Neodymium ion imprinted polymer（Nd^3＋-IIP） particles for selective solid-phase extraction of Nd^3＋ were prepared and determined with inductively coupled plasma atomic emission spectrometry（ICP-AES）.The unleached...Neodymium ion imprinted polymer（Nd^3＋-IIP） particles for selective solid-phase extraction of Nd^3＋ were prepared and determined with inductively coupled plasma atomic emission spectrometry（ICP-AES）.The unleached Nd^3＋-IIP particles were prepared by the copoly-merization of Nd^3＋-5,7-dichloroquinoline-8-ol-4-vinylpyridine ternary complex with styrene and divinyl benzene, then Nd^3＋ was leached to obtain Nd^3＋-IIP particles.The adsorption capacity of the Nd3＋-IIP was 35.18 mg/g.The largest selectivity coefficient for Nd3＋ in the presence of competitive ions such as La^3＋, Ce^3＋, Pr^3＋ and Sm^3＋ was over 110.The proposed method was validated by analyzing two certified reference materials（GBW07301a sediment and GBW07401 soil） and the determined values were in a good agreement with standard values.The method was convenient, selective, sensitive and applicable to the determination of trace Nd^3＋ in environmental samples with complicated matrix.展开更多
A facile method for the preparation of sodium alginate（SA）/carboxyl-functionalized graphene（G-COOH）composite hydrogel was developed. Based on the coordination ability of lanthanide ions to the carboxyl groups, a s...A facile method for the preparation of sodium alginate（SA）/carboxyl-functionalized graphene（G-COOH）composite hydrogel was developed. Based on the coordination ability of lanthanide ions to the carboxyl groups, a series of hydrogel derived from different ratios of SA and G-COOH was fabricated by neodymium（Nd3＋） ions coordination. A relatively uniform layered structure was recorded by SEM at the interior of SA/G-COOH hydrogel. Several parameters such as water content, swelling ratio（SR）, tensile test and solvent resistance were also investigated. The SA/G-COOH composite hydrogel showed excellent mechanical strength, and the tensile strength of SA/G-COOH composite hydrogel reaches 53.72 MPa at high water content. Due to the coordination ability of Nd3＋ ions, the hydrogel also exhibited an excellent solvent resistance and stability.展开更多
Neodymium silicides were synthesized by Nd ion implant6d into Si substrates with the aid of a metal vapor vacuum arc (MEVVA) ion source. The blender of Nd5Si4 and NdSi2 was formed in a neodymium-implanted silicon thin...Neodymium silicides were synthesized by Nd ion implant6d into Si substrates with the aid of a metal vapor vacuum arc (MEVVA) ion source. The blender of Nd5Si4 and NdSi2 was formed in a neodymium-implanted silicon thin film during the as-implanted state, but there was only single neodymium silicide compound in the postannealed state, and the phase changed from NdSi2 to Nd5Si4 with increasing annealing temperature. The blue-violet luminescence excited by ultra-violet was observed at the room temperature (RT), and the intensity of photoluminescence (PL) increased with increasing the neodymium ion fluence. Moreover, the photoluminescence was closely dependent on the temperature of rapid thermal annealing (RTA). A mechanism of photoluminescence was discussed.展开更多
文摘Neodymium ion imprinted polymer（Nd^3＋-IIP） particles for selective solid-phase extraction of Nd^3＋ were prepared and determined with inductively coupled plasma atomic emission spectrometry（ICP-AES）.The unleached Nd^3＋-IIP particles were prepared by the copoly-merization of Nd^3＋-5,7-dichloroquinoline-8-ol-4-vinylpyridine ternary complex with styrene and divinyl benzene, then Nd^3＋ was leached to obtain Nd^3＋-IIP particles.The adsorption capacity of the Nd3＋-IIP was 35.18 mg/g.The largest selectivity coefficient for Nd3＋ in the presence of competitive ions such as La^3＋, Ce^3＋, Pr^3＋ and Sm^3＋ was over 110.The proposed method was validated by analyzing two certified reference materials（GBW07301a sediment and GBW07401 soil） and the determined values were in a good agreement with standard values.The method was convenient, selective, sensitive and applicable to the determination of trace Nd^3＋ in environmental samples with complicated matrix.
基金supported by the National Natural Science Foundation of China under Grant Nos.21274020 and 21304019
文摘A facile method for the preparation of sodium alginate（SA）/carboxyl-functionalized graphene（G-COOH）composite hydrogel was developed. Based on the coordination ability of lanthanide ions to the carboxyl groups, a series of hydrogel derived from different ratios of SA and G-COOH was fabricated by neodymium（Nd3＋） ions coordination. A relatively uniform layered structure was recorded by SEM at the interior of SA/G-COOH hydrogel. Several parameters such as water content, swelling ratio（SR）, tensile test and solvent resistance were also investigated. The SA/G-COOH composite hydrogel showed excellent mechanical strength, and the tensile strength of SA/G-COOH composite hydrogel reaches 53.72 MPa at high water content. Due to the coordination ability of Nd3＋ ions, the hydrogel also exhibited an excellent solvent resistance and stability.
基金National Natural Science Foundation (No. 59671051)
文摘Neodymium silicides were synthesized by Nd ion implant6d into Si substrates with the aid of a metal vapor vacuum arc (MEVVA) ion source. The blender of Nd5Si4 and NdSi2 was formed in a neodymium-implanted silicon thin film during the as-implanted state, but there was only single neodymium silicide compound in the postannealed state, and the phase changed from NdSi2 to Nd5Si4 with increasing annealing temperature. The blue-violet luminescence excited by ultra-violet was observed at the room temperature (RT), and the intensity of photoluminescence (PL) increased with increasing the neodymium ion fluence. Moreover, the photoluminescence was closely dependent on the temperature of rapid thermal annealing (RTA). A mechanism of photoluminescence was discussed.
