The grain boundary phase affects the magnetic properties and corrosion resistance of sintered NdFeB magnets.In this work,a small amount of In was added to NdFeB magnets by induction melting to systematically investiga...The grain boundary phase affects the magnetic properties and corrosion resistance of sintered NdFeB magnets.In this work,a small amount of In was added to NdFeB magnets by induction melting to systematically investigate its effect on the evolution of the microstructure,magnetic properties and corrosion resistance of NdFeB magnets.Microstructural analysis illustrated that minor In addition generated more grain boundary phases and an abundant amorphous phase at the triple-junction grain boundary.While the addition of In failed to enhance the magnetic isolation effect between adjacent matrix grains,its incorporation fortuitously elevated the electrochemical potential of the In-containing magnets.Besides,during corrosion,an In-rich precipitate phase formed,hindering the ingress of the corrosive medium into the magnet.Consequently,this significantly bolstered the corrosion resistance of the sintered NdFeB magnets.The phase formation,magnetic properties and corrosion resistance of In-doped NdFeB magnets are detailed in this work,which provides new prospects for the preparation of high-performance sintered NdFeB magnets.展开更多
An eco-friendly superhydrophobic protective film(DTMS/TEOS silane film)was fabricated on sintered NdFeB substrate through the utilization of electrochemically assisted deposition technology.The structure,properties,an...An eco-friendly superhydrophobic protective film(DTMS/TEOS silane film)was fabricated on sintered NdFeB substrate through the utilization of electrochemically assisted deposition technology.The structure,properties,and film-forming mechanism of dodecyltrime-thoxysilane(DTMS)/tetraethoxysilane(TEOS)silane films were comprehensively analyzed using Fourier transform infrared spectroscopy(FT-IR),scanning electron microscopy(SEM),X-ray photoelectron spectroscopy(XPS),potentiodynamic polarization curves and electrochemical impedance spectroscopy(EIS).Based on the test results,it can be determined that this film has a superhydrophobic property with a hydrophobicity angle of 152°.This special property can be attributed to the long alkyl chains in the DTMS molecule,the rough morphology,and the low surface energy of the DTMS/TEOS silane film.The surface of sintered NdFeB is coated with a layered three-dimensional network silane film that forms through the condensation of silanol substances.This film provides excellent corrosion resistance to the sintered NdFeB substrate,reducing its corrosion current density to 2.02×10~(-6)A/cm~2.Moreover,the impact of film on the magnetic characteristics of sintered NdFeB was assessed and found to be minimal.展开更多
With the continuous development of artillery,the disadvantages of hydraulic recoil brakes gradually appear.At the same time,the appearance of high-performance Nd Fe B permanent magnet makes it possible to apply electr...With the continuous development of artillery,the disadvantages of hydraulic recoil brakes gradually appear.At the same time,the appearance of high-performance Nd Fe B permanent magnet makes it possible to apply electromagnetic braking technology to recoil mechanism.In this paper,prototype tests of a certain artillery were carried out to verify the feasibility of the electromagnetic brake(EMB)and obtain the electromagnetic braking force.Due to the brittleness of Nd Fe B,in order to eliminate the worry about the safety of EMB,SHPB experiments of Nd Fe B were carried out.Then,based on the assumption of uniform crack distribution,the law of crack propagation and damage accumulation was described theoretically,and the damage constitutive model suitable for brittle materials was proposed by combining the Zhu-Wang-Tang(ZWT)equation.Finally,the numerical simulation model of the artillery prototype was established and through calculation,the dynamic mechanical characteristics of Nd Fe B in the prototype were analyzed.The calculation results show that the strength of Nd Fe B can meet the requirements of the use in the working process.From the perspective of damage factor,the damage value of the permanent magnet on the far right is larger,and the damage value of the inner ring gradually decreases to the outer ring.展开更多
基金National Natural Science Foundation of China(No.52161040)Major Science and Technology Research and Development Project of Jiangxi Province(No.20203ABC28W006)+1 种基金Natural Science Foundation of Jiangxi Province,China,(No.20202ACBL214011)Key Project of"Science and Technology to Promote Mongolian Development",China(No.XM2021BT03)。
基金funded by Ningbo Key R&D Plan and“Unveiling and Leading”(Grant No.2023Z093)Ningbo Science and Technology Innovation 2025 Major Special Project(Grant No.2022Z106)Hezhou City Central Leading Local Science and Technology Development Special Fund Project(Grant No.HK ZY2022002).
