Diverse models have been proposed for the role of the Tarim Craton within the Paleoproterozoic Columbia supercontinent assembly. Here we report a suite of-1.71 Ga Nb-enriched meta-gabbro lenses in the eastern Quanji M...Diverse models have been proposed for the role of the Tarim Craton within the Paleoproterozoic Columbia supercontinent assembly. Here we report a suite of-1.71 Ga Nb-enriched meta-gabbro lenses in the eastern Quanji Massif, within the Tarim Craton in NW China. The meta-gabbroic rocks have Nb contents of 11.5-16.4 ppm with Nb/La ratios varying from 0.84 to 1.02((Nb/La)_N = 0.81-0.98) and Nb/U ratios from 38.0 to 47.2. They show low SiO_2(45.1-48.5 wt.%) and MgO(5.96-6.81 wt.%) and Mg#(Mg# = Mg/(Mg + Fe) = 43.5-47.7), high FeO^t(13.0-15.7 wt.%) and moderate Ti02(1.70-2.51 wt.%).with tholeiitic affinities. These rocks possess low fractionated REE patterns without obvious Eu anomalies(Eu/Eu~* = 0.87-1.02). Their primitive mantle-normalized elements patterns display significant Zr-Hf troughs, positive Nb anomalies, weak negative Ti and P anomalies, and high contents of Rb and Ba,resembling Nb-enriched basalts generated in arc-related tectonic settings. Their arc-like geochemical signatures together with whole rock εNd(t) values of 0.4-2.1 and corresponding old T_(DM)(2.22-2.37 Ga)as well as(^(143)Nd/^(144)Nd)_t and(^(87)Sr/^(86)Sr)t(t = 1712 Ma) values of 0.5104-0.5105 and 0.7030-0.7058,respectively, suggest that their precursor magma originated from mantle wedge peridotite metasomatised by subduction-derived melts. The results from our study reveal subduction along the eastern periphery of the Tarim Craton and marginal outgrowth continuing to ~1.7 Ga within the Columbia supercontinent.展开更多
Melting of subducting oceanic lithosphere and associated melt-mantle interactions in convergent plate margins require specific geodynamic environment that allows the oceanic slab to be abnormally heated.Here we focus ...Melting of subducting oceanic lithosphere and associated melt-mantle interactions in convergent plate margins require specific geodynamic environment that allows the oceanic slab to be abnormally heated.Here we focus on the Early Mesozoic mafic rocks and granite porphyry,which provide insights into slab melting processes associated with final closure of the Paleo-Asian Ocean.The granite porphyry samples are calc-alkaline and distinguished by high Sr contents,strong depletion of heavy rare earth elements,resulting in high(La/Yb);and Sr/Y ratios,and negligible Eu anomalies.Based on their high Na_(2)O and Mg O,low K_(2)O contents,positiveε_(Hf)(t)andε_(Nd)(t)and low(^(87)Sr/^(86)Sr)ivalues,we propose that the granite porphyry was likely derived from partial melting of subducting Paleo-Asian oceanic crust.The Nb-enriched mafic rocks are enriched in Rb,Th,U,Pb and K,and depleted in Nb,Ta,Ba,P and Ti,corroborating a subduction-related origin.Their heterogeneous Sr-Nd-Hf-O isotopic compositions and other geochemical features suggest that they were likely derived from partial melting of peridotitic mantle wedge interacted with oceanic slab-derived adakitic melts.Trace element and isotope modeling results and elevated zirconδ^(18)O values suggest variable subducting sediments input into the mantle wedge,dominated by terrigenous sediments.Synthesizing the widely-developed bimodal rock associations,conjugated dikes,thermal metamorphism,tectonic characteristics,paleomagnetic constraints,and paleogeographical evidence along the Solonke-Changchun suture zone,we identify a slab window triggered by slab break-off,which accounts for slab melting and formation of the Nb-enriched mafic rocks and associated adakitic granite porphyry in southeastern Central Asian Orogenic Belt.展开更多
