3-nitro-1,2,4-triazol-5-one(NTO) and its salts are insensitive energetic materials with wide application prospects.The widespread emphasis has been put on the above materials by research workers at home and abroad sin...3-nitro-1,2,4-triazol-5-one(NTO) and its salts are insensitive energetic materials with wide application prospects.The widespread emphasis has been put on the above materials by research workers at home and abroad since the 1980s.The preparation, characterization and application of NTO and its salts are reviewed.Three kinds of NTO-based explosive formulations abroad are introduced.The research status of NTO is summarized.The research focal point in future is pointed out.展开更多
Eleven rare earth salts of 3-nitro-1, 2 , 4-triazol-5-one (NTO) was prepared by using aqueous solutions of lithium salt of NTO and corresponding rare earth nitrates. The formulae of these salts are determined as RE(NT...Eleven rare earth salts of 3-nitro-1, 2 , 4-triazol-5-one (NTO) was prepared by using aqueous solutions of lithium salt of NTO and corresponding rare earth nitrates. The formulae of these salts are determined as RE(NTO)3. nH2O, where RE is Y, La, Ce, Pr, Nd, Sm, Eu, Gd,Tb, Dy or Yb, and n is 6, 7, 7, 7, 8, 7, 7, 7, 5, 5 and 6 correspondingly. Their thermal decomposition mechanism was studied by using DSC, TG-DTG and FT-IR techniques under linearly increasing temperature.展开更多
A relationship is established, using the least squares method, between the standard enthalpy of formation and the standard enthalpy of formation divided by the exothermic denitration decomposition peak absolute temper...A relationship is established, using the least squares method, between the standard enthalpy of formation and the standard enthalpy of formation divided by the exothermic denitration decomposition peak absolute temperature corresponding to β →0.展开更多
文摘3-nitro-1,2,4-triazol-5-one(NTO) and its salts are insensitive energetic materials with wide application prospects.The widespread emphasis has been put on the above materials by research workers at home and abroad since the 1980s.The preparation, characterization and application of NTO and its salts are reviewed.Three kinds of NTO-based explosive formulations abroad are introduced.The research status of NTO is summarized.The research focal point in future is pointed out.
文摘Eleven rare earth salts of 3-nitro-1, 2 , 4-triazol-5-one (NTO) was prepared by using aqueous solutions of lithium salt of NTO and corresponding rare earth nitrates. The formulae of these salts are determined as RE(NTO)3. nH2O, where RE is Y, La, Ce, Pr, Nd, Sm, Eu, Gd,Tb, Dy or Yb, and n is 6, 7, 7, 7, 8, 7, 7, 7, 5, 5 and 6 correspondingly. Their thermal decomposition mechanism was studied by using DSC, TG-DTG and FT-IR techniques under linearly increasing temperature.
文摘A relationship is established, using the least squares method, between the standard enthalpy of formation and the standard enthalpy of formation divided by the exothermic denitration decomposition peak absolute temperature corresponding to β →0.
