Nanoparticle aggregation effects on radiative heat transport of nanoliquid over a vertical cylinder with sensitivity analysis

A sensitivity analysis is performed to analyze the effects of the nanoparticle(NP)aggregation and thermal radiation on heat transport of the nanoliquids(titania based on ethylene glycol)over a vertical cylinder.The optimization of heat transfer rate and friction factor is performed for NP volume fraction(1%≤φ≤3%),radiation parameter(1≤R_(t)≤3),and mixed convection parameter(1.5≤λ≤2.5)via the facecentered central composite design(CCD)and the response surface methodology(RSM).The modified Krieger and Dougherty model(MKDM)for dynamic viscosity and the Bruggeman model(BM)for thermal conductivity are utilized to simulate nanoliquids with the NP aggregation aspect.The complicated nonlinear problem is treated numerically.It is found that the temperature of nanoliquid is enhanced due to the aggregation of NPs.The friction factor is more sensitive to the volume fraction of NPs than the thermal radiation and the mixed convection parameter.Furthermore,the heat transport rate is more sensitive to the effect of radiative heat compared with the NP volume fraction and mixed convection parameter.

Mechanism of nanoparticle aggregation in gas-liquid microfluidic mixing

Using gas-liquid segmented micromixers to prepare nanoparticles that have a homogeneous particle size, controllable shape, and monodispersity advantages. Although nanoparticle aggregation within a microfluid has been shown to be affected by the shear effect, the shear effect triggering conditions in gasliquid two-phase flow is unclear and the aggregation behavior of nanoparticles under the shear effect is difficult to predict, resulting in uncontrollable physical and chemical properties of nanoparticle aggregates. In this study, a numerical simulation of nanoparticle aggregation in gas-liquid two-phase flow under the shear effect is performed using the CFD-DEM method. Then, the effects of total flow rate,gas-liquid two-phase flow ratio, and particle volume fraction on particle aggregation were analyzed to achieve control of particle aggregation shape and size. Meanwhile, the triggering mechanism of the shear effect and the mechanism of the shear effect on the aggregation of nanoparticles were clarified. The results show that increasing the total flow rate or decreasing the gas-liquid two-phase flow rate ratio can induce the shear effect, which reduces the particle aggregation size and makes the morphology tend to be spherical. Moreover, increasing the particle volume fraction, and total flow rate or decreasing the gas-liquid two-phase flow rate ratio also increases the number of particle collisions and induce interparticle adhesion. Hence, particle adhesion and the shear effect compete with each other and together affect particle aggregation.

Significance of Nanoparticles Aggregation with Cattaneo-Christov Heat Flux on the Water and Ethylene Glycol Mixture Based MWCNTs-Nanofluid Flow over a Stretching Cylinder

This work aims to analyze the flow of electrically conducting MWCNTs-nanofluid over a stretching cylinder with the aggregation and non-aggregation effects of nanoparticles. The working fluid comprised a combination of water and ethylene glycol, with volumetric proportions of (50:50) considered. Convective boundary constraints and modified Fourier law are implemented in heat transmission assessment. The mathematical flow model is formulated in the form of PDEs and is transformed into ODEs via similarity transformation. Numerical outcomes will be obtained with the use of the bvp4c technique and will be displayed with the help of graphs and tables. The results show that the surface drag coefficient is enhanced in the case of aggregation of nanoparticles whereas heat transfer rate is enhanced in the non-aggregation effect of nanoparticles. Furthermore, the temperature distribution enhances the increasing values of particle volume fraction in the case of aggregation effects of nanoparticles whereas temperature distribution lowers in the case of non-aggregation effect of nanoparticles. .

Flow of colloidal suspension and irreversibility analysis with aggregation kinematics of nanoparticles in a microchannel

The current exploration focuses on the ethylene glycol(EG)based nanoliquid flow in a microchannel.The effectiveness of the internal heat source and linear radiation is reflected in the present investigation.The estimation of suitable thermal conductivity model has affirmative impact on the convective heat transfer phenomenon.The examination is conceded with the nanoparticle aggregation demonstrated by the Maxwell-Bruggeman and Krieger-Dougherty models which tackle the formation of nanolayer.These models effectively describe the thermal conductivity and viscosity correspondingly.The dimensionless mathematical expressions are solved numerically by the Runge Kutta Fehlberg approach.A higher thermal field is attained for the Bruggeman model due to the formation of thermal bridge.A second law analysis is carried out to predict the sources of irreversibility associated with the thermal system.It is remarked that lesser entropy generation is obtained for the aggregation model.The entropy generation rate declines with the slip flow and the thermal heat flux.A notable enhancement in the Bejan number is attained by increasing the Biot number.It is established that the nanoparticle aggragation model exhibits a higher Bejan number in comparision with the usual flow model.

