A High-Temperature β-Phase NaMnO2 Stabilized by Cu Doping and Its Na Storage Properties

The high-temperature β-phase NaMnO2 is a promising material for Na-ion batteries（NIBs） due to its high capacity and abundant resources. However, the synthesis of phase-pure -NaMnO2 is burdensome and costineffective because it needs to be sintered under oxygen atmosphere at high temperature and followed by a quenching procedure. Here we first report that the pure β phase can be stabilized by Cu-doping and easily synthesized by replacing a proportion of Mn with Cu via a simplified process including sintering in air and cooling to room temperature naturally. Based on the first-principle calculations, the band gap decreases from 0.7 eV to 0.3 eV, which indicates that the electronic conductivity can be improved by Cu-doping. The designed -NaCu（0.1）Mn（0.9）O2 is applied as cathode in NIBs, exhibiting an energy density of 419 Wh/kg and better performance in terms of rate capability and cycling stability than those in the undoped case.

Achieving high initial Coulombic efficiency for competent Na storage by microstructure tailoring from chiral nematic nanocrystalline cellulose

Although it has been proven that porous,heteroatomic,and defective structures improve Na storage performance,they also severely affect the initial Coulombic efficiency(ICE)due to the huge irreversible capacity in the first cycle,which always limits the practical application of carbon anodes in commercial Na-ion batteries(NIBs).Here,we show the successful synthesis of nanocrystalline cellulose and the derivative hard carbons.A series of treatments including acid hydrolysis,hydrothermal carbonization,and hightemperature pyrolysis help tune the pores,heteroatoms,and defects to achieve an optimized balance between superior ICE and reversible capacity of up to 90.4%and 314 mAh g^(−1).This study highlights that tailoring the electrode microstructure could be an important strategy in the future design of carbonaceous anode materials for high-performance Na-ion batteries.

Freestanding MoSe_(2)nanoflowers for superior Li/Na storage properties

MoSe_(2),with high theoretical specific capacity,has attracted a lot of attention.There remains an open challenge to effectively suppress the irreversible selenium dissolution and rapid capacity decrease induced by severe volume change during cycling.Herein,we synthesize MoSe_(2)nanoflowers dispersed on one-dimensional(1D)N-doped carbon nanofibers(MoSe_(2)@NCNFs)for use as a freestanding electrode.In this unique structure,the 1D N-doped carbon nanofibers are found to not only enhance the conductivity but also ensure the structural integrity during the Li^(+)/Na^(+)insertion/destraction processes.As expected,at 2 A·g^(-1),the specific capacity of the MoSe_(2)@NCNFs is maintained at 180 mAh·g^(-1)after 500 cycles when used in lithium storage applications.Furthermore,in the case of sodium storage,at 1 A·g^(-1),the MoSe_(2)@NCNFs shows a capacity of 122mAh·g^(-1)after 500 cycles.These findings suggest that the MoSe_(2)@NCNF electrodes may be a promising candidate for use in reversible Li/Na storage applications.

Natural Lignin:A Sustainable and Cost-Effective Electrode Material for High-Temperature Na-Ion Battery

Rechargeable sodium-ion batteries usually suffer from accelerated electrode destruction at high temperatures and high synthesis costs of electrode materials.Therefore,it is highly desirable to explore novel organic electrodes considering their cost-effectiveness and large adaptability to volume changes.Herein,natural biomass,pristine lignin,is employed as the sodium-ion battery anodes,and their sodium storage performance is investigated at room temperature and 60℃.The lignin anodes exhibit excellent high-temperature sodium-ion battery performance.This mainly results from the generation of abundant reactive sites(C=O)due to the high temperature-induced homogeneous cleavage of the C_(β)-O bond in the lignin macromolecule.This work can inspire researchers to explore other natural organic materials for large-scale applications and high-value utilization in advanced energy storage devices.

High-temperature treatment induced carbon anode with ultrahigh Na storage capacity at low-voltage plateau

Sodium-ion batteries （NIBs） show great prospect on the energy storage applications benefiting from thei low cost and the abundant Na resources despite the expected lower energy density compared wit lithium-ion batteries （LIBs）. To further enhance the competitive advantage, especially in energy densit3 developing the high-capacity carbon anode materials can be one of the effective approaches to realiz this goal. Herein, we report a novel carbon anode made from charcoal with a high capacity of ~400 Ah g i, wherein about 85% （〉330 mAh g^-1） of its total capacity is derived from the long plateau regio below ~0.1 V. which differs fiom those of typical hard carbon materials （~300 mAh g^-l） in NIBs but i similar to the graphite anode in LIBs. When coupled with air-stable Nao.gCuo.22Feo.3oMno.4802 oxid cathode, a high-energy density of ~240 Wh kg^-1 is achieved with good rate capability and cyclin stability. The discovery of this promising carbon anode is expected to further improve the energy densit of NIBs towards large-scale electrical energy storage.

Performance analysis of an iSCSI-based unified storage network

In this paper, we introduced a novel storage architecture 'Unified Storage Network', which merges NAC( Network Attached Channel) and SAN( Storage Area Network) , and provides the file I/O services as NAS devices and provides the block I/O services as SAN. To overcome the drawbacks from FC, we employ iSCSI to implement the USN( Unified Storage Network) . To evaluate whether iSCSI is more suitable for implementing the USN, we analyze iSCSI protocol and compare it with FC protocol from several components of a network protocol which impact the performance of the network. From the analysis and comparison, we can conclude that the iSCSI is more suitable for implementing the storage network than the FC under condition of the wide-area network. At last, we designed two groups of experiments carefully.

