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LARGE TIME BEHAVIOR OF GLOBAL STRONG SOLUTIONS TO A TWO-PHASE MODEL WITH A MAGNETIC FIELD 被引量:1
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作者 Wenjun WANG Zhen CHENG 《Acta Mathematica Scientia》 SCIE CSCD 2022年第5期1921-1946,共26页
In this paper,the Cauchy problem for a two-phase model with a magnetic field in three dimensions is considered.Based on a new linearized system with respect to(c−c_(∞),P−P_(∞),u,H)for constants c_(∞)≥0 and P_(∞)&... In this paper,the Cauchy problem for a two-phase model with a magnetic field in three dimensions is considered.Based on a new linearized system with respect to(c−c_(∞),P−P_(∞),u,H)for constants c_(∞)≥0 and P_(∞)>0,the existence theory of global strong solution is established when the initial data is close to its equilibrium in three dimensions for the small H^(2) initial data.We improve the existence results obtained by Wen and Zhu in[40]where an additional assumption that the initial perturbations are bounded in L^(1)-norm was needed.The energy method combined with the low-frequency and high-frequency decomposition is used to derive the decay of the solution and hence the global existence.As a by-product,the time decay estimates of the solution and its derivatives in the L^(2)-norm are obtained. 展开更多
关键词 two-phase model magnetic field strong solution global existence decay rates
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THE EFFECTS OF MAGNETIC FIELD ON TWO-PHASE LIQUID METAL FLOW 被引量:1
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作者 Rong Sheng (Institute of Mechanics,Chinese Academy of Sciences,Beijing) 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 1990年第2期128-132,共5页
In this paper,the basic equations of two-phase liquid metal flow in a magnetic field are de- rived,and specifically,two-phase liquid metal MHD flow in a rectangular channel is studied,and the expres- sions of velocity... In this paper,the basic equations of two-phase liquid metal flow in a magnetic field are de- rived,and specifically,two-phase liquid metal MHD flow in a rectangular channel is studied,and the expres- sions of velocity distribution of liquid and gas phases and the ratio K_0 of the pressure drop in two-phase MHD flow to that in single-phase are derived.Results of calculation show that the ratio K_0 is smaller than unity and decreases with increasing void fraction and Hartmann number because the effective electrical conduc- tivity in the two-phase case decreases. 展开更多
关键词 two-phase Equid metal MHD flow magnetic field VELOCITY pressure gradient void fraction Hartmann number
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Two-Phase Flow of Blood with Magnetic Dusty Particles in Cylindrical Region: A Caputo Fabrizio Fractional Model
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作者 Anees Imitaz Aamina Aamina +2 位作者 Farhad Ali Ilyas Khan Kottakkaran Sooppy Nisar 《Computers, Materials & Continua》 SCIE EI 2021年第3期2253-2264,共12页
The present study is focused on the unsteady two-phase flow of blood in a cylindrical region.Blood is taken as a counter-example of Brinkman type fluid containing magnetic(dust)particles.The oscillating pressure gradi... The present study is focused on the unsteady two-phase flow of blood in a cylindrical region.Blood is taken as a counter-example of Brinkman type fluid containing magnetic(dust)particles.The oscillating pressure gradient has been considered because for blood flow it is necessary to investigate in the form of a diastolic and systolic pressure.The transverse magnetic field has been applied externally to the cylindrical tube to study its impact on both fluids as well as particles.The system of derived governing equations based on Navier Stoke’s,Maxwell and heat equations has been generalized using the well-known Caputo–Fabrizio(C–F)fractional derivative.The considered fractional model has been solved analytically using the joint Laplace and Hankel(L&H)transformations.The effect of various physical parameters such as fractional parameter,Gr,M andγ on blood and magnetic particles has been shown graphically using the Mathcad software.The fluid behaviour is thinner in fractional order as compared to the classical one. 展开更多
关键词 two-phase blood flow dusty fluid Brinkman type model magnetic dusty particles heat transfer C-F derivative
