Assessment of the Heavy Metals and Natural Radioactivity in Phosphate Mines and Occupational Health Effects at Some Egyptian Regions

In this work, the specific activities of natural radionuclides, namely 238U series, 232Th series and 40K, have been measured in collected sedimentary phosphate deposits samples from El-Hamraween, El-Quser and Safaga phosphate mines in Egypt. HPGe γ-spectrometry was used. This study was undertaken to estimate the radiation hazard indices in phosphate mining at the studied mines on their occupational workers, to establish correlation relationships between the some measured heavy metals such as As, Cd and Pb in blood workers and their concentration in phosphate rock ores and to determinate the biomarkers in the blood workers such as malondialdehyde (MDA) and superoxide dismutase (SOD). The phosphate mine sample of El-Hamrawein has the lowest activity concentration of 226Ra, 232Th and 40K in comparison to the phosphate mine samples of El-Quseir and Safaga (El-Hamrawein kg-1, 122.4 to 188.3 Bq·kg-1 and 115.4 to 165.8 Bq·kg-1 for Safaga, El-Quseir and El-Hamrawein, respectively. For 232Th activity concentrations varied from 135.6 to 212.3 Bq·kg-1, 112.8 to 167.4 Bq·kg-1 and 132.8 to 188.6 Bq·kg-1 for Safaga, El-Quseir and El-Hamrawein, respectively. For 40K activity concentrations varied from 225.2 to 312.8 Bq·kg-1, 168.7 to 268.9 Bq·kg-1 and 95.2 to 155.8 Bq·kg-1 for Safaga, El-Quseir and El-Hamrawein, respectively. The workers of old ages have higher concentration of the investigated heavy metals than those of young ages. There is a good relation between the concentration of the investigated metals in phosphate mine samples and their concentration in blood of the occupational workers in these mines.

Assessment of Radioactivity in Borehole Waters of the North Riviera Sodeci Catchment Field in Abidjan, Côte d’Ivoire

The radioactive isotopes of the decay series of uranium-238 (238U), thorium-232 (232Th) and potassium-40 (40K) occur naturally in varying amounts in groundwater. They are the subject of many measures, mainly because of the risk they represent from a public health point of view. The purpose of this study is to measure the radioisotope content of borehole waters from the north riviera (NR) catchment field of the Ivorian drinking water distribution company (SODECI). These measurements will make it possible to assess the absolute levels of radioisotopes in the water from SODECI’s boreholes used directly for drinking or swimming, and possibly the associated risk from a public health point of view. To achieve this, a sampling campaign from the seven functional boreholes and the control or treatment tower took place in July 2018 at the NR well field. The analysis of radionuclides by gamma spectrometry was carried out in the laboratory of the Radiation Protection Institute (RPI) of the Ghana Atomic Energy Commission (GAEC). The naturally occurring radionuclides identified during the borehole water samples analysis are 238U, 232Th, and 40K. The results reveal that the specific activities of uranium vary from 0.45 ± 0.18 Bq/L to 0.55 ± 0.17 Bq/L with an average of 0.49 ± 0.15 Bq/L. Those of thorium vary from 0.66 ± 0.14 Bq/L to 0.78 ± 0.18 Bq/L with an average of 0.72 ± 0.16 Bq/L and potassium of 4.14 ± 0.53 Bq/L at 5.87 ± 0.60 Bq/L with an average of 5.32 ± 0.58 Bq/L.

Altitude-dependent distribution of 137Cs in the environment:a case study of Aragats massif, Armenia

This paper considers the distribution of technogenic 137Cs and naturally occurring radionuclides:238 U,232 Th and40 R concentrations in soils and 137Cs in atmospheric dry depositions by altitudinal belts of the Aragats mountain massif,Republic of Armenia.Undisturbed soil samples were collected at altitudes from 1000 to 3200 m.For the determination of geochemical variability,two soil sampling campaigns were undertaken.Atmospheric dry depositions were sampled from five stations at1100-3200 m collected onto organic fiber filters between June and December 2016.137Cs activity was measured using a high-purity Germanium detector coupled to a multichannel analyzer(Canberra).Results indicated that specific activity of 137Cs in soils at 1000 m is495-528 Bq m^-2,andat3200 mis10,500-11,470 Bq m^-2.No correlation observed for 137Cs versus naturally occurring radionuclides,which varies in distribution by altitude.Specific activities of 137Cs in dry atmospheric depositions varies from 1.06 at 846 m to2.37 Bq m^-2 per quarter at 3200 m and increases as the altitude increases.Activities of 137Cs in soil and dry atmospheric deposition correlated significantly,and 137Cs activity in soils and atmospheric dry depositions decrease as the absolute altitude decreases.The 50-year effective dose from exposure to 137Cs fallout varies with altitude from 0.007 to 1.42 m Sv.