Bauxite residue deposit area(BRDA)is a typical abandoned mining wasteland representing extreme hostile environment with increased alkalinity.Microbially-driven neutralization of bauxite residue,based on the microbial ...Bauxite residue deposit area(BRDA)is a typical abandoned mining wasteland representing extreme hostile environment with increased alkalinity.Microbially-driven neutralization of bauxite residue,based on the microbial acid producing metabolisms,is a novel strategy for achieving rapid pH neutralization and thus improving its environmental outcomes.The hypothesis was that these extreme conditions promote microbial communities which are capable of novel ecologically relevant functions.Several alkaliphilic acid producing bacteria were isolated in this study.One strain was selected for its superior growth pattern and acid metabolism(termed EEEL02).Based on the phylogenetic analysis,this strain was identified as Bacillus thuringiensis.The optimized fermentation conditions were as follows:pH 10;NaCl concentration 5%;temperature 25℃;EEEL02 preferred glucose and peptone as carbon and nitrogen sources,respectively.Based on optimal fermentation conditions,EEEL02 induced a significant pH reduction from 10.26 to 5.62 in 5-day incubation test.Acetic acid,propionic acid and CO2(g)were the major acid metabolites of fermentation,suggesting that the pH reduction in bauxite residue may be caused by acid neutralization derived from microbial metabolism.This finding provided the basis of a novel strategy for achieving rapid pH neutralization of bauxite residue.展开更多
Bauxite residues,a large volume solid waste,are in urgent need of effective disposal and management.Especially,strategies to alleviate the high alkalinity of bauxite residue remain a big challenge.Here,we developed a ...Bauxite residues,a large volume solid waste,are in urgent need of effective disposal and management.Especially,strategies to alleviate the high alkalinity of bauxite residue remain a big challenge.Here,we developed a synergistic pyrolysis to neutralize the alkalinity of bauxite residue and upgrade the structure of biomass simultaneously.By cooperating the catalytic feature from bauxite residue,rice straw,a cellulose-enriched biomass,could prefer to produce acidic components under a hypothermal pyrolysis temperature(below 250℃)and partial oxygen-contained atmosphere as evidenced by the synchronous TGA-FTIR analysis.In return,these in-situ produced acidic components neutralized the bauxite residue profoundly(pH decreased from 11.5 to 7.2)to obtain a neutral product with long-term water leaching stability.Also,a higher pyrolysis temperature led to neutral biochar-based products with well-defined carbonization characteristics.Thus,the biomass-driven pyrolysis strategy provides a potential to dispose the alkalinity issue of bauxite residue and further opportunities for the sustainable reuse and continuing management of bauxite residue.展开更多
Aluminum is an important basic raw material for national economic development.The alumina industry has been expanding rapidly due to the increasing demand for aluminum.Bauxite residue is a highly alkaline solid by-pro...Aluminum is an important basic raw material for national economic development.The alumina industry has been expanding rapidly due to the increasing demand for aluminum.Bauxite residue is a highly alkaline solid by-product generated when alumina is extracted from bauxite ore in alumina refineries[1,2].展开更多
Bauxite residue disposal areas(BRDAs)are physically degraded and hostile to plant growth.Nevertheless,natural plant colonization was observed in an abandoned BRDA in Central China.The pioneer plant species at the disp...Bauxite residue disposal areas(BRDAs)are physically degraded and hostile to plant growth.Nevertheless,natural plant colonization was observed in an abandoned BRDA in Central China.The pioneer plant species at the disposal area were identified,whilst distribution characteristics of salt ions such as Na^+,K^+,and Ca^2+in plant tissues and rhizosphere residues were investigated.The mean concentration of exchangeable Na^+in the rhizosphere soils was 19.5 cmol/kg,which suggested that these pioneer plants had relatively high salinity resistance.Sodium content varied from 0.84 cmol/kg(Digitaria sanguinalis)to 39.7 cmol/kg(Kochia scoparia),whilst K to Na ratio varied from 0.71(Myricaria bracteata)to 32.39(Digitaria sanguinalis)in the shoots,which demonstrated that the salinity tolerance mechanisms of these pioneer species differed significantly.Accumulation factors of Na^+in local plant species ranged from 0.04(D.sanguinalis)to 3.29(M.bracteata),whilst the translocation factor varied from 0.13(D.sanguinalis)to 2.92(M.bracteata).The results suggested that four pioneer plant species including K.scoparia,M.bracteate,Cynodon dactylon and D.sanguinalis could be suitable for revegetation at other disposal areas.展开更多
Revegetation on bauxite residue disposal areas is the most promising strategy to reduce its potential ecological risk during stacking or disposing.Migration of salt ions in bauxite residue is one of the major issues t...Revegetation on bauxite residue disposal areas is the most promising strategy to reduce its potential ecological risk during stacking or disposing.Migration of salt ions in bauxite residue is one of the major issues to stimulate soil formation to support plant growth.21 residue samples were collected and the related parameters including exchangeable cations,soluble ions,total salt,pH,electrical conductivity(EC)and exchangeable sodium percentage(ESP)were selected to evaluate alkalization and salinization of bauxite residue.High levels of ions,cation exchange capacity(TOC),total salt,exchangeable sodium percentage(ESP)and cation exchange capacity(CEC)in bauxite residue were detected with greater coefficient of variation(CV),which indicated that distribution characteristics of salt ions varied significantly.The percentage of sulfate-chloride-soda type in the residues accounted for 71.43%.The mean value of pH was 10.10,whilst mean value of ESP was 52.05%.It indicated that the residues in this case study belonged to sulfate-chloride-soda saline and alkaline soil.The research results could provide theoretical basis for soil formation in bauxite residue.展开更多
Vegetation encroachment occurred in bauxite residue disposal area(BRