Intense 1-5 μm infrared emission from near-to mid-infrared was obtained from Ho3+/Yb3+codoped TeO2-ZnF2 oxyfluorotellurite glasses which were prepared by melt-quenching method under the 980 nm LD excitation,and the e...Intense 1-5 μm infrared emission from near-to mid-infrared was obtained from Ho3+/Yb3+codoped TeO2-ZnF2 oxyfluorotellurite glasses which were prepared by melt-quenching method under the 980 nm LD excitation,and the emission intensity can be enhanced with the increase of ZnF2 content.Judd-Ofelt analysis was used to evaluate the radiative transition parameters of the excited levels according to the absorption spectra.The stimulated emission cross section of 5 I6→5 I8(1.2 μm),5 I7→5 I8(2.0μm),5 I6→5 I7(2.85 μm) and 5 I5→5 I6(4.0 μm) transitions were calculated to reach 0.639 × 10-20,0.760 ×10-20,0.985×10 20 and 0.484 × 10-20 cm2,respectively.The energy transfer coefficients(CDA) are enhanced with the increase of ZnF2 content and phonon contribution ratios of phonon assisted energy transfer process between Ho3+ and Yb3+were figured out.Our results demonstrate that these TeO2-ZnF2 glasses,which possess good thermal stability and transparency,low phonon energy(about 600 cm-1),excellent near-and mid-infrared emission in the range of 1-5 μm wavelength,would be promising material for infrared optical fibers and infrared lasers.展开更多
Accidents such as support failure and excessive deformation of roadways due to drastic changes in strata behaviors are frequently reported when mining the extra-thick coal seams Nos.3e5 in Datong coal mine with top-co...Accidents such as support failure and excessive deformation of roadways due to drastic changes in strata behaviors are frequently reported when mining the extra-thick coal seams Nos.3e5 in Datong coal mine with top-coal caving method,which significantly hampers the mine's normal production.To understand the mechanism of strata failure,this paper presented a structure evolution model with respect to strata behaviors.Then the behaviors of strata overlying the extra-thick coal seams were studied with the combined method of theoretical analysis,physical simulation,and field measurement.The results show that the key strata,which are usually thick-hard strata,play an important role in overlying movement and may influence the mining-induced strata behaviors in the working face using top-coal caving method.The structural model of far-field key strata presents a 'masonry beam' type structure when'horizontal O-X' breakage type happens.The rotational motion of the block imposed radial compressive stress on the surrounding rock mass of the roadway.This can induce excessive deformation of roadway near the goaf.Besides,this paper proposed a pre-control technology for the hard roof based on fracture holes and underground roof pre-splitting.It could effectively reduce stress concentration and release the accumulated energy of the strata,when mining underground coal resources with top-coal caving method.展开更多
基金Project supported by the National Natural Science Foundation of China (11574260)Hunan Provincial Graduate Research Innovation Project (CX2017B283)。
文摘Intense 1-5 μm infrared emission from near-to mid-infrared was obtained from Ho3+/Yb3+codoped TeO2-ZnF2 oxyfluorotellurite glasses which were prepared by melt-quenching method under the 980 nm LD excitation,and the emission intensity can be enhanced with the increase of ZnF2 content.Judd-Ofelt analysis was used to evaluate the radiative transition parameters of the excited levels according to the absorption spectra.The stimulated emission cross section of 5 I6→5 I8(1.2 μm),5 I7→5 I8(2.0μm),5 I6→5 I7(2.85 μm) and 5 I5→5 I6(4.0 μm) transitions were calculated to reach 0.639 × 10-20,0.760 ×10-20,0.985×10 20 and 0.484 × 10-20 cm2,respectively.The energy transfer coefficients(CDA) are enhanced with the increase of ZnF2 content and phonon contribution ratios of phonon assisted energy transfer process between Ho3+ and Yb3+were figured out.Our results demonstrate that these TeO2-ZnF2 glasses,which possess good thermal stability and transparency,low phonon energy(about 600 cm-1),excellent near-and mid-infrared emission in the range of 1-5 μm wavelength,would be promising material for infrared optical fibers and infrared lasers.
基金supported by the Special Funding Projects of“Sanjin Scholars”Supporting Plan(Grant No.2050205)
文摘Accidents such as support failure and excessive deformation of roadways due to drastic changes in strata behaviors are frequently reported when mining the extra-thick coal seams Nos.3e5 in Datong coal mine with top-coal caving method,which significantly hampers the mine's normal production.To understand the mechanism of strata failure,this paper presented a structure evolution model with respect to strata behaviors.Then the behaviors of strata overlying the extra-thick coal seams were studied with the combined method of theoretical analysis,physical simulation,and field measurement.The results show that the key strata,which are usually thick-hard strata,play an important role in overlying movement and may influence the mining-induced strata behaviors in the working face using top-coal caving method.The structural model of far-field key strata presents a 'masonry beam' type structure when'horizontal O-X' breakage type happens.The rotational motion of the block imposed radial compressive stress on the surrounding rock mass of the roadway.This can induce excessive deformation of roadway near the goaf.Besides,this paper proposed a pre-control technology for the hard roof based on fracture holes and underground roof pre-splitting.It could effectively reduce stress concentration and release the accumulated energy of the strata,when mining underground coal resources with top-coal caving method.