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Manufacturing of Surface Nanostructured Fibers Featuring an Antibacterial Effect by Magnetic Field Transportation of Magnetite@Silver Core-Shell Nanoparticles
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作者 Roy Buschbeck Franziska Lüttich +6 位作者 Sebastian Spange Ronny Kocher Michael Roder Andreas Heft Bernd Grünler Arnd Schimanski Heinrich Lang 《Journal of Materials Science and Chemical Engineering》 2017年第12期1-16,共16页
Magnetic core-shell nanoparticles of type Fe3O4@Ag were synthesized in gram scale following a combined co-precipitation phase-transfer method and afterwards, processed to nanoparticle polymer (polypropylene and polyam... Magnetic core-shell nanoparticles of type Fe3O4@Ag were synthesized in gram scale following a combined co-precipitation phase-transfer method and afterwards, processed to nanoparticle polymer (polypropylene and polyamide) composites. These composites were used as sheath material for the fabrication of core-sheath fibers. During the melt spinning process, a magnetic field was applied around the roving, whereby the particles move in the still liquid sheath polymer towards the surface. The produced fiber materials were investigated by AFM showing a nanostructuring of the surface, which was indirectly confirmed by determination of a slight surface tension lowering. Nanoparticle movement was shown by cross-section SEM and EDX measurements. The antibacterial activity of the spun fibers was proven by contacting them with Escherichia coli. A long-term stability of this effect was observable by carrying out a standard washability test. In contrast to previous works this new approach uses no deposition technique to introduce surface changes. It rather applies a magnetic force to move appropriately equipped nanoparticles from the inside of the fiber to the surface. This leads in only one step to a strong superficial anchoring of the particles resulting in a unique combination of long-term stable antibacterial and improved anti-soiling effects. 展开更多
关键词 NANOCOMPOSITES Polymer Fibers Core-Shell Nanoparticles magnetic Field Treatment nanostructured Surface
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Remanence Characteristic of Nanostructure of Hard/Soft Magnetic Multilayered Systems 被引量:2
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作者 HUJing-Guo LIUJi-Wen 《Communications in Theoretical Physics》 SCIE CAS CSCD 2001年第6期740-744,共5页
The relation between microscopic properties (e.g., layer thickness, easy axis orientation) and the macroscopic magnetic properties such as remanent magnetization of the ferromagnetic multilayer system is investigated ... The relation between microscopic properties (e.g., layer thickness, easy axis orientation) and the macroscopic magnetic properties such as remanent magnetization of the ferromagnetic multilayer system is investigated based on a simple micromagnet approach. We concentrate on a multilayer design with periodic boundary condition, where alternating soft/hard layers build a nanostructured multilayer. For any easy axis direction in the soft and hard layers a simple explicit expression of remanence of the system has been derived analytically. We find that the remanence clearly depends on the thickness of the soft magnetic layer and is nearly independent of the thickness of hard magnetic layer. On the other hand, the remanence increases upon reducing the angle enclosed by the saturation magnetization and the easy axis directions of soft magnetic layer. However, it is unsensitive to the easy axis direction of hard magnetic layer, but there exists a maximum remanence for a certain easy axis direction of hard magnetic layer. 展开更多
关键词 nanostructured two-phase magnet exchange-spring behavior MICROmagnetICS REMANENCE
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Magnetic properties of nanostructural γ-Ni-28Fe alloy 被引量:1
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作者 刘银 秦晓英 丘泰 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2006年第6期1370-1373,共4页