Effect of TiO_2 nanoparticle aggregation on marine microalgae Isochrysis galbana

TiO2 nanoparticles（NPs） could adversely impact aquatic ecosystems. However, the aggregation of these NPs could attenuate this effect. In this work, the biological effects of TiO2 NPs on a marine microalgae Isochrysis galbana were investigated. The aggregation kinetics of TiO2 NPs under different conditions was also investigated to determine and understand these effects. Results showed that, though TiO2 NPs had no obvious impact on the size and reproducibility of algal cells under testing conditions, they caused a negative effect on algal chlorophyll, which led to a reduction in photosynthesis. Furthermore, fast aggregation of TiO2 NPs occurred under all conditions, especially at the pH close to the p Hzpc. Increasing ionic strength and NP concentration also enhanced the aggregation rate.The aggregation and the following sedimentation of TiO2 NPs reduced their adverse effects on I. galbana.

The aggregation characteristics and formation mechanism of nanoparticles in ductile shear zone

1 Introduction Nanoparticles are widely found in the ductile shear zone and it is considered to have a close relation with faulting.The sizes of these nanoparticles are generallyless than 100 nm.They have a variety of morphologies like globular structure rod-like and tubular,by the order aggregating of these nanoparticles various aggregations

The effect of silica nanoparticle aggregates on wax dissolution in diesel oil

In recent years, silica nanoparticle aggregates （SNPAs） have been used to decrease the injection pressure of wells in low permeability reservoirs achieving good results. In order to study the mechanisms for reduction in the injection pressure of low permeability wells by the SNPA-diesel oil system injection, the microstructure of SNPAs was observed with a transmission electron microscope （TEM）. The particle size distribution of SNPAs was also measured by the laser scattering method. The viscosities of diesel oil and SNPA-diesel oil system were measured with a capillary viscometer. The effect of SNPAs on the solubility of wax in the diesel oil was experimentally studied. The influencing factors, including temperature and SNPA concentration in diesel oil, on wax solubility were analyzed. A pore-throat film displacement model （PTFDM） was built for mechanism explanation. The microstructure and size distribution analyses show that the SNPAs are in the nanometer size range. The viscosity of the SNPA-diesel oil system is lower than that of the diesel oil. The solubility of wax in the diesel oil increases greatly due to SNPA addition, the solubility ratio reaches 7.5. The solubility of wax in diesel oil increases with increases in the concentration of SNPAs in the diesel oil and with the temperature. It is proved that the addition of SNPAs to diesel oil helps remove the wax deposited near the wellbore. This maybe one of the main mechanisms for injection pressure decreases in low permeability reservoirs.

A case study of aggregation behaviors of titanium dioxide nanoparticles in the presence of dodecylbenzene sulfonate in natural water

The present work aims to ascertain the mechanisms of surfactant（dodecylbenzene sulfonate; DBS） effects on the aggregation behaviors of TiO2 nanoparticles（TiO2-NPs） in natural water samples. Aggregation experiments were conducted at a TiO2-NPs concentration of 10 mg/L in deionized water and in natural water samples via dynamic light scattering and Zeta potential determination. Average attachment efficiency was calculated to compare the aggregation behaviors of nanoparticles in the two aqueous media. Results showed that the effects of DBS on aggregation could be interpreted by both Derjaguin–Landau–Verwey–Overbeek（DLVO） and non-DLVO mechanisms. In natural water samples,aggregation did not occur rapidly and was able to develop slowly under all conditions, and the roles of DBS were obvious at high DBS concentration owing to the impacts of inherent components of natural water samples, such as colloids and natural organic compounds.Future aggregation studies should concentrate on multi-factor, multi-colloidal and dynamic aspects under similar environmental conditions.

Water chemistry controlled aggregation and photo-transformation of silver nanoparticles in environmental waters

The inevitable release of engineered silver nanoparticles（Ag NPs） into aquatic environments has drawn great concerns about its environmental toxicity and safety. Although aggregation and transformation play crucial roles in the transport and toxicity of Ag NPs, how the water chemistry of environmental waters influences the aggregation and transformation of engineered Ag NPs is still not well understood. In this study, the aggregation of polyvinylpyrrolidone（PVP） coated Ag NPs was investigated in eight typical environmental water samples（with different ionic strengths, hardness, and dissolved organic matter（DOM） concentrations） by using UV–visible spectroscopy and dynamic light scattering. Raman spectroscopy was applied to probe the interaction of DOM with the surface of Ag NPs. Further, the photo-transformation and morphology changes of Ag NPs in environmental waters were studied by UV–visible spectroscopy, inductively coupled plasma mass spectrometry, and transmission electron microscopy. The results suggested that both electrolytes（especially Ca2＋and Mg2＋） and DOM in the surface waters are key parameters for Ag NP aggregation, and sunlight could accelerate the morphology change, aggregation, and further sedimentation of Ag NPs. This water chemistry controlled aggregation and photo-transformation should have significant environmental impacts on the transport and toxicity of Ag NPs in the aquatic environments.

