Improving catalyst performance by studying the preparation parameters, material structures and analysis methods is important work for catalyst researchers. In this study, Cu-Pt nanocomposites with different metal rati...Improving catalyst performance by studying the preparation parameters, material structures and analysis methods is important work for catalyst researchers. In this study, Cu-Pt nanocomposites with different metal ratios were synthesized on MWCNTs using a polyol method. The structures and morphologies of the nano hybrid catalysts were analyzed by XRD and TEM. The XRD results indicate that Pt and Cu formed a bimetallic solid solution. The average diameters of the Pt and Cu-Pt nanoparticles on MWCNTs were between 3-10 nm and 5-15 nm, respectively. The electrocatalytic behavior of methanol oxidation reactions was investigated by cyclic voltammery (CV). Cu(20%)/[Pt/MWCNTs(1:4)], which contained an optimal degree of solid solution, enhanced the methanol oxidation to the greatest degree.展开更多
基金the financial support of the Taiwan National Science Council
文摘Improving catalyst performance by studying the preparation parameters, material structures and analysis methods is important work for catalyst researchers. In this study, Cu-Pt nanocomposites with different metal ratios were synthesized on MWCNTs using a polyol method. The structures and morphologies of the nano hybrid catalysts were analyzed by XRD and TEM. The XRD results indicate that Pt and Cu formed a bimetallic solid solution. The average diameters of the Pt and Cu-Pt nanoparticles on MWCNTs were between 3-10 nm and 5-15 nm, respectively. The electrocatalytic behavior of methanol oxidation reactions was investigated by cyclic voltammery (CV). Cu(20%)/[Pt/MWCNTs(1:4)], which contained an optimal degree of solid solution, enhanced the methanol oxidation to the greatest degree.