Nanostructural γ-Ni-28Fe alloy(nano γ-Ni-28Fe)was successfully prepared by mechanochemical alloying(MCA).The relationship between the microstructure and the synthesis conditions was investigated by using XRD,TEM,SEM... Nanostructural γ-Ni-28Fe alloy(nano γ-Ni-28Fe)was successfully prepared by mechanochemical alloying(MCA).The relationship between the microstructure and the synthesis conditions was investigated by using XRD,TEM,SEM as well as BET analyzer.The results show that nano γ-Ni-28Fe alloy is composed of a gamma phase(FCC structure).Its grain size is about 20 nm at reduction temperature below 600 ℃.The magnetic measurements indicate that the saturation magnetization of nano γ-Ni-28Fe alloy is 102.4 A·m2/kg,and the coercivity is much higher than that of conventional coarse-grained counterpart.The result may be attributed to its decrease of the grain size and chemical composition in nano γ-Ni-28Fe alloy. 展开更多
关键词 nanostructural material Ni-28Fe ALLOY MECHANOCHEMICAL ALLOYING microstructure magnetIC PROPERTY
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Wave-Vector and Temperature-Dependent Electron Transport in a Magnetic Nanostructure Modulated by Bias 被引量:2
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作者 卢建夺 李云宝 +1 位作者 王玉华 侯阳来 《Communications in Theoretical Physics》 SCIE CAS CSCD 2010年第8期365-368,共4页
We theoretically investigate the wave-vector and temperature-dependent electron transport in a magneticnanostructure modulated by an applied bias.The large spin-polarization can be achieved in such a device,and the de... We theoretically investigate the wave-vector and temperature-dependent electron transport in a magneticnanostructure modulated by an applied bias.The large spin-polarization can be achieved in such a device,and the degreeof spin-polarization strongly depends on the transverse wave-vector and the temperature.These interesting propertiesmay be helpful to spin-polarize electrons into semiconductors,and this device may be used as a spin filter. 展开更多
关键词 magnetic nanostructure SPIN-POLARIZATION spin filtering
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Morphology, Size-controlled Synthesis of CoO Nanostructure and Its Magnetic Property 被引量:1
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作者 贾潇 岳芳 +2 位作者 杨光 潘海波 刘文革 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2014年第10期1472-1478,共7页
CoO nanostructures with tunable morphology and size have been prepared via a simple one-pot solvothermal synthesis. The as-prepared nanoparticles were fully characterized using X-ray diffraction(XRD), transmission e... CoO nanostructures with tunable morphology and size have been prepared via a simple one-pot solvothermal synthesis. The as-prepared nanoparticles were fully characterized using X-ray diffraction(XRD), transmission electron microscopy(TEM), field-emission scanning electron microscope(FESEM), etc. The morphology and size of the product can be easily controlled by adjusting the raw materials added. Reaction time and the solvent ratio also play important roles in the synthesis of octahedral nanostructures. The magnetic property of the as-prepared samples was also investigated. 展开更多
关键词 controlled synthesis CoO nanostructure magnetic property
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Remanence characteristic of nanostructure of hard/soft magnetic multilayered systems with random easy axis orientations 被引量:1
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作者 HU Jing-guo(Physics Department of Yangzhou University Yangzhou 225002) 《原子与分子物理学报》 CAS CSCD 北大核心 2002年第3期289-294,共6页
The macroscopic magnetic properties such as remanent magnetization of the ferromagnetic multilayer system with random easy axis orientations is investigated by using a effective micromagnet approach. The multilayer, w... The macroscopic magnetic properties such as remanent magnetization of the ferromagnetic multilayer system with random easy axis orientations is investigated by using a effective micromagnet approach. The multilayer, which alternating soft/hard layers in which their easy axis orientations is random build a nanostructured multilayer, is considered to meet periodic boundary condition, the dependence of remanence on thickness has been analytical derived. Author find that the remancence clearly depends on the thickness of the soft magnetic layer nearly independence of thickness of hard magnetic layer. this analytical results are in excellent agreement with previous numerical results. 展开更多
关键词 磁学性质 磁化强度 纳米结构 硬磁性 软磁性
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Synthesis and Characterization of Nanostructured Fe-Ni Alloy Whisker 被引量:1
