The phosphors of ABF_4:Eu^(2+)and A_2SiF_6:Eu^(2+)(A=Na,K,Rb,Cs)have been synthesized,and the crystallographic data obtained accord with ASTM.In these materials,the f→f sharp lines emissions of Eu^(2+) were observed....The phosphors of ABF_4:Eu^(2+)and A_2SiF_6:Eu^(2+)(A=Na,K,Rb,Cs)have been synthesized,and the crystallographic data obtained accord with ASTM.In these materials,the f→f sharp lines emissions of Eu^(2+) were observed.The coordination numbers of Eu^(2+)in both NaBF_4 and Na_2SiF_6 hosts are less than 8.展开更多
Nucleosides and Nucleotides are polydentate ligands, offering potential binding sites for metal ions. Energy interaction parameters: Slater Condon Fk (cm-1), Spin Orbit interaction ξ4f? (cm-1), Nephelauxetic Ratio (...Nucleosides and Nucleotides are polydentate ligands, offering potential binding sites for metal ions. Energy interaction parameters: Slater Condon Fk (cm-1), Spin Orbit interaction ξ4f? (cm-1), Nephelauxetic Ratio (β), Bonding (b1/2) and Covalency (δ) parameter for the interaction of Pr(III) with Nucleoside and Nucleotide are evaluated to study the mode of binding of the Nucleic Acid Components (Guanosine and Guanosine Triphosphate) with Pr(III). Further Intensity Parameters like Oscillation Strength and Judd Ofelt Parameter (T2, T4, T6) have been evaluated to investigate degree of inner or outer sphere co-ordination of Pr(III) with Nucliec Acid ligands. Comperative Absorption Spectra in different solvents substantiate the informations, gathered from the evaluated values of both energy interaction and intensity parameters. Further evaluation of Thermodynamic parameters (ΔG, ΔH and ΔS) through Kinetic studies enable to provide the detailed information about the reaction pathways and thermodynamic behavour of the complexation process of neucleosides and nucleotides with Pr(III) and Ca2+.展开更多
A novel technique of symmetric type quasi-linear electron pulse duration modulation is proposed. The salient feature from the conventional photoelectron gun is the introduction of the alternating electric field resona...A novel technique of symmetric type quasi-linear electron pulse duration modulation is proposed. The salient feature from the conventional photoelectron gun is the introduction of the alternating electric field resonator. The electric field that results is synchronously controlled to generate the desired quasi-linear differential energy modulation on the electron pulse passing through. The effect resulted directly is that the leading electrons undergo negative energy modulation and decelerate, while the rear ones positive energy modulation and accelerate, which eventually leads to electron-pulse-duration modulation. The technical details are demonstrated.展开更多
The f→f electronic emission of Eu<sup>2+</sup> with configuration of 4f<sup>7</sup> can bring about laser generation. Some of Eu<sup>2+</sup>-activated crystals which can produce s...The f→f electronic emission of Eu<sup>2+</sup> with configuration of 4f<sup>7</sup> can bring about laser generation. Some of Eu<sup>2+</sup>-activated crystals which can produce sharp line emission, are candidates for visible solid-state laser at shorter wavelengths because their threshold is low and accumulated energy high.展开更多
基金Project supported by the National Natural Science Foundation of China.
文摘The phosphors of ABF_4:Eu^(2+)and A_2SiF_6:Eu^(2+)(A=Na,K,Rb,Cs)have been synthesized,and the crystallographic data obtained accord with ASTM.In these materials,the f→f sharp lines emissions of Eu^(2+) were observed.The coordination numbers of Eu^(2+)in both NaBF_4 and Na_2SiF_6 hosts are less than 8.
文摘Nucleosides and Nucleotides are polydentate ligands, offering potential binding sites for metal ions. Energy interaction parameters: Slater Condon Fk (cm-1), Spin Orbit interaction ξ4f? (cm-1), Nephelauxetic Ratio (β), Bonding (b1/2) and Covalency (δ) parameter for the interaction of Pr(III) with Nucleoside and Nucleotide are evaluated to study the mode of binding of the Nucleic Acid Components (Guanosine and Guanosine Triphosphate) with Pr(III). Further Intensity Parameters like Oscillation Strength and Judd Ofelt Parameter (T2, T4, T6) have been evaluated to investigate degree of inner or outer sphere co-ordination of Pr(III) with Nucliec Acid ligands. Comperative Absorption Spectra in different solvents substantiate the informations, gathered from the evaluated values of both energy interaction and intensity parameters. Further evaluation of Thermodynamic parameters (ΔG, ΔH and ΔS) through Kinetic studies enable to provide the detailed information about the reaction pathways and thermodynamic behavour of the complexation process of neucleosides and nucleotides with Pr(III) and Ca2+.
文摘A novel technique of symmetric type quasi-linear electron pulse duration modulation is proposed. The salient feature from the conventional photoelectron gun is the introduction of the alternating electric field resonator. The electric field that results is synchronously controlled to generate the desired quasi-linear differential energy modulation on the electron pulse passing through. The effect resulted directly is that the leading electrons undergo negative energy modulation and decelerate, while the rear ones positive energy modulation and accelerate, which eventually leads to electron-pulse-duration modulation. The technical details are demonstrated.
基金Project supported by the National Natural Science Foundation of China.
文摘The f→f electronic emission of Eu<sup>2+</sup> with configuration of 4f<sup>7</sup> can bring about laser generation. Some of Eu<sup>2+</sup>-activated crystals which can produce sharp line emission, are candidates for visible solid-state laser at shorter wavelengths because their threshold is low and accumulated energy high.