Influences of anion concentration and valence on dispersion and aggregation of titanium dioxide nanoparticles in aqueous solutions

Dispersion and aggregation of nanoparticles in aqueous solutions are important factors for safe application of nanoparticles. In this study, dispersion and aggregation of nano-TiO2 in aqueous solutions containing various anions were investigated. The influences of anion concentration and valence on the aggregation size, zeta potential and aggregation kinetics were individually investigated. Results showed that the zeta potential decreased from 19.8 to-41.4 mV when PO4^（3-） concentration was increased from 0 to 50 mg/L, while the corresponding average size of nano-TiO2 particles decreased from 613.2 to 540.3 nm. Both SO4^（2-） and NO3^-enhanced aggregation of nano-TiO2in solution. As SO4^（2-） concentration was increased from 0 to 500 mg/L, the zeta potential decreased from 19.8 to 1.4 mV, and aggregate sizes increased from 613.2 to 961.3 nm.The trend for NO3^- fluctuation was similar to that for SO4^（2-） although the range of variation for NO3^- was relatively narrow. SO4^（2-） and NO3^-accelerated the aggregation rapidly, while PO4^（3-） did so slowly. These findings facilitate the understanding of aggregation and dispersion mechanisms of nano-TiO2 in aqueous solutions in the presence of anions of interest.

Is there a silver lining? Aggregation and photo-transformation of silver nanoparticles in environmental waters

The nanotechnology industry advances rapidly,and at the vanguard are the promising silver nanoparticles（Ag NPs）,which have diverse applications.These nanometer-sized particles have been shown to inhibit the ability of bacteria to produce adenosine triphosphate（ATP）,a molecule necessary for chemical energy transport in cells.The antimicrobial properties of Ag NPs（and Ag＋）make them valued antibacterial

Surface enhanced Raman scattering of gold nanoparticles aggregated by a gold-nanofilm-coated nanofiber

Aggregation of metal nanoparticles plays an important role in surface enhanced Raman scattering （SERS）. Here, a strategy of dynamically aggregating/releasing gold nanopartides is demonstrated using a gold-nanofilm-coated nanofiber, with the assistance of enhanced optical force and plasmonic photothermal effect. Strong SERS signals of rhodamine 6G are achieved at the hotspots formed in the inter-particle and film-partide nanogaps. The proposed SERS substrate was demonstrated to have a sensitivity of 10-12 M, reliable reproducibility, and good stability.

Complex interplay between formation routes and natural organic matter modification controls capabilities of C_(60)nanoparticles(nC_(60)) to accumulate organic contaminants

Accumulation of organic contaminants on fullerene nanoparticles（nC（60）） may significantly affect the risks of C（60） in the environment.The objective of this study was to further understand how the interplay of nC（60） formation routes and humic acid modification affects contaminant adsorption of nC（60）.Specifically,adsorption of 1,2,4,5-tetrachlorobenzene（a model nonionic,hydrophobic organic contaminant） on nC（60） was greatly affected by nC（60）formation route- the formation route significantly affected the aggregation properties of nC（60）,thus affecting the available surface area and the extent of adsorption via the pore-filling mechanism.Depending on whether nC（60） was formed via the ＂top-down＂ route（i.e.,sonicating C（60） powder in aqueous solution） or ＂bottom-up＂ route（i.e.,phase transfer from an organic solvent） and the type of solvent involved（toluene versus tetrahydrofuran）,modification of nC（60） with Suwannee River humic acid（SRHA） could either enhance or inhibit the adsorption affinity of nC（60）.The net effect depended on the specific way in which SRHA interacted with C（60） monomers and/or C（60） aggregates of different sizes and morphology,which determined the relative importance of enhanced adsorption from SRHA modification via preventing C（60） aggregation and inhibited adsorption through blocking available adsorption sites.The findings further demonstrate the complex mechanisms controlling interactions between nC（60） and organic contaminants,and may have significant implications for the life-cycle analysis and risk assessment of C（60）.

Determination of methylene blue by resonance light scattering method using silica nanoparticles as probe

A simple and novel method was developed to determine methylene blue（MB） by resonance light scattering（RLS） using silica nanoparticles（SiO2NPs） as the probe.It was found that MB could enhance the RLS intensity of SiO2NPs.Moreover,the increase in RLS intensity was linear with the concentration of MB over the range of 0.01-3.0 μg mL^-1.The limit of detection（LOD） was as low as 4.36 ng mL^-1（3σ） and the relative standard deviation（RSD） was 2.4%（n=6）.Under the optimum experimental conditions,this proposed method was successfully applied for the determination of MB in aquaculture samples with recoveries between 96.3% and 107%.Possible mechanisms for the RLS enhancement of SiO2NPs in the presence of MB were also discussed.