The Duolong mineral district in western Tibet is one of the largest porphyry Cu–Au deposit fields with significant metallogenic potential in China.Its tectonic environment relevant to Early Cretaceous Cu–Au minerali...The Duolong mineral district in western Tibet is one of the largest porphyry Cu–Au deposit fields with significant metallogenic potential in China.Its tectonic environment relevant to Early Cretaceous Cu–Au mineralization remains controversial.Here we report new whole-rock major and trace element,and Sr-Nd-Hf-Pb isotopic data for the newly discovered basalt in the Nadun area,Duolong mineral district,to decipher their genesis and further constrain the tectonic environment.A contemporaneous rhyolite sample interbedded with the basalt in the lower part of the volcanic section in the Nadun area yields an LA-ICP-MS zircon U–Pb age of 122.5±1.2 Ma.The basalt samples exhibit high-K calc-alkaline/shoshonite properties and are enriched in high field strength elements,e.g.,high Ti O_(2)(1.43–1.79 wt.%)and Nb(14.6–19.5 ppm)contents,with high Nb/La ratios(0.4–0.6),which are compositionally comparable to those of Nb-enriched arc basalts(NEABs).The(^(87) Sr/^(86) Sr)iratios of 0.7052 to 0.7056,negative eNd(t)(-0.7 to-0.2)and eHf(t)values(+6.0 to+6.5),and high(^(206) Pb/^(204)Pb)i,(^(207) Pb/^(204)Pb)i,(^(208) Pb/^(204)Pb)iand ratios(18.522 to 18.561,15.641 to 15.645 and 38.679 to 38.730,respectively)suggest that the Nadun NEABs are more enriched than those of the island arc basalts(IABs)in the area.The slightly enriched radiogenic isotopes for the Nadun NEABs indicate that the subducting sediments play an important role in the source.Furthermore,their high Nb,Ti,and Cu contents indicate that the source mantle wedge was metasomatized by slab melts.The Nadun NEAB and other coeval magmatic rocks in the Duolong mineral district,including adakite,OIB-like basalt,MORB-type basalt,A-type rhyolite,and common IAB,are typical rock assemblages of ridge subduction.We infer that the Duolong mineral district were formed by ridge subduction in the Early Cretaceous.展开更多
The present work is a petrological study of the gabbroic rocks of wadi Shianite Southeastern Desert of Egypt. Chemical analyses for major and trace elements showed that there are 3 main gabbro types. These are: 1)?pyr...The present work is a petrological study of the gabbroic rocks of wadi Shianite Southeastern Desert of Egypt. Chemical analyses for major and trace elements showed that there are 3 main gabbro types. These are: 1)?pyroxene hornblende gabbronorite;?2) hornblende gabbro;?and 3) anorthosite.?The opaque minerals study of the gabbroic rocks showed that they composed mainly of ilmenite, magnetite and sulphides. The present gabbroic rocks work are related to calc-alkaline magma type, similar to the younger gabbros in other areas in the Eastern Desert.展开更多
A series ophiolitic massifs in the northeastern part of Cuba are generally considered to be relics of proto-Caribbean or Caribbean lithosphere, emplaced during Paleogene collision of the NW Caribbean and North America...A series ophiolitic massifs in the northeastern part of Cuba are generally considered to be relics of proto-Caribbean or Caribbean lithosphere, emplaced during Paleogene collision of the NW Caribbean and North American plates(Iturralde-Vinent et al., 2016). However, neither their age nor their geodynamic settings are well constrained. They are generally considered to be Creataceous in age but they have been interpreted as having formed in a back-arc basin, forearc basin or plume setting(e.g. Giunta et al., 2009;Marchesi et al., 2016;Kerr et al., 1999). The Moa-Baracoa ophiolitic massif consists of mantle harzburgite, a Moho transition zone, layered and isotropic gabbro, and pillow basalts. The isotropic gabbros, collected west of Moa(20°35′17.99″N, 75°02′56.58″W), are composed mainly of subhedral plagioclase and subhedral to euhedral clinopyroxene with minor primary brown amphibole. The plagioclase grains are fresh, whereas the clinopyroxene very weakly altered and partly replaced by secondary amphibole. Cathodoluminescence(CL) images of zircon grains separated from isotropic