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作者 DONG Guo-jun,WANG Gui-xiang,ZHANG Mi-lin,LI Ru-Min,WANG JunCollege of Chemical Engineering, Harbin Engineering University, Harbin 150001, China 《哈尔滨工程大学学报(英文版)》 2002年第2期83-86,共4页
The nanocrystalline γ-(Fe,Ni) alloy whiskers have been prepared by chemical reduction of Fe2+ and Ni2+ ions with potassium borohydride under the function of a dispersant agent PE followed by heat treatment at 600℃ u... The nanocrystalline γ-(Fe,Ni) alloy whiskers have been prepared by chemical reduction of Fe2+ and Ni2+ ions with potassium borohydride under the function of a dispersant agent PE followed by heat treatment at 600℃ under the protection of nitrogen.Conditions, such as quantity of NaOH, concentration of salts, and species of surfactants, of preparation of Fe-Ni alloy have been discussed. X-ray diffraction(XRD), transmission electron microscopy(TEM) and vibrating sample magnetometer(VSM) characterized the synthesized Fe-Ni alloy. Character, capability and use of the materials have been summarized. 展开更多
关键词 WHISKER FE-NI ALLOY nanostructured MATERIALS magnetIC MATERIALS
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The electron transport characters in a nanostructure with the periodic magnetic-electric barriers
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作者 卢建夺 邵亮 +1 位作者 侯阳来 戴厚梅 《Chinese Physics B》 SCIE EI CAS CSCD 2007年第10期3080-3086,共7页
This paper detailedly studies the transmission probability, the spin polarization and the conductance of the ballistic electron in a nanostrueture with the periodic magnetic-electric barriers These observable quantit... This paper detailedly studies the transmission probability, the spin polarization and the conductance of the ballistic electron in a nanostrueture with the periodic magnetic-electric barriers These observable quantities are found to be strongly dependent not only on the magnetic configuration, the incident electron energy and the incident wave vector, but also on the number of the periodic magnetic-electric barriers The transmission coefficient and the spin polarization show a periodic pattern with the increase of the separation between two adjacent magnetic fields, and the resonance splitting increases as the number of periods increases. Surprisingly, it is found that a polarization can be achieved by spin-dependent resonant tunnelling in this structure, although the average magnetic field of the structure is zero. 展开更多
关键词 magnetic nanostructure spin polarization resonance splitting wave-vector filtering
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Manipulating magnetic anisotropy and ultrafast spin dynamics of magnetic nanostructures
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作者 成昭华 何为 +6 位作者 张向群 孙达力 杜海峰 吴琼 叶军 房亚鹏 刘郝亮 《Chinese Physics B》 SCIE EI CAS CSCD 2015年第7期3-22,共20页
We present our extensive research into magnetic anisotropy. We tuned the terrace width of Si(111) substrate by a novel method: varying the direction of heating current and consequently manipulating the magnetic ani... We present our extensive research into magnetic anisotropy. We tuned the terrace width of Si(111) substrate by a novel method: varying the direction of heating current and consequently manipulating the magnetic anisotropy of magnetic structures on the stepped substrate by decorating its atomic steps. Laser-induced ultrafast demagnetization of a Co FeB/MgO/CoFeB magnetic tunneling junction was explored by the time-resolved magneto-optical Kerr effect(TRMOKE) for both the parallel state(P state) and the antiparallel state(AP state) of the magnetizations between two magnetic layers. It was observed that the demagnetization time is shorter and the magnitude of demagnetization is larger in the AP state than those in the P state. These behaviors are attributed to the ultrafast spin transfer between two CoFeB layers via the tunneling of hot electrons through the MgO barrier. Our observation indicates that ultrafast demagnetization can be engineered by the hot electron tunneling current. This opens the door to manipulate the ultrafast spin current in magnetic tunneling junctions. Furthermore, an all-optical TR-MOKE technique provides the flexibility for exploring the nonlinear magnetization dynamics in ferromagnetic materials, especially with metallic materials. 展开更多
关键词 magnetic anisotropy ultrafast spin dynamics magnetic nanostructures
