A Fe modified Na2WO4 compound was synthesized by a solution impregnation method and was ball-milled with MgH2 to constitute a novel MgH2-Fe2O3/Na2WO4 composite. The effects of the Fe2O3/Na2WO4 additive on the hydrogen...A Fe modified Na2WO4 compound was synthesized by a solution impregnation method and was ball-milled with MgH2 to constitute a novel MgH2-Fe2O3/Na2WO4 composite. The effects of the Fe2O3/Na2WO4 additive on the hydrogen storage properties of MgH2 together with the corresponding mechanism were investigated. At 423 K, within the first 200 seconds, the hydrogen absorption amount of MgH2+20 wt% Fe2O3/Na2WO4 was almost 5 times that of pure MgH2. And at 573 K, its total hydrogen desorption amount was 7 times that for pure MgH2. Meanwhile, its onset dehydrogenation temperature was 110 K lower than that of pure MgH2. It was worth noting that the MgH2+20 wt% Fe/Na2WO4 presented the lower dehydrogenation reaction activation energy(Ea) of 35.9 kJ·mol^-1 compared to that of pure MgH2. The active MgWO4, Mg2 FeH6 and MgO formed during the milling process were responsible for the improvement of the hydrogen storage properties for MgH2.展开更多
The spectral parameters of Nd3+ ions in Nd3+:Klu(WO4)2 crystal were calculated based on Judd-Ofelt theory and obtained as follows: for the oscillator strengths ?λ: ?2 = 7.5029×10-20 cm2, ?4 = 7.1837×10-20...The spectral parameters of Nd3+ ions in Nd3+:Klu(WO4)2 crystal were calculated based on Judd-Ofelt theory and obtained as follows: for the oscillator strengths ?λ: ?2 = 7.5029×10-20 cm2, ?4 = 7.1837×10-20 cm2 and ?6 = 3.1189×10-20 cm2; the radiative lifetime is 123 μs; the quantum efficiency is equal to 64.55%; and β1 = 0.5498, β2 = 0.3943, β3 = 0.0551 and β4 = 0.0027 for the fluorescence branch ratios.展开更多
The laser host crystals of KLu(WO4)2(KLuW) with large sizes up to 43 × 35 × 16 mm3 have been grown along, [110], b, and c crystallographic directions, respectively, by the top-seeded solution growth (TSSG) s...The laser host crystals of KLu(WO4)2(KLuW) with large sizes up to 43 × 35 × 16 mm3 have been grown along, [110], b, and c crystallographic directions, respectively, by the top-seeded solution growth (TSSG) slow-cooling method. The macro defects are observed using optical microscopy. The main defects found were cracks, inclusions, growth striations, sector boundaries and twin boundaries. The formation mechanism and approaches to reduce or eliminate the defects have been analyzed.展开更多
基金Funded by the National Natural Science Foundation of China(No.51771164)Scientific Research Projects in Colleges and Universities in Hebei Province,China(No.ZD2019307)+2 种基金the Fundamental Research Funds for the Central Universities(No.3142019013)the Natural Science Foundation of Hebei Province of China(No.E2019508214)the Program for Top-notch Young Talents in University of Hebei Province(No.BJ2016043)
文摘A Fe modified Na2WO4 compound was synthesized by a solution impregnation method and was ball-milled with MgH2 to constitute a novel MgH2-Fe2O3/Na2WO4 composite. The effects of the Fe2O3/Na2WO4 additive on the hydrogen storage properties of MgH2 together with the corresponding mechanism were investigated. At 423 K, within the first 200 seconds, the hydrogen absorption amount of MgH2+20 wt% Fe2O3/Na2WO4 was almost 5 times that of pure MgH2. And at 573 K, its total hydrogen desorption amount was 7 times that for pure MgH2. Meanwhile, its onset dehydrogenation temperature was 110 K lower than that of pure MgH2. It was worth noting that the MgH2+20 wt% Fe/Na2WO4 presented the lower dehydrogenation reaction activation energy(Ea) of 35.9 kJ·mol^-1 compared to that of pure MgH2. The active MgWO4, Mg2 FeH6 and MgO formed during the milling process were responsible for the improvement of the hydrogen storage properties for MgH2.
基金This work was supported by the National Natural Science Foundation of China (50272066) and Key Project of Science and Technology of Fujian Province (2001F004)
文摘The spectral parameters of Nd3+ ions in Nd3+:Klu(WO4)2 crystal were calculated based on Judd-Ofelt theory and obtained as follows: for the oscillator strengths ?λ: ?2 = 7.5029×10-20 cm2, ?4 = 7.1837×10-20 cm2 and ?6 = 3.1189×10-20 cm2; the radiative lifetime is 123 μs; the quantum efficiency is equal to 64.55%; and β1 = 0.5498, β2 = 0.3943, β3 = 0.0551 and β4 = 0.0027 for the fluorescence branch ratios.
基金Supported by Natural Science Foundation of Jilin Province(20220101024JC,20200201247JC,20170520110JH)National Natural Science Foundation of China(11504029,11474035)。
文摘The laser host crystals of KLu(WO4)2(KLuW) with large sizes up to 43 × 35 × 16 mm3 have been grown along, [110], b, and c crystallographic directions, respectively, by the top-seeded solution growth (TSSG) slow-cooling method. The macro defects are observed using optical microscopy. The main defects found were cracks, inclusions, growth striations, sector boundaries and twin boundaries. The formation mechanism and approaches to reduce or eliminate the defects have been analyzed.
