With the pretreatment of pyrolysis, the uniform, smooth, dense and crack free Gd2O3∶Eu3+ films were obtained by sol-gel process without shielding atmosphere. Atomic force microscopy （AFM）, X-ray diffraction （XRD）...With the pretreatment of pyrolysis, the uniform, smooth, dense and crack free Gd2O3∶Eu3+ films were obtained by sol-gel process without shielding atmosphere. Atomic force microscopy （AFM）, X-ray diffraction （XRD）, Ellipsometry, transmission, photoluminescence and X-ray excited emission were applied to study to the surface morphology, structure, thickness and optical properties of the films. The results show that the films are made up of grains with cubic structure in average size about 22 nm. With 21 times reproducible spin coating and pyrolysis treatment, the thickness of the film could reach to 792 nm and the transmittance of the film in visible region is above 90%. Two peaks at 223 and 250 nm are found in excitation spectra, which correspond to host lattice （HL） excitation and charge transfer （CT） excitation, respectively. Meanwhile, the main peak relates to HL excitation which is contrary to that of Gd2O3∶Eu3+ powder. This phenomenon will be beneficial to radioluminescence. The emission spectra show that the main peak located at 611 nm could be excited either by UV or X-ray, which correspond to （（）7F2→（）5D0） transition in Eu3+ ions. The luminescence intensity at 10 ms is only 10-4 time of that at 10 μs, which means that the afterglow in Gd2O3∶Eu3+ films is insignificant for X-ray imaging.展开更多
NiO-La0.3Ce0.7O2-δ(LDC30) novel anode was investigated for IT-SOFCs(Intermediate Temperature-Solid Oxide Fuel Cells) with LaGaO3-based electrolyte. The results showed that LDC30 has a suitable chemical compatibility ...NiO-La0.3Ce0.7O2-δ(LDC30) novel anode was investigated for IT-SOFCs(Intermediate Temperature-Solid Oxide Fuel Cells) with LaGaO3-based electrolyte. The results showed that LDC30 has a suitable chemical compatibility with NiO and NiO-LDC30 has a good thermal expansion matching with LDC30 interlayer and LSGM(La0.8Sr0.2Ga0.8Mg0.2O3-δ) electrolyte, so NiO-LDC30/LDC30 was considered as a feasible and novel anode system. It was also shown that NiO content plays a key role on polarization performance and morphology of the anode. When the content of NiO was 60%(mass fraction), the polarization loss of anode was the lowest. Next we will optimize the porosity and sintering procedure to modify the microstructure and performance of the anode.展开更多
文摘With the pretreatment of pyrolysis, the uniform, smooth, dense and crack free Gd2O3∶Eu3+ films were obtained by sol-gel process without shielding atmosphere. Atomic force microscopy （AFM）, X-ray diffraction （XRD）, Ellipsometry, transmission, photoluminescence and X-ray excited emission were applied to study to the surface morphology, structure, thickness and optical properties of the films. The results show that the films are made up of grains with cubic structure in average size about 22 nm. With 21 times reproducible spin coating and pyrolysis treatment, the thickness of the film could reach to 792 nm and the transmittance of the film in visible region is above 90%. Two peaks at 223 and 250 nm are found in excitation spectra, which correspond to host lattice （HL） excitation and charge transfer （CT） excitation, respectively. Meanwhile, the main peak relates to HL excitation which is contrary to that of Gd2O3∶Eu3+ powder. This phenomenon will be beneficial to radioluminescence. The emission spectra show that the main peak located at 611 nm could be excited either by UV or X-ray, which correspond to （（）7F2→（）5D0） transition in Eu3+ ions. The luminescence intensity at 10 ms is only 10-4 time of that at 10 μs, which means that the afterglow in Gd2O3∶Eu3+ films is insignificant for X-ray imaging.
文摘NiO-La0.3Ce0.7O2-δ(LDC30) novel anode was investigated for IT-SOFCs(Intermediate Temperature-Solid Oxide Fuel Cells) with LaGaO3-based electrolyte. The results showed that LDC30 has a suitable chemical compatibility with NiO and NiO-LDC30 has a good thermal expansion matching with LDC30 interlayer and LSGM(La0.8Sr0.2Ga0.8Mg0.2O3-δ) electrolyte, so NiO-LDC30/LDC30 was considered as a feasible and novel anode system. It was also shown that NiO content plays a key role on polarization performance and morphology of the anode. When the content of NiO was 60%(mass fraction), the polarization loss of anode was the lowest. Next we will optimize the porosity and sintering procedure to modify the microstructure and performance of the anode.
文摘为研究稀土发光纳米晶的微观结构和形貌对发光性能的影响,用凝胶-微波干燥法和凝胶-烘箱干燥法制备了花状形貌的Sr3Al2O6晶体.研究了微波干燥和烘箱干燥两种不同的干燥方式对溶胶-凝胶法制备的Sr3Al2O6∶Eu2+发光粉体粒径、形貌、团聚程度、干燥时间及发光性能等的影响,结果表明采用微波干燥不仅可以大大缩短干燥所需时间,而且有利于减弱Sr3Al2O6∶Eu2+发光粉料的团聚和团聚程度,制得了颗粒分散均匀、团聚程度低、发光强度高的Sr3Al2O6∶Eu2+花状形貌粉体.研究了Sr3Al2O6∶Eu2+发光粉体的新型形貌对发光性能的影响,微波干燥法制备的均匀分散的花状形貌发光粉体发光强度高,余辉时间长达20 min.