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Magnetic and optical properties of zinc chromite nanostructures prepared by microwave method
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作者 Zahra MOUSAVI Mahdiyeh ESMAEILI-ZARE Masoud SALAVATI-NIASARI 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第12期3980-3986,共7页
The nanostructures of zinc chromite(Zn Cr2O4) were fabricated by the microwave method. It was shown that the well-crystallized spinel structure is formed after annealing at 700 °C. The influence of reaction tim... The nanostructures of zinc chromite(Zn Cr2O4) were fabricated by the microwave method. It was shown that the well-crystallized spinel structure is formed after annealing at 700 °C. The influence of reaction time and irradiation power of oven on the size and shape of the as-prepared Zn Cr2O4 samples was studied. The synthesized samples were characterized by X-ray diffraction(XRD), scanning electron microscopy(SEM), energy dispersive X-ray(EDX), transmission electron microscopy(TEM), diffuse reflectance spectroscopy(DRS), photoluminescence(PL) spectroscopy, Fourier transform infrared(FTIR) spectra and vibrating sample magnetometry(VSM), respectively. The optical band gap calculated using DRS was found to be 3.50 e V for Zn Cr2O4 nanostructures. Photoluminescence measurements also confirmed this result. 展开更多
关键词 zinc chromite nanostructurES superhydrophilicty magnetic property optical property
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Electronic Resonant Splitting in a Nanostructure with Periodic Magnetic-Electric Barriers
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作者 LU Jian-Duo 《Communications in Theoretical Physics》 SCIE CAS CSCD 2008年第3期783-785,共3页
In this letter, the transmission probability and the conductance of the ballistic electron are studied in a nanostructure with the periodic magnetic-electric barriers. We find that the resonant splitting increases wit... In this letter, the transmission probability and the conductance of the ballistic electron are studied in a nanostructure with the periodic magnetic-electric barriers. We find that the resonant splitting increases with the number of periods increasing, so the number of the resonant peaks increases and the peaks become sharper. For the m-th periodic magnetic-electric barriers tunneling the splitting is (m - 1)-fold. 展开更多
关键词 magnetic nanostructure resonant splitting magnetic-electronic barriers
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Fluorescent Superparamagnetic Core-Shell Nanostructures: Facile Synthesis of Fe@C-CN<sub>x</sub>Particles for Reusable Photocatalysts
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作者 Sankaran Murugesan Oleksandr Kuznetsov +1 位作者 Zhou Zhou Valery Khabashesku 《Advances in Nanoparticles》 2019年第1期1-19,共19页
Synthesis and characterization of hybrid fluorescent superparamagnetic core-shell particles of Fe@C-CNx composition are presented for the first time. The prepared Fe@C-CNx hybrid nanoparticles were found to possess mu... Synthesis and characterization of hybrid fluorescent superparamagnetic core-shell particles of Fe@C-CNx composition are presented for the first time. The prepared Fe@C-CNx hybrid nanoparticles were found to possess multifunctionality by exhibiting strong superparamagnetic properties and bright fluorescence emissions at 500 nm after the excitation with light in the UV-visible range. Fe@C-CNx also exhibits photocatalytic activities for organic dye degradation comparable to pure amorphous CNx with reusability through magnetic separation. The combination of magnetic and fluorescent properties of core-shell Fe@C-CNx nanoparticles opens opportunities for their application as sensors and magnet manipulated reusable photocatalysts. Superparamagnetic Fe@C core-shell nanoparticles were used as the template material in the synthesis, where the carbon shell was functionalized through one-step free-radical addition of alkyl groups terminated with carboxylic acid moieties. The method utilizes the organic acyl peroxide of dicarboxylic acid (succinic acid peroxide) as a non-oxidant functional free radical precursor for functionalization. Further, covalently functionalized succinyl-Fe@C core-shell nanoparticles were coated with the amorphous carbon nitride (CNx) generated by an in-situ solution-based chemical reaction of cyanuric chloride with lithium nitride. A detailed physicochemical characterization of the microstructure, magnetic and fluorescence properties of the synthesized hybrid nanoparticles is provided. 展开更多