文摘The grain boundary phase affects the magnetic properties and corrosion resistance of sintered NdFeB magnets.In this work,a small amount of In was added to NdFeB magnets by induction melting to systematically investigate its effect on the evolution of the microstructure,magnetic properties and corrosion resistance of NdFeB magnets.Microstructural analysis illustrated that minor In addition generated more grain boundary phases and an abundant amorphous phase at the triple-junction grain boundary.While the addition of In failed to enhance the magnetic isolation effect between adjacent matrix grains,its incorporation fortuitously elevated the electrochemical potential of the In-containing magnets.Besides,during corrosion,an In-rich precipitate phase formed,hindering the ingress of the corrosive medium into the magnet.Consequently,this significantly bolstered the corrosion resistance of the sintered NdFeB magnets.The phase formation,magnetic properties and corrosion resistance of In-doped NdFeB magnets are detailed in this work,which provides new prospects for the preparation of high-performance sintered NdFeB magnets.
基金financial support from the Public Welfare Projects of Zhejiang Province,China(No.LGG22E010002)the National Natural Science Foundation of China(Nos.52001300,52171083)。
文摘An eco-friendly superhydrophobic protective film(DTMS/TEOS silane film)was fabricated on sintered NdFeB substrate through the utilization of electrochemically assisted deposition technology.The structure,properties,and film-forming mechanism of dodecyltrime-thoxysilane(DTMS)/tetraethoxysilane(TEOS)silane films were comprehensively analyzed using Fourier transform infrared spectroscopy(FT-IR),scanning electron microscopy(SEM),X-ray photoelectron spectroscopy(XPS),potentiodynamic polarization curves and electrochemical impedance spectroscopy(EIS).Based on the test results,it can be determined that this film has a superhydrophobic property with a hydrophobicity angle of 152°.This special property can be attributed to the long alkyl chains in the DTMS molecule,the rough morphology,and the low surface energy of the DTMS/TEOS silane film.The surface of sintered NdFeB is coated with a layered three-dimensional network silane film that forms through the condensation of silanol substances.This film provides excellent corrosion resistance to the sintered NdFeB substrate,reducing its corrosion current density to 2.02×10~(-6)A/cm~2.Moreover,the impact of film on the magnetic characteristics of sintered NdFeB was assessed and found to be minimal.
基金financially supported by the“National Natural Science Foundation of China”[Grant No.52105106]the“China National Postdoctoral Program for Innovative Talents”[Grant No.BX2021126]+2 种基金the“Jiangsu Province Natural Science Foundation”[Grant No.BK20210342]the“Jiangsu Planned Projects for Postdoctoral Research Funds”[Grant No.2021K008A]the“Nanjing Municipal Human Resources and Social Security Bureau”[Grant No.MCA21121]。
文摘With the continuous development of artillery,the disadvantages of hydraulic recoil brakes gradually appear.At the same time,the appearance of high-performance Nd Fe B permanent magnet makes it possible to apply electromagnetic braking technology to recoil mechanism.In this paper,prototype tests of a certain artillery were carried out to verify the feasibility of the electromagnetic brake(EMB)and obtain the electromagnetic braking force.Due to the brittleness of Nd Fe B,in order to eliminate the worry about the safety of EMB,SHPB experiments of Nd Fe B were carried out.Then,based on the assumption of uniform crack distribution,the law of crack propagation and damage accumulation was described theoretically,and the damage constitutive model suitable for brittle materials was proposed by combining the Zhu-Wang-Tang(ZWT)equation.Finally,the numerical simulation model of the artillery prototype was established and through calculation,the dynamic mechanical characteristics of Nd Fe B in the prototype were analyzed.The calculation results show that the strength of Nd Fe B can meet the requirements of the use in the working process.From the perspective of damage factor,the damage value of the permanent magnet on the far right is larger,and the damage value of the inner ring gradually decreases to the outer ring.