NASSN:a NAS-based storage network

With the digital information and application requirement on the Internet increasing fleetly nowadays,it is urgent to work out a network storage system with a large capacity,a high availability and scalability.To solve the above-mentioned issues,a NAS-based storage network(for short NASSN)has been designed.Firstly,the NASSN integrates multi-NAS,iNAS(an iSCSI-based NAS)and enterprise SAN with the help of storage virtualization,which can provide a greater capacity and better scalability.Secondly,the NASSN can provide high availability with the help of server and storage subsystem redundancy technologies.Thirdly,the NASSN simultaneously serves for both the file I/O and the block I/O with the help of an iSCSI module,which has the advantages of NAS and SAN.Finally,the NASSN can provide higher I/O speed by a high network-attached channel which implements the direct data transfer between the storage device and client.In the experiments,the NASSN has ultra-high-throughput for both of the file I/O requests and the block I/O requests.

Research on the Security of the United Storage Network Based on NAS

A multi-user view file system (MUVFS) and a security scheme are developed to improve the security of the united storage network (USN) that integrates a network attached storage (NAS) and a storage area network (SAN). The MUVFS offers a storage volume view for each authorized user who can access only the data in his own storage volume, the security scheme enables all users to encrypt and decrypt the data of their own storage view at client-side, and the USN server needs only to check the users’ identities and the data’s integrity. Experiments were performed to compare the sequential read, write and read/write rates of NFS+MUVFS+secure_module with those of NFS. The results indicate that the security of the USN is improved greatly with little influence on the system performance when the MUVFS and the security scheme are integrated into it.

Three-Dimensional Self-assembled Hairball-Like VS4 as High-Capacity Anodes for Sodium-Ion Batteries

Sodium-ion batteries(SIBs)are considered to be attractive candidates for large-scale energy storage systems because of their rich earth abundance and consistent performance.However,there are still challenges in developing desirable anode materials that can accommodate rapid and stable insertion/extraction of Na+and can exhibit excellent electrochemical performance.Herein,the self-assembled hairball-like VS4 as anodes of SIBs exhibits high discharge capacity(660 and 589 mAh g−1 at 1 and 3 A g−1,respectively)and excellent rate property(about 100%retention at 10 and 20 A g−1 after 1000 cycles)at room temperature.Moreover,the VS4 can also exhibit 591 mAh g−1 at 1 A g−1 after 600 cycles at 0°C.An unlike traditional mechanism of VS4 for Na+storage was proposed according to the dates of ex situ characterization,cyclic voltammetry,and electrochemical kinetic analysis.The capacities of the final stabilization stage are provided by the reactions of reversible transformation between Na2S and S,which were considered the reaction mechanisms of Na–S batteries.This work can provide a basis for the synthesis and application of sulfur-rich compounds in fields of batteries,semiconductor devices,and catalysts.

A New Scheme of Integrating NAS with SAN

This paper reviewed two types of network storage technique: NAS and SAN. After comparing and analyzing, it concluded that the ultimate realization of network storage will be in the eventual convergence of NAS and SAN architectures. Currently, all the integration methods are based on the architecture level. This paper presented a device level integration scheme based on IXP1200 network processor. The device can be used as an NAS file server or an SAN’s storage node. Furthermore, it can be used as a bridge to connect NAS and SAN, and then be shared by their clients.

Security System in United Storage Network and Its Implementation

With development of networked storage and its applications, united storage network (USN) combined with network attached storage (NAS) and storage area network (SAN) has emerged. It has such advantages as high performance, low cost, good connectivity, etc. However the security issue has been complicated because USN responds to block I/O and file I/O requests simultaneously. In this paper, a security system module is developed to prevent many types of attacks against USN based on NAS head. The module not only uses effective authentication to prevent unauthorized access to the system data, but also checks the data integrity. Experimental results show that the security module can not only resist remote attacks and attacks from those who has physical access to the USN, but can also be seamlessly integrated into underlying file systems, with little influence on their performance.

A Disk Scheduling Algorithm:SPFF

We put forward an optimal disk schedule with n disk requests and prove its optimality mathematically.Generalizing the idea of an optimal disk schedule, we remove the limit of n requests and, at the same time, consider the dynamically arrival model of disk requests to obtain an algorithm, shortest path first-fit first （SPFF）. This algorithm is based on the shortest path of disk head motion constructed by all the pendent requests. From view of the head moving distance, it has the stronger glohality than SSTF. From view of the head-moving direction, it has the better flexibility than SCAN. Therefore, SPFF keeps the advantage of SCAN and, at the same time, absorbs the strength of SSTF. The algorithm SPFF not only shows the more superiority than other scheduling polices, but also have higher adjustability to meet the computer system＇s different demands.

Advances in metal phosphides for sodium-ion batteries

Sodium-ion batteries(SIBs)have been extensively studied as the potential alter-native to lithium-ion batteries(LIBs)due to the abundant natural reserves and low price of sodium resources.Nevertheless,Na+ions possess a larger radius than Li+,resulting in slow diffusion dynamics in electrode materials,and thus seeking appropriate anode materials to meet high performance standards has become a trend in the field of SIBs.In this context,owing to the advantages of high theoretical capacity and proper redox potential,metal phosphides(MPs)are considered to be the promising materials to make up for the gap of SIBs anode materials.In this review,the recent development of MPs anode materials for SIBs is reviewed and analyzed comprehensively and deeply,including the synthesis method,advanced modification strategy,electrochemical performance,and Na storage mechanism.In addition,to promote the wide application of the emerg-ing MPs anodes for SIBs,several research emphases in the future are pointed out to overcome challenges toward the commercial application.