gabbro display oscillatory zoning and broad zoning, analogous to typical igneous zircon in gabbro. Ten zircon grains with oscillatory zoning in CL images yielded a mean U-Pb SHRIMP age of 136.7±1.8 Ma. Isotropic gabbro samples have low SiO2(47.22 wt%–49.25 wt%), TiO2(0.13 wt%–0.26 wt%) and K2O(0.04 wt%–0.08 wt%) and high MgO(8.22 wt%–16.72 wt%), Cr(1337–2065 μg/g) and Ni(192–507 μg/g) contents. Their CaO, Al2O3 and Na2O contents vary from 13.56 wt% to 15.78 wt%, 14.98 wt % to 21.98 wt %, and 0.71 wt % to 1.87 wt %, respectively. In the SiO2 versus Zr/TiO2*0.0001 diagram, the samples plot in the sub-alkaline basalt field but show calcalkaline affinities in the FeOT/MgO vs. SiO2 diagram. The gabbros contain low REE contents(∑REE = 4.71–7.71), and their chondrite normalized REE patterns show very weak depletion in light REE(LREE,(La/Yb)N = 0.34–0.50) and flat heavy REE(HREE,(Gd/Yb)N = 1.02–1.15) profiles, with slightly positive Eu anomalies(Eu/Eu* = 1.55–1.76) suggesting magmatic accumulation of plagioclase. Furthermore, all samples are depleted in Nb and Th, and enriched in Ba, Pb and Sr in the primitive mantle-normalized trace element diagram. Geochemical features, such as high values of Ba/La(30–38) and low Th/Yb(0.02–0.03), medium values of(Ta/La)PM(0.30–0.35)and(Hf/Sm)PM(0.58–0.80), indicate enrichment by slab-derived fluids and subduction-related metasomatism. These isotropic gabbros are geochemically comparable with those of the Kermanshah and Neyriz ophiolites of Iran(Monsef et al., 2018) that are thought to have originated in a SSZ environment. Therefore, we suggest that the isotropic gabbros in the MoaBaracoa massif crystallized from early Cretaceous SSZ magmas that were most likely derived from a mantle source metasomatized by slab fluids in a suprasubduction zone environment.展开更多
The Rif Mountain located in Northern Morocco represents the westernmost extremity of the Peri-Mediterranean Alpine orogenic system.This belt is classically subdivided into:1)Internal zones(or Internal Rif which is an ...The Rif Mountain located in Northern Morocco represents the westernmost extremity of the Peri-Mediterranean Alpine orogenic system.This belt is classically subdivided into:1)Internal zones(or Internal Rif which is an allochthonous metamorphic domain known worldwide thanks to the presence of large peridotite outcrops);2)flysch zones(sediments corresponding to the original cover of the Maghrebian Tethys);and 3)External zones(or External Rif representing the North African margin remnants).The External Rif is itself subdivided into Prerif,Mesorif and Intrarif domains from the South to the North and is composed by Upper Triassic to Cenozoic sediments structured in a nappe stack.Mafic rock intrusions were reported in this External Rif since the preliminary geological studies even if they were wrongly mapped as"granites".Later careful fieldwork and mapping studies specified nevertheless their gabbroic nature.A more recent petrological and geochemical study of a few outcrops of those gabbroic intrusions conducted the corresponding authors,encouraged by the presence of ultramafic rocks(Beni Malek serpentines)in the eastern part of the External Rif to consider those gabbros as oceanic and so,associated to"an ophiolitic suture".Nevertheless,a recent and extended survey on the architecture and the rifting history of the Mesozoic margin of the Maghrebian Tethys focusing mainly on the Mesorif domain favor another interpretation.The detailed petrography of those mafic intrusions(mainly gabbros+dolerites and rarely extrusive rocks);their geochemical fingerprints and mainly their geochronological data(ages around 200 Ma based on U-Pb zircon LA-ICP dating)all together indicate clearly that those mafic intrusions are rather a"newly discovered"manifestation of the Central Atlantic Magmatic Province activity"CAMP"in the External Rif belt.The CAMP magmatism has been largely well described and characterized in all the other geological domains of Morocco(Anti-Atlas,High Atlas,Middle Atlas and Meseta)but never described until the date in the Rif belt which highlights the importance of the results reported here.展开更多
