Surface OH radical concentration in Beijing City was measured by impregnated filter trapping technique-high performance liquid chromatography (IFT-HPLC). The observed concentration of OH radical showed obvious diurnal...Surface OH radical concentration in Beijing City was measured by impregnated filter trapping technique-high performance liquid chromatography (IFT-HPLC). The observed concentration of OH radical showed obvious diurnal and seasonal variations, with maximum readings at noon or afternoon, similar to 80x10(6)OH/cm(3) in summer and similar to 20x10(6)-40x10(6)OH/cm(3) in fall. On the basis of measured data, the reaction rates related to the photochemical process of HO(x) (OH+HO(2)) were derived and characteristics of atmospheric chemical processes in the city were analyzed. The results showed that conversion rates of atmospheric OH and HO(2) in the summer of Beijing City were about 700x10(6) molecule/(cm(3) . s) and 600x10(6)molecule/(cm(3) . s), respectively. And the net production of OH in the air of the city mainly originated from the photolysis of the gaseous HNO(2), and the main sink of OH were the photochemical reactions with VOCs, NO(2), HCHO and CO. It was different from the clean area.展开更多
为研究不同海拔下SCR系统性能,分别在80、90、100 k Pa大气压力下对一台满足国五排放标准的高压共轨柴油机进行性能与排放试验,以研究排气温度、排气流量和海拔变化对NO_(x)转化率和NH_(3)泄漏量的影响。结果表明:在排气流量为350 kg/h...为研究不同海拔下SCR系统性能,分别在80、90、100 k Pa大气压力下对一台满足国五排放标准的高压共轨柴油机进行性能与排放试验,以研究排气温度、排气流量和海拔变化对NO_(x)转化率和NH_(3)泄漏量的影响。结果表明:在排气流量为350 kg/h情况下,NO_(x)转化率随排气温度升高呈现先增后减的趋势,不同温度下NO_(x)转化率最大差值为43.4百分点;NH_(3)泄漏量随着温度的升高大体上呈下降趋势,不同温度下NH_(3)泄漏量最大差值为328×10^(-6);NO_(x)转化率随排气流量升高呈现先增后减的趋势,在250℃时,不同排气流量下NO_(x)转化效率最大相差21.5百分点;NH_(3)泄漏量随排气流量的增大而增加,在250℃时,不同排气流量下NH_(3)泄漏量最大差值为90.8×10^(-6)。相同工况下,海拔越高,NO_(x)转化率越高,NH_(3)泄漏量越小,大气压力为80和100 k Pa下NO_(x)转化率最大相差20.1百分点,NH_(3)泄漏量最大相差54.6×10^(-6)。展开更多
The presented work reports the selective catalytic reduction(SCR)of NO_(x) assisted by dielectric barrier discharge plasma via simulating marine diesel engine exhaust,and the experimental results demonstrate that the ...The presented work reports the selective catalytic reduction(SCR)of NO_(x) assisted by dielectric barrier discharge plasma via simulating marine diesel engine exhaust,and the experimental results demonstrate that the low-temperature activity of NH_(3)-SCR assisted by non-thermal plasma is enhanced significantly,particularly in the presence of a C_(3)H_(6) additive.Simultaneously,CeMnZrO_(x)@TiO_(2) exhibits strong tolerance to SO_(2) poisoning and superior catalytic stability.It is worthwhile to explore a new approach to remove NO_(x) from marine diesel engine exhaust,which is of vital significance for both academic research and practical applications.展开更多
基金Under the auspices of the National Natural Science Foundation of China(No.40075026)
文摘Surface OH radical concentration in Beijing City was measured by impregnated filter trapping technique-high performance liquid chromatography (IFT-HPLC). The observed concentration of OH radical showed obvious diurnal and seasonal variations, with maximum readings at noon or afternoon, similar to 80x10(6)OH/cm(3) in summer and similar to 20x10(6)-40x10(6)OH/cm(3) in fall. On the basis of measured data, the reaction rates related to the photochemical process of HO(x) (OH+HO(2)) were derived and characteristics of atmospheric chemical processes in the city were analyzed. The results showed that conversion rates of atmospheric OH and HO(2) in the summer of Beijing City were about 700x10(6) molecule/(cm(3) . s) and 600x10(6)molecule/(cm(3) . s), respectively. And the net production of OH in the air of the city mainly originated from the photolysis of the gaseous HNO(2), and the main sink of OH were the photochemical reactions with VOCs, NO(2), HCHO and CO. It was different from the clean area.
文摘为研究不同海拔下SCR系统性能,分别在80、90、100 k Pa大气压力下对一台满足国五排放标准的高压共轨柴油机进行性能与排放试验,以研究排气温度、排气流量和海拔变化对NO_(x)转化率和NH_(3)泄漏量的影响。结果表明:在排气流量为350 kg/h情况下,NO_(x)转化率随排气温度升高呈现先增后减的趋势,不同温度下NO_(x)转化率最大差值为43.4百分点;NH_(3)泄漏量随着温度的升高大体上呈下降趋势,不同温度下NH_(3)泄漏量最大差值为328×10^(-6);NO_(x)转化率随排气流量升高呈现先增后减的趋势,在250℃时,不同排气流量下NO_(x)转化效率最大相差21.5百分点;NH_(3)泄漏量随排气流量的增大而增加,在250℃时,不同排气流量下NH_(3)泄漏量最大差值为90.8×10^(-6)。相同工况下,海拔越高,NO_(x)转化率越高,NH_(3)泄漏量越小,大气压力为80和100 k Pa下NO_(x)转化率最大相差20.1百分点,NH_(3)泄漏量最大相差54.6×10^(-6)。
基金supported by National Key Research and Development Project of China(No.2019YFC1805503)National Engineering Laboratory for Mobile Source Emission Control Technology(No.NELMS2019A13)+1 种基金the Open Project Program of the State Key Laboratory of Petroleum Pollution Control(No.PPC2019013)Major Science and Technology Projects of Shanxi Province(No.20181102017)。
文摘The presented work reports the selective catalytic reduction(SCR)of NO_(x) assisted by dielectric barrier discharge plasma via simulating marine diesel engine exhaust,and the experimental results demonstrate that the low-temperature activity of NH_(3)-SCR assisted by non-thermal plasma is enhanced significantly,particularly in the presence of a C_(3)H_(6) additive.Simultaneously,CeMnZrO_(x)@TiO_(2) exhibits strong tolerance to SO_(2) poisoning and superior catalytic stability.It is worthwhile to explore a new approach to remove NO_(x) from marine diesel engine exhaust,which is of vital significance for both academic research and practical applications.
