Sn thin film on Cu foil substrate as the anode of lithium ion battery was prepared by direct current magnetron sputtering(DCMS). The surface morphology,composition and thickness and the electrochemical behaviors of th...Sn thin film on Cu foil substrate as the anode of lithium ion battery was prepared by direct current magnetron sputtering(DCMS). The surface morphology,composition and thickness and the electrochemical behaviors of the prepared Sn thin film were characterized by scanning electron microscopy(SEM),X-ray diffraction(XRD),inductively coupled plasma atomic emission spectrometry(ICP),cyclic voltammetry(CV) and galvanostatic charge/ discharge(GC) measurements. It is found that the Sn film is consists of pure Sn with an average particle diameter of 100 nm. The thickness of the film is about 320 nm. The initial lithium insertion capacity of the Sn film is 771 mA·h/g. The reversible capacity of the film is 570 mA·h/g and kept at 270 mA·h/g after 20 cycles.展开更多
The SEM and AFM images of three TiO2 nano-films prepared at different conditions were obtained and transformed into digital format.The multifractal analyses for three films were made using height from a depth of thick...The SEM and AFM images of three TiO2 nano-films prepared at different conditions were obtained and transformed into digital format.The multifractal analyses for three films were made using height from a depth of thickness of film B and q from 55 to -55.The scale- invariance is very good for all lnχq(ε)～ln( plots and τ(q)～q plots at least close to three orders of magnitude.But the multifractal spectra f(a) of the films are quite distinct due to their different height distribution.展开更多
Nitinol alloy occluders are widely used in the transcatheter intervention treatment of congenital heart diseases like patent ductus arteriosus(PDA).However,nitinol alloy contains high levels of nickel,which can lead t...Nitinol alloy occluders are widely used in the transcatheter intervention treatment of congenital heart diseases like patent ductus arteriosus(PDA).However,nitinol alloy contains high levels of nickel,which can lead to toxic effects in the immune and hematopoietic systems if released in sufficient quantities.A new type of single-rivet occluder coated with nano-film has been developed to limit the release of nickel.In total,23 patients were recruited and randomly assigned to the experimental group(n=12) with the new nano-film single-rivet occluders or the control group(n=11) with the traditional occluders.One case in the control group was lost to follow-up.The remaining 22 cases were followed up at 24 h,7 days,1 month,3 months,and 6 months after the procedure.There were no statistically significant differences in routine blood test,alanine aminotransferase,creatinine,and troponin between the experimental and control groups.Serum nickel concentration in both two groups increased at 24 h after the procedure,peaked at 1 month,and returned to preoperative levels at 6 months.Serum nickel levels in the experimental group were significantly lower than in the control group at 24 h,7 days,1 month,and 3 months after the procedure.These data suggested that the nano-film coating effectively prevented nickel release from the new occluders,and therefore has a preferable safety profile.展开更多
基金Projects(50771046 20373016) supported by the National Natural Science Foundation of China+2 种基金Project(05200534) supported by the Natural Science Foundation of Guangdong Province, ChinaProject(2006A10704003) supported by the Key Project of Guangdong Province, ChinaProject(2006Z3-D2031) supported by the Key Project of Guangzhou City, China
文摘Sn thin film on Cu foil substrate as the anode of lithium ion battery was prepared by direct current magnetron sputtering(DCMS). The surface morphology,composition and thickness and the electrochemical behaviors of the prepared Sn thin film were characterized by scanning electron microscopy(SEM),X-ray diffraction(XRD),inductively coupled plasma atomic emission spectrometry(ICP),cyclic voltammetry(CV) and galvanostatic charge/ discharge(GC) measurements. It is found that the Sn film is consists of pure Sn with an average particle diameter of 100 nm. The thickness of the film is about 320 nm. The initial lithium insertion capacity of the Sn film is 771 mA·h/g. The reversible capacity of the film is 570 mA·h/g and kept at 270 mA·h/g after 20 cycles.
文摘The SEM and AFM images of three TiO2 nano-films prepared at different conditions were obtained and transformed into digital format.The multifractal analyses for three films were made using height from a depth of thickness of film B and q from 55 to -55.The scale- invariance is very good for all lnχq(ε)～ln( plots and τ(q)～q plots at least close to three orders of magnitude.But the multifractal spectra f(a) of the films are quite distinct due to their different height distribution.
基金supported by grants from the National Natural Science Foundation of China(No.31330029)Wuhan Youth Program for Healthcare Scholars(No.201477)Wuhan Chenguang Program of Science and Technology(No.2016070204010148)
文摘Nitinol alloy occluders are widely used in the transcatheter intervention treatment of congenital heart diseases like patent ductus arteriosus(PDA).However,nitinol alloy contains high levels of nickel,which can lead to toxic effects in the immune and hematopoietic systems if released in sufficient quantities.A new type of single-rivet occluder coated with nano-film has been developed to limit the release of nickel.In total,23 patients were recruited and randomly assigned to the experimental group(n=12) with the new nano-film single-rivet occluders or the control group(n=11) with the traditional occluders.One case in the control group was lost to follow-up.The remaining 22 cases were followed up at 24 h,7 days,1 month,3 months,and 6 months after the procedure.There were no statistically significant differences in routine blood test,alanine aminotransferase,creatinine,and troponin between the experimental and control groups.Serum nickel concentration in both two groups increased at 24 h after the procedure,peaked at 1 month,and returned to preoperative levels at 6 months.Serum nickel levels in the experimental group were significantly lower than in the control group at 24 h,7 days,1 month,and 3 months after the procedure.These data suggested that the nano-film coating effectively prevented nickel release from the new occluders,and therefore has a preferable safety profile.