基金supported by the National Science Foundation of ChinaNSFC grants(Grant Nos.41602056,41372075,41172069)+1 种基金the China Postdoctoral Science Foundation(Grant No.2016M590729)the Fundamental Research Funds for National Universities,China University of Geosciences(Wuhan)(Grant No.CUG160846)
文摘Diverse models have been proposed for the role of the Tarim Craton within the Paleoproterozoic Columbia supercontinent assembly. Here we report a suite of-1.71 Ga Nb-enriched meta-gabbro lenses in the eastern Quanji Massif, within the Tarim Craton in NW China. The meta-gabbroic rocks have Nb contents of 11.5-16.4 ppm with Nb/La ratios varying from 0.84 to 1.02((Nb/La)_N = 0.81-0.98) and Nb/U ratios from 38.0 to 47.2. They show low SiO_2(45.1-48.5 wt.%) and MgO(5.96-6.81 wt.%) and Mg#(Mg# = Mg/(Mg + Fe) = 43.5-47.7), high FeO^t(13.0-15.7 wt.%) and moderate Ti02(1.70-2.51 wt.%).with tholeiitic affinities. These rocks possess low fractionated REE patterns without obvious Eu anomalies(Eu/Eu~* = 0.87-1.02). Their primitive mantle-normalized elements patterns display significant Zr-Hf troughs, positive Nb anomalies, weak negative Ti and P anomalies, and high contents of Rb and Ba,resembling Nb-enriched basalts generated in arc-related tectonic settings. Their arc-like geochemical signatures together with whole rock εNd(t) values of 0.4-2.1 and corresponding old T_(DM)(2.22-2.37 Ga)as well as(^(143)Nd/^(144)Nd)_t and(^(87)Sr/^(86)Sr)t(t = 1712 Ma) values of 0.5104-0.5105 and 0.7030-0.7058,respectively, suggest that their precursor magma originated from mantle wedge peridotite metasomatised by subduction-derived melts. The results from our study reveal subduction along the eastern periphery of the Tarim Craton and marginal outgrowth continuing to ~1.7 Ga within the Columbia supercontinent.
基金financially supported by the National Natural Science Foundation of China(Grant 41872056)Graduate Innovation Fund of Jilin University(Grant No.101832020CX196)。
文摘Melting of subducting oceanic lithosphere and associated melt-mantle interactions in convergent plate margins require specific geodynamic environment that allows the oceanic slab to be abnormally heated.Here we focus on the Early Mesozoic mafic rocks and granite porphyry,which provide insights into slab melting processes associated with final closure of the Paleo-Asian Ocean.The granite porphyry samples are calc-alkaline and distinguished by high Sr contents,strong depletion of heavy rare earth elements,resulting in high(La/Yb);and Sr/Y ratios,and negligible Eu anomalies.Based on their high Na_(2)O and Mg O,low K_(2)O contents,positiveε_(Hf)(t)andε_(Nd)(t)and low(^(87)Sr/^(86)Sr)ivalues,we propose that the granite porphyry was likely derived from partial melting of subducting Paleo-Asian oceanic crust.The Nb-enriched mafic rocks are enriched in Rb,Th,U,Pb and K,and depleted in Nb,Ta,Ba,P and Ti,corroborating a subduction-related origin.Their heterogeneous Sr-Nd-Hf-O isotopic compositions and other geochemical features suggest that they were likely derived from partial melting of peridotitic mantle wedge interacted with oceanic slab-derived adakitic melts.Trace element and isotope modeling results and elevated zirconδ^(18)O values suggest variable subducting sediments input into the mantle wedge,dominated by terrigenous sediments.Synthesizing the widely-developed bimodal rock associations,conjugated dikes,thermal metamorphism,tectonic characteristics,paleomagnetic constraints,and paleogeographical evidence along the Solonke-Changchun suture zone,we identify a slab window triggered by slab break-off,which accounts for slab melting and formation of the Nb-enriched mafic rocks and associated adakitic granite porphyry in southeastern Central Asian Orogenic Belt.
