The element diffusion process of Nb_3Sn superconductors by bronze route was studied using X-ray diffraction, scanning electron microscopy and energy dispersive spectroscopy. The critical current of superconductors was...The element diffusion process of Nb_3Sn superconductors by bronze route was studied using X-ray diffraction, scanning electron microscopy and energy dispersive spectroscopy. The critical current of superconductors was measured by four-point method. The results show that a diffusion layer has formed around the boundaries between the filaments and bronze matrix after 15 h heat treatment. The diffusion layer thickness keeps stable after heat treatment duration of 50~75 h. The stable and solid Nb 3 Sn layer is obtained in the sample after 100 h heat treatment. Excessive heat treatment would induce superconductivity degeneration because of superconductor grain coarsening. The characteristics of the element diffusion process were discussed. The diffusion of tin atom is the governing factor in diffusion. In this study, Nb_3_Sn superconductors with good superconducting property were fabricated successfully at 670 °C after 100h heat treatment.展开更多
The diffusion process of Sn in the transformation of Nb_6Sn_5 to Nb_3Sn has been studied.The experimental results show that the growth of Nb_3Sn laver is controlled by two processes,i.e. the short range diffusion of S...The diffusion process of Sn in the transformation of Nb_6Sn_5 to Nb_3Sn has been studied.The experimental results show that the growth of Nb_3Sn laver is controlled by two processes,i.e. the short range diffusion of Sn which is responsihle for the inner layer with large grains,and the long,range diffusion of Sn which results in the outer layer with fine grains.It was found thai grain size depends on the reaction temperature.A model of Nb_3Sn growth based on the above processes was established and its solution was found to be in good agreement with ex- perimental results.展开更多
Low-temperature synthesis of Nb_(3)Sn thin-film cavity is of great significance in the field of superconducting radio frequency(SRF).The bronze process can grow only stable Nb_(3)Sn phase at 700℃,so it is considered ...Low-temperature synthesis of Nb_(3)Sn thin-film cavity is of great significance in the field of superconducting radio frequency(SRF).The bronze process can grow only stable Nb_(3)Sn phase at 700℃,so it is considered to be the most promising process for low-temperature synthesis of Nb3Sn thin-film cavity.We successfully fabricated the worldwide first Nb_(3)Sn thin-film cavity by bronze process.We technically solved the key problems of precursor preparation,characterized and analyzed the uniformity of the Nb_(3)Sn film,and tested the performance of the cutout samples and the whole cavity of the Nb_(3)Sn film.It is obtained that the Q0value of the cavity at 4.2 K is about 1.2×10^(9),which is greater than the performance of the bulk-niobium cavity under the same conditions.This result means that the preparation of Nb_(3)Sn by bronze process has the great potential to more practical copper-based Nb_(3)Sn thin-film cavity,which is expected to achieve a substantial improvement in the performance of SRF cavity and comprehensive engineering applications.展开更多
Boundary conditions constructed by two typical geometrical configurations related to the manufacturing methods of bronze process and tin-rich Nb tube method have been considered in a diffusion model in which the diffu...Boundary conditions constructed by two typical geometrical configurations related to the manufacturing methods of bronze process and tin-rich Nb tube method have been considered in a diffusion model in which the diffusion of Sn in CuSn matrix plays a major role is as- sumed.The dependence of thickness of Nb_3Sn layer on reaction time has been derived.It is shown that the growth rate of Nb_3Sn relates to the configuration of the superconductor,the geometrical parameters of Nb filaments and CuSn matrix.The theory is qualitatively con- sistent with the experimental results.展开更多
基金supported by the National Natural Science Foundation of China(No.50925726)
文摘The element diffusion process of Nb_3Sn superconductors by bronze route was studied using X-ray diffraction, scanning electron microscopy and energy dispersive spectroscopy. The critical current of superconductors was measured by four-point method. The results show that a diffusion layer has formed around the boundaries between the filaments and bronze matrix after 15 h heat treatment. The diffusion layer thickness keeps stable after heat treatment duration of 50~75 h. The stable and solid Nb 3 Sn layer is obtained in the sample after 100 h heat treatment. Excessive heat treatment would induce superconductivity degeneration because of superconductor grain coarsening. The characteristics of the element diffusion process were discussed. The diffusion of tin atom is the governing factor in diffusion. In this study, Nb_3_Sn superconductors with good superconducting property were fabricated successfully at 670 °C after 100h heat treatment.
