ZnO nanoparticles with an average size of 125 nm were prepared via homogeneous precipitation method and were characterized by SEM.The products were surface-modified by the surfactant SDS.Surface-modified nano particle...ZnO nanoparticles with an average size of 125 nm were prepared via homogeneous precipitation method and were characterized by SEM.The products were surface-modified by the surfactant SDS.Surface-modified nano particles were added at a mass ratio of 1.0%,2.0%,3.0%,and 4.0%,respectively,in base oil and their friction and wear behaviors were evaluated on a MRS-10D type four-ball wear tester.After four-ball wear tests,the morphology of the rubbing surfaces was evaluated with metallographic microscope.It was revealed that the modified nano ZnO had excellent behavior for improving anti-wear property and friction coefficient,which could greatly reduce the friction of machine parts.展开更多
Nano zinc oxide （ZnO） is a very useful and important material in many industrial and biological applications. In the present work, ZnO was synthesized by post thermal degradation of the precursor ＂zinc acetate di-h...Nano zinc oxide （ZnO） is a very useful and important material in many industrial and biological applications. In the present work, ZnO was synthesized by post thermal degradation of the precursor ＂zinc acetate di-hydrate＂ templated in crosslinked polyacrylic acid （PAA）. The crosslinked PAA template was prepared through an in-situ polymerization process adopted in presence of ammonium per sulphate, as an initiator, and N, Nt- methylene bis-acrylamide as the crosslinker. Variation of preparation parameters and their impact on the oxide stoichiometry, crystal structure, crystallite size and surface texture of the oxide were investigated. Energy dispersive X-ray technique （EDX）, X-ray diffraction （XRD） and scanning electron microscopy （SEM） were convincingly used to reveal the oxide structural features and characteristics. The performed bioassay tests indicated the efficacy of this method of preparation to produce nano ZnO with novel insecticidal activity against the greater wax moth, Galleria rnellonella.展开更多
基金supported by Liaoning Provincial Office of Education for Innovation Team (Project number:2006T001)Liaoning Province of Key Laboratory Project (Project number:2008403001)
文摘ZnO nanoparticles with an average size of 125 nm were prepared via homogeneous precipitation method and were characterized by SEM.The products were surface-modified by the surfactant SDS.Surface-modified nano particles were added at a mass ratio of 1.0%,2.0%,3.0%,and 4.0%,respectively,in base oil and their friction and wear behaviors were evaluated on a MRS-10D type four-ball wear tester.After four-ball wear tests,the morphology of the rubbing surfaces was evaluated with metallographic microscope.It was revealed that the modified nano ZnO had excellent behavior for improving anti-wear property and friction coefficient,which could greatly reduce the friction of machine parts.
文摘Nano zinc oxide （ZnO） is a very useful and important material in many industrial and biological applications. In the present work, ZnO was synthesized by post thermal degradation of the precursor ＂zinc acetate di-hydrate＂ templated in crosslinked polyacrylic acid （PAA）. The crosslinked PAA template was prepared through an in-situ polymerization process adopted in presence of ammonium per sulphate, as an initiator, and N, Nt- methylene bis-acrylamide as the crosslinker. Variation of preparation parameters and their impact on the oxide stoichiometry, crystal structure, crystallite size and surface texture of the oxide were investigated. Energy dispersive X-ray technique （EDX）, X-ray diffraction （XRD） and scanning electron microscopy （SEM） were convincingly used to reveal the oxide structural features and characteristics. The performed bioassay tests indicated the efficacy of this method of preparation to produce nano ZnO with novel insecticidal activity against the greater wax moth, Galleria rnellonella.