基金supported by the National Natural Science Foundation of China(Grant Nos.42002235,41803002)the National Key R&D Program of China(2016YFC0600408)+3 种基金the China Postdoctoral Science Foundation(Grant Nos.2019M652495,2018M642708)the Taishan Scholar Program of Shandong(ts201712075)the Ao Shan Talents Cultivation Program Supported by Qingdao National Laboratory for Marine Science and Technology(2017ASTCP-OS07)the Pilot National Laboratory for Marine Science and Technology(Qingdao)(No.JCZX202026)。
文摘The Duolong mineral district in western Tibet is one of the largest porphyry Cu–Au deposit fields with significant metallogenic potential in China.Its tectonic environment relevant to Early Cretaceous Cu–Au mineralization remains controversial.Here we report new whole-rock major and trace element,and Sr-Nd-Hf-Pb isotopic data for the newly discovered basalt in the Nadun area,Duolong mineral district,to decipher their genesis and further constrain the tectonic environment.A contemporaneous rhyolite sample interbedded with the basalt in the lower part of the volcanic section in the Nadun area yields an LA-ICP-MS zircon U–Pb age of 122.5±1.2 Ma.The basalt samples exhibit high-K calc-alkaline/shoshonite properties and are enriched in high field strength elements,e.g.,high Ti O_(2)(1.43–1.79 wt.%)and Nb(14.6–19.5 ppm)contents,with high Nb/La ratios(0.4–0.6),which are compositionally comparable to those of Nb-enriched arc basalts(NEABs).The(^(87) Sr/^(86) Sr)iratios of 0.7052 to 0.7056,negative eNd(t)(-0.7 to-0.2)and eHf(t)values(+6.0 to+6.5),and high(^(206) Pb/^(204)Pb)i,(^(207) Pb/^(204)Pb)i,(^(208) Pb/^(204)Pb)iand ratios(18.522 to 18.561,15.641 to 15.645 and 38.679 to 38.730,respectively)suggest that the Nadun NEABs are more enriched than those of the island arc basalts(IABs)in the area.The slightly enriched radiogenic isotopes for the Nadun NEABs indicate that the subducting sediments play an important role in the source.Furthermore,their high Nb,Ti,and Cu contents indicate that the source mantle wedge was metasomatized by slab melts.The Nadun NEAB and other coeval magmatic rocks in the Duolong mineral district,including adakite,OIB-like basalt,MORB-type basalt,A-type rhyolite,and common IAB,are typical rock assemblages of ridge subduction.We infer that the Duolong mineral district were formed by ridge subduction in the Early Cretaceous.
文摘The present work is a petrological study of the gabbroic rocks of wadi Shianite Southeastern Desert of Egypt. Chemical analyses for major and trace elements showed that there are 3 main gabbro types. These are: 1)?pyroxene hornblende gabbronorite;?2) hornblende gabbro;?and 3) anorthosite.?The opaque minerals study of the gabbroic rocks showed that they composed mainly of ilmenite, magnetite and sulphides. The present gabbroic rocks work are related to calc-alkaline magma type, similar to the younger gabbros in other areas in the Eastern Desert.
基金supported by grants the Natural Science Foundation of China(Grant Nos.41802055 and 41802034)the International Geoscience Programme(Grant No.IGCP649,2015–2020)+2 种基金the Natural Science Foundation of Jiangsu(Grant No.BK20180349)the Research Founding from Chinese Academy of Geological Sciences(J1903)the fund from the Key Laboratory of DeepEarth Dynamics of Ministry of Natural Resources
文摘A series ophiolitic massifs in the northeastern part of Cuba are generally considered to be relics of proto-Caribbean or Caribbean lithosphere, emplaced during Paleogene collision of the NW Caribbean and North American plates(Iturralde-Vinent et al., 2016). However, neither their age nor their geodynamic settings are well constrained. They are generally considered to be Creataceous in age but they have been interpreted as having formed in a back-arc basin, forearc basin or plume setting(e.g. Giunta et al., 2009;Marchesi et al., 2016;Kerr et al., 1999). The Moa-Baracoa ophiolitic massif consists of mantle harzburgite, a Moho transition zone, layered and isotropic gabbro, and pillow basalts. The isotropic gabbros, collected west of Moa(20°35′17.99″N, 75°02′56.58″W), are composed mainly of subhedral plagioclase and subhedral to euhedral clinopyroxene