)contributed to 51%–58%of the annual emissions.The direct NO emissions factor(EFd)was 0.021%±0.021%.Significantly lower Q10 values(p<0.01)occurred in the F treatment during the CP(approximately 3.6)compared to those during the other period or in the other treatment(approximately 4.9?5.1),indicating a fertilizer-induced reduction in the temperature sensitivity.The selected soil variables jointly accounted for up to 72%(p<0.01)of the variance for all the fluxes across both treatments.This finding suggests that temporally and/or spatially distributed fluxes from alpine calcareous-soil ecosystems for feed crop production may be easily predicted if data on these soil variables are available.Further studies are needed to test the hypothesis that the EFd is larger in alpine feed-oat fields than those in this study if the soil moisture content is higher during the period following the basal application of ammoniumor urea-based fertilizer.

Design of the electron cyclotron emission diagnostic on EXL-50 spherical torus

The electron cyclotron emission(ECE)diagnostic system has been developed on the ENN spherical torus(EXL-50).The ECE system is designed to detect radiation emitted by energetic electrons,rather than conventional 1D electron temperature profile measurement,in the frequency range of 4-40 GHz.The system is composed of five subsystems,each covering a different frequency band,including the C-band(4-8 GHz),X-band(8-12 GHz),Ku-band(12-18 GHz),K-band(18-26.5 GHz)and Kα-band(26.4-40 GHz).The system uses heterodyne detection to analyze the received signals.The K-band and Kα-band subsystems are located horizontally in the equatorial plane of the EXL-50,while the C-band,X-band and Ku-band subsystems are located under the vacuum vessel of the EXL-50.To direct the microwaves from the plasma to the antennas for the horizontal detection subsystems,a quasi-optical system has been developed.For the vertical detection subsystems,the antennas are directly attached to the port located beneath the torus at R=700 mm,which is also the magnetic axis of the torus.The system integration,bench testing and initial experimental results will be thoroughly discussed,providing a comprehensive understanding of the ECE system s performance and capabilities.

Influence of Pretreatment Conditions of Stainless Steel Substrates on Field Emission Properties of Carbon Nanotubes Films

Carbon nanotubes (CNTs) are synthesized from methane and hydrogen gas mixture directly on stainless steel plates by microwave plasma chemical vapor deposition (MWPCVD).By varying pretreatment conditions of the substrates such as mechanically polishing and acid washing,it is found the polishing and acid washing can lower the turn-on field and improve the emission current density.The current density of the un-pretreated sample attains 1.2mA/cm 2,but the polished sample and polished acidly washed sample attain 3.2 and 2.75mA/cm 2,respectively,at the electric field of 6.25V/μm.

Nonlinear change of ion-induced secondary electron emission in theκ-Al_(2)O_(3) surface charging from first-principle modelling

Secondary electron emission(SEE)induced by the positive ion is an essential physical process to influence the dynamics of gas discharge which relies on the specific surface material.Surface charging has a significant impact on the material properties,thereby affecting the SEE in the plasma-surface interactions.However,it does not attract enough attention in the previous studies.In this paper,SEE dependent on the charged surface of specific materials is described with the computational method combining a density functional theory(DFT)model from the first-principle theory and the theory of Auger neutralization.The effect ofκ-Al2O3 surface charge,as an example,on the ion-induced secondary electron emission coefficient(SEEC)is investigated by analyzing the defect energy level and band structure on the charged surface.Simulation results indicate that,with the surface charge from negative to positive,the SEEC of a part of low ionization energy ions(such as Ei=12.6 eV)increases first and then decreases,exhibiting a nonlinear changing trend.This is quite different from the monotonic decreasing tendency observed in the previous model which simplifies the electronic structure.This irregular increase of the SEEC can be attributed to the lower escaped probability of orbital energy.The results further illustrate that the excessive charge could cause the bottom of the conduction band close to the valence band,thus leading to the decrease of the orbital energy occupied by the excited electrons.The nonlinear change of SEEC demonstrates a more realistic situation of how the electronic structure of material surface influences the SEE process.This work provides an accurate method of calculating SEEC from specific materials,which is urgent in widespread physical scenarios sensitive to surface materials,such as increasingly growing practical applications concerning plasma-surface interactions.

Co_(3)O_(4)as an efficient passive NO_(x) adsorber for emission control during cold-start of diesel engines

The Co_(3)O_(4)nanoparticles,dominated by a catalytically active(110)lattice plane,were synthesized as a low-temperature NO_(x) adsorbent to control the cold start emissions from vehicles.These nanoparticles boast a substantial quantity of active chemisorbed oxygen and lattice oxygen,which exhibited a NO_(x) uptake capacity commensurate with Pd/SSZ-13 at 100℃.The primary NO_(x) release temperature falls within a temperature range of 200-350℃,making it perfectly suitable for diesel engines.The characterization results demonstrate that chemisorbed oxygen facilitate nitro/nitrites intermediates formation,contributing to the NO_(x) storage at 100℃,while the nitrites begin to decompose within the 150-200℃range.Fortunately,lattice oxygen likely becomes involved in the activation of nitrites into more stable nitrate within this particular temperature range.The concurrent processes of nitrites decomposition and its conversion to nitrates results in a minimal NO_(x) release between the temperatures of 150-200℃.The nitrate formed via lattice oxygen mainly induces the NO_(x) to be released as NO_(2) within a temperature range of 200-350℃,which is advantageous in enhancing the NO_(x) activity of downstream NH_(3)-SCR catalysts,by boosting the fast SCR reaction pathway.Thanks to its low cost,considerable NO_(x) absorption capacity,and optimal release temperature,Co_(3)O_(4)demonstrates potential as an effective material for passive NO_(x) adsorber applications.