关键词 magnetic Nanoparticles CORE-SHELL nanostructurES Fe@C-CNx Fluorescence PHOTOCATALYSTS
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First-principles study of electronic and magnetic properties of Fe atoms on Cu_(2)N/Cu(100)
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作者 陈佳乐 胡军 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第8期498-503,共6页
First-principles calculations were conducted to investigate the structural,electronic,and magnetic properties of single Fe atoms and Fe dimers on Cu_(2)N/Cu(100).Upon adsorption of an Fe atom onto Cu_(2)N/Cu(100),robu... First-principles calculations were conducted to investigate the structural,electronic,and magnetic properties of single Fe atoms and Fe dimers on Cu_(2)N/Cu(100).Upon adsorption of an Fe atom onto Cu_(2)N/Cu(100),robust Fe-N bonds form,resulting in the incorporation of both single Fe atoms and Fe dimers within the surface Cu_(2)N layer.The partial occupancy of Fe-3d orbitals lead to large spin moments on the Fe atoms.Interestingly,both single Fe atoms and Fe dimers exhibit in-plane magnetic anisotropy,with the magnetic anisotropy energy(MAE)of an Fe dimer exceeding twice that of a single Fe atom.This magnetic anisotropy can be attributed to the predominant contribution of the component along the x direction of the spin-orbital coupling Hamiltonian.Additionally,the formation of Fe-Cu dimers may further boost the magnetic anisotropy,as the energy levels of the Fe-3d orbitals are remarkably influenced by the presence of Cu atoms.Our study manifests the significance of uncovering the origin of magnetic anisotropy in engineering the magnetic properties of magnetic nanostructures. 展开更多
关键词 magnetic nanostructures magnetic anisotropy spin–orbital coupling ultrathin substrate
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Structural characteristics and magnetic properties of bulk nanocrystalline Fe_(84)Zr_2Nb_4B_(10) alloy prepared by mechanical alloying and spark plasma sintering consolidation 被引量:7
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作者 Tang, Cuiyong Xiao, Zhiyu +3 位作者 Luo, Fei Wang, Jun Ma, Chunyu Zhang, Wen 《Rare Metals》 SCIE EI CAS CSCD 2012年第3期255-259,共5页
Magnetic properties of Fe84Zr2Nb4B10 sample were investigated. The sample was produced from nanocrystalline powders made by the mechanical alloying (MA) and consolidation using the spark plasma sintering (SPS) techniq... Magnetic properties of Fe84Zr2Nb4B10 sample were investigated. The sample was produced from nanocrystalline powders made by the mechanical alloying (MA) and consolidation using the spark plasma sintering (SPS) technique. Effects of milling time on phase transformation, structural characteristics, and magnetic properties of powders were examined by X-ray diffraction (XRD), scanning electron microscopy (SEM), and physical property measure system (PPMS), respectively. Results show that nanostructured α-Fe supersaturated solid solution is obtained in the final MAed products. The saturation magnetization (Ms) increased with increasing milling time and became constant at 130 h, but the coercivity (Hc) increased firstly and then decreased. The consolidated bulk sample exhibited a high density of 6.893 g·cm-3, there was no phase change during SPS process, and the saturation magnetization and susceptibility of the SPSed bulk sample improved in comparison with the milled powders. The variation of magnetic parameters can be explained by nano-scale effect and Herzer model. 展开更多
关键词 mechanical alloying nanostructured materials SINTERING magnetIZATION
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Layer resolved magnetization reversal study in SmCo_5 /Fe nanocomposite bilayers 被引量:2
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作者 F.Shahzad S.A.Siddiqi +5 位作者 M.Y.Im A.Avallone P.Fischer Z.Hussain I.Siddiqi F.Hellman 《Chinese Physics B》 SCIE EI CAS CSCD 2010年第3期528-532,共5页