with minor primary brown amphibole. The plagioclase grains are fresh, whereas the clinopyroxene very weakly altered and partly replaced by secondary amphibole. Cathodoluminescence(CL) images of zircon grains separated from isotropic gabbro display oscillatory zoning and broad zoning, analogous to typical igneous zircon in gabbro. Ten zircon grains with oscillatory zoning in CL images yielded a mean U-Pb SHRIMP age of 136.7±1.8 Ma. Isotropic gabbro samples have low SiO2(47.22 wt%–49.25 wt%), TiO2(0.13 wt%–0.26 wt%) and K2O(0.04 wt%–0.08 wt%) and high MgO(8.22 wt%–16.72 wt%), Cr(1337–2065 μg/g) and Ni(192–507 μg/g) contents. Their CaO, Al2O3 and Na2O contents vary from 13.56 wt% to 15.78 wt%, 14.98 wt % to 21.98 wt %, and 0.71 wt % to 1.87 wt %, respectively. In the SiO2 versus Zr/TiO2*0.0001 diagram, the samples plot in the sub-alkaline basalt field but show calcalkaline affinities in the FeOT/MgO vs. SiO2 diagram. The gabbros contain low REE contents(∑REE = 4.71–7.71), and their chondrite normalized REE patterns show very weak depletion in light REE(LREE,(La/Yb)N = 0.34–0.50) and flat heavy REE(HREE,(Gd/Yb)N = 1.02–1.15) profiles, with slightly positive Eu anomalies(Eu/Eu* = 1.55–1.76) suggesting magmatic accumulation of plagioclase. Furthermore, all samples are depleted in Nb and Th, and enriched in Ba, Pb and Sr in the primitive mantle-normalized trace element diagram. Geochemical features, such as high values of Ba/La(30–38) and low Th/Yb(0.02–0.03), medium values of(Ta/La)PM(0.30–0.35)and(Hf/Sm)PM(0.58–0.80), indicate enrichment by slab-derived fluids and subduction-related metasomatism. These isotropic gabbros are geochemically comparable with those of the Kermanshah and Neyriz ophiolites of Iran(Monsef et al., 2018) that are thought to have originated in a SSZ environment. Therefore, we suggest that the isotropic gabbros in the MoaBaracoa massif crystallized from early Cretaceous SSZ magmas that were most likely derived from a mantle source metasomatized by slab fluids in a suprasubduction zone environment.
文摘The Rif Mountain located in Northern Morocco represents the westernmost extremity of the Peri-Mediterranean Alpine orogenic system.This belt is classically subdivided into:1)Internal zones(or Internal Rif which is an allochthonous metamorphic domain known worldwide thanks to the presence of large peridotite outcrops);2)flysch zones(sediments corresponding to the original cover of the Maghrebian Tethys);and 3)External zones(or External Rif representing the North African margin remnants).The External Rif is itself subdivided into Prerif,Mesorif and Intrarif domains from the South to the North and is composed by Upper Triassic to Cenozoic sediments structured in a nappe stack.Mafic rock intrusions were reported in this External Rif since the preliminary geological studies even if they were wrongly mapped as"granites".Later careful fieldwork and mapping studies specified nevertheless their gabbroic nature.A more recent petrological and geochemical study of a few outcrops of those gabbroic intrusions conducted the corresponding authors,encouraged by the presence of ultramafic rocks(Beni Malek serpentines)in the eastern part of the External Rif to consider those gabbros as oceanic and so,associated to"an ophiolitic suture".Nevertheless,a recent and extended survey on the architecture and the rifting history of the Mesozoic margin of the Maghrebian Tethys focusing mainly on the Mesorif domain favor another interpretation.The detailed petrography of those mafic intrusions(mainly gabbros+dolerites and rarely extrusive rocks);their geochemical fingerprints and mainly their geochronological data(ages around 200 Ma based on U-Pb zircon LA-ICP dating)all together indicate clearly that those mafic intrusions are rather a"newly discovered"manifestation of the Central Atlantic Magmatic Province activity"CAMP"in the External Rif belt.The CAMP magmatism has been largely well described and characterized in all the other geological domains of Morocco(Anti-Atlas,High Atlas,Middle Atlas and Meseta)but never described until the date in the Rif belt which highlights the importance of the results reported here.