文摘The diffusion process of Sn in the transformation of Nb_6Sn_5 to Nb_3Sn has been studied.The experimental results show that the growth of Nb_3Sn laver is controlled by two processes,i.e. the short range diffusion of Sn which is responsihle for the inner layer with large grains,and the long,range diffusion of Sn which results in the outer layer with fine grains.It was found thai grain size depends on the reaction temperature.A model of Nb_3Sn growth based on the above processes was established and its solution was found to be in good agreement with ex- perimental results.
基金supported by the National Natural Science Foundation of China(Grant Nos.12075295 and 12105335)。
文摘Low-temperature synthesis of Nb_(3)Sn thin-film cavity is of great significance in the field of superconducting radio frequency(SRF).The bronze process can grow only stable Nb_(3)Sn phase at 700℃,so it is considered to be the most promising process for low-temperature synthesis of Nb3Sn thin-film cavity.We successfully fabricated the worldwide first Nb_(3)Sn thin-film cavity by bronze process.We technically solved the key problems of precursor preparation,characterized and analyzed the uniformity of the Nb_(3)Sn film,and tested the performance of the cutout samples and the whole cavity of the Nb_(3)Sn film.It is obtained that the Q0value of the cavity at 4.2 K is about 1.2×10^(9),which is greater than the performance of the bulk-niobium cavity under the same conditions.This result means that the preparation of Nb_(3)Sn by bronze process has the great potential to more practical copper-based Nb_(3)Sn thin-film cavity,which is expected to achieve a substantial improvement in the performance of SRF cavity and comprehensive engineering applications.
文摘Boundary conditions constructed by two typical geometrical configurations related to the manufacturing methods of bronze process and tin-rich Nb tube method have been considered in a diffusion model in which the diffusion of Sn in CuSn matrix plays a major role is as- sumed.The dependence of thickness of Nb_3Sn layer on reaction time has been derived.It is shown that the growth rate of Nb_3Sn relates to the configuration of the superconductor,the geometrical parameters of Nb filaments and CuSn matrix.The theory is qualitatively con- sistent with the experimental results.
基金the National Natural Science Foundation of China(Grant Nos.11602185,11972271,and 12322208)the Young Elite Scientists Sponsorship Program by CAST(Grant No.2020QNRC001)the Fundamental Research Funds for the Central Universities.
基金the National Natural Science Foundation of China(Grant Nos.11427904,12025506,and 12172357)the Key Scientific Instruments Development Program of CAS(Grant No.GJJSTD20210007)the Key Projects of Guangdong Basic and Applied Basic Research Fund Joint Fund(Grant No.2022B1515120051).
文摘中国科学院近代物理研究所正在研发第四代ECR(电子回旋共振)离子源FECR(first 4th generation ECR ion source).以20 kW/45 GHz微波加热运行为目标,需要研制Nb_(3)Sn超导磁体以实现对所加热等离子体的有效磁场约束.作为首台采用Nb_(3)Sn超导磁体技术的ECR离子源,FECR的主磁场线圈由4套独立的轴向螺线管线圈与1套径向六极线圈所构成,且均采用单股Nb_(3)Sn线绕制而成,这给线圈的加工、冷体装配、磁体的失超保护等环节带来一系列挑战.为使磁体能在高场、高应力作用下安全稳定运行,项目采用基于铝壳体结构与bladder&key的预紧应力控制技术,完成了一套半尺寸冷体样机的研发.该样机已完成4.2 K低温测试.本项研究的核心关键问题与挑战是如何在复杂的高精度机械装配与高电流强磁场励磁过程中实现对易碎Nb_(3)Sn导线的有效保护.本篇文章中,我们将阐述如何设计、研制、装配及测试工作于复杂磁场与应力环境的高性能Nb_(3)Sn六极磁铁.针对于单个六极线圈的测试,我们设计研发了一种称为“Mirror”结构的测试工装.论文中会详细论述基于壳层结构与bladder&key的装配预紧技术在半尺寸样机上的应用效果.同时,论文对在半尺寸样机上观察到的强烈磁通跳跃现象和它对失超探测保护的严峻挑战问题及相关解决或规避方案进行相关论述.