A hard/soft SmCo5/ Fe nanocomposite magnetic bilayer system is fabricated on x-ray transparent 100-200 nm thin SiaN4 films by magnetron sputtering. The microscopic magnetic domain pattern and its behaviours during mag... A hard/soft SmCo5/ Fe nanocomposite magnetic bilayer system is fabricated on x-ray transparent 100-200 nm thin SiaN4 films by magnetron sputtering. The microscopic magnetic domain pattern and its behaviours during magnetization reversal in the hard and the soft magnetic phases are studied separately by element specific magnetic soft x-ray microscopy at a spatial resolution of better than 25 Nm. We observe that the domain patterns for the soft and hard phases show coherent behaviours in varying magnetic fields. We derive local M(H) curves from the images of Fe and SmCo5 separately and find the switches for hard and soft phases to be the same. 展开更多
关键词 MULTILAYERS x-ray microscopes magnetic properties of nanostructures
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Structure and Magnetic Properties of Fe1-xCx Solid Solution Prepared by Mechanical Alloying 被引量:2
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作者 许士跃 张金仓 +3 位作者 钟敏建 陈杭德 张正明 何正明 《Journal of Shanghai University(English Edition)》 CAS 2005年第6期550-556,共7页
Supersaturated solid solutions Fe1-xCx (0≤x≤0.9 ) of wide composition range have been prepared by mechanical alloying process. Nanocrystalline phase was formed for 0 ≤ x ≤ 0.67 and a large grain phase for 0.75 ... Supersaturated solid solutions Fe1-xCx (0≤x≤0.9 ) of wide composition range have been prepared by mechanical alloying process. Nanocrystalline phase was formed for 0 ≤ x ≤ 0.67 and a large grain phase for 0.75 ≤ x ≤ 0.9. The large fraction of graphite volume puts off formation of nanocrystalline phase for high carbon content. In the large grain phase, magnetization follows simple magnetic dilution, and eoereivity He is mainly due to dissolution of carbon at grain boundaries. In the nanocrystalline phase the alloying effect of carbon is revealed by a distinct reduction of average magnetic moment. The increasing lattice constant with increasing carbon content is observed for x ≤ 0.5, suggesting that the high carbon concentration may enhance diffusion of carbon into the Fe lattice. It shows a discontinuity in the Hc variation with a grain size D of nanocrystalline phase. For small grain D below the critical value, Hc increases with D. For a large grain D, Hc decreases with increasing D. The solubility limit of carbon in a-Fe extended by nanocry- stalline phase formation is discussed. 展开更多
关键词 mechanical alloying transition metal alloys and compounds magnetIZATION nanostructured materials
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Structure,morphology and opto-magnetic properties of Bi_2MoO_6 nano-photocatalyst synthesized by sol-gel method 被引量:4
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作者 V.UMAPATHY A.MANIKANDAN +2 位作者 S.ARUL ANTONY P.RAMU P.NEERAJA 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第10期3271-3278,共8页
Bismuth molybdate (Bi2MoO6) nano-particles (NPs) were synthesized using bismuth nitrate, ammonium molybdate, citric acid and ethyl cellulose by a simple sol-gel method. The structure, morphology, opto-magnetic and... Bismuth molybdate (Bi2MoO6) nano-particles (NPs) were synthesized using bismuth nitrate, ammonium molybdate, citric acid and ethyl cellulose by a simple sol-gel method. The structure, morphology, opto-magnetic and photocatalytic properties of the obtained powder were characterized by X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectra, high resolution scanning electron microscopy (HRSEM), energy dispersive X-ray (EDX), ultraviolet-visible diffuse reflectance spectra (DRS), photoluminescence (PL) spectra and vibrating sample magnetometer (VSM) techniques. The XRD, FT-IR and EDX results indicate that the resultant powder is pure and single phase crystalline Bi2MoO6 with orthorhombic structure. The HRSEM image shows that the morphology of obtained powder consists with well defined nano-particles structure. The VSM results show superparamagnetic behavior of the obtained nano-particles. The photocatalytic activity of Bi2MoO6 nano-particles was performed. The addition of TiO2 catalyst enhances the photocatalytic activity of Bi2MoO6 nano-particles. The catalysts Bi2MoO6, TiO2 and mixed oxide catalyst Bi2MoO6-TiO2 nano-composites (NCs) were tested for the photocatalytic degradation (PCD) of 4-chlorophenol (4-CP). It is found that the PCD efficiency of Bi2MoO6-TiO2 NCs is higher than that of pure Bi2MoO6 and TiO2 catalysts. 展开更多
关键词 Bi2MoO6 nanostructurE sol-gel synthesis optical properties magnetic properties PHOTOCATALYST
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