Nd^3＋ doped KLa（MoO4）2 single crystal with the size up to Ф25 × 40 mm^3 was grown by the Czochralski technique. The absorption and luminescence spectra of trivalent neodymium in KLa（MoO4）2 crystal were inve...Nd^3＋ doped KLa（MoO4）2 single crystal with the size up to Ф25 × 40 mm^3 was grown by the Czochralski technique. The absorption and luminescence spectra of trivalent neodymium in KLa（MoO4）2 crystal were investigated at room temperature. The absorption and emission cross 10-20 sections are 3.02 ×10^-20 cm^2 at 808 nm and 20.01 × 10^-2 cm^2 at 1061 nm, respectively. The fluorescence lifetime is 164μs at room temperature.展开更多
The spectral parameters of Nd^3＋ ions in Nd^3＋-doped NaGd（MoO4）2 crystal have been investigated based on Judd-Ofelt theory and obtained as follows： The intensity parameters Ωeff are Ω2 = 24.77×10^20, Ω4 =...The spectral parameters of Nd^3＋ ions in Nd^3＋-doped NaGd（MoO4）2 crystal have been investigated based on Judd-Ofelt theory and obtained as follows： The intensity parameters Ωeff are Ω2 = 24.77×10^20, Ω4 = 7.31×10^-20 and Ω6 = 6.91×10^-20 cm^2. The radiative lifetime is 100 μs, and the quantum efficiency is 93.9%. The fluorescence branch ratios were calculated to be β1 = 0.441, β2 = 0.469,β3 = 0.086 and β4=0.004.展开更多
文摘采用高温固相法制备了KLa(Mo O4)2∶Sm3+红色荧光粉,利用X射线衍射对晶体结构进行表征,发现不同浓度Sm3+掺杂的样品均为单斜相结构。测量了样品的激发和发射光谱,观察到样品在紫外区及可见蓝绿区均有强的激发带,在404 nm激发下存在4个发射峰。测量了不同温度下样品的发射光谱和荧光衰减曲线,对样品的荧光温度猝灭进行了分析,确定了样品发光的温度猝灭是由横向穿越所导致的,采用Arrhennius模型对实验数据进行拟合,确定激活能约为0.48 e V,表明荧光粉具有良好的热稳定性。
基金This work was supported by the National Natural Science Foundation of China (50272066) and Key Project of Science and Technology of Fujian (2001H107)
文摘Nd^3＋ doped KLa（MoO4）2 single crystal with the size up to Ф25 × 40 mm^3 was grown by the Czochralski technique. The absorption and luminescence spectra of trivalent neodymium in KLa（MoO4）2 crystal were investigated at room temperature. The absorption and emission cross 10-20 sections are 3.02 ×10^-20 cm^2 at 808 nm and 20.01 × 10^-2 cm^2 at 1061 nm, respectively. The fluorescence lifetime is 164μs at room temperature.
基金This work supported by the Natural Science Foundation of Fujian Province (No.60378031)Key Project of Science andTechnology of Fujian Province (No.2001F004).
基金This work was supported by the National Natural Science Foundation of China (60378031) and Key Project of Science and Technology of Fujian Province (2001H1007)
文摘The spectral parameters of Nd^3＋ ions in Nd^3＋-doped NaGd（MoO4）2 crystal have been investigated based on Judd-Ofelt theory and obtained as follows： The intensity parameters Ωeff are Ω2 = 24.77×10^20, Ω4 = 7.31×10^-20 and Ω6 = 6.91×10^-20 cm^2. The radiative lifetime is 100 μs, and the quantum efficiency is 93.9%. The fluorescence branch ratios were calculated to be β1 = 0.441, β2 = 0.469,β3 = 0.086 and β4=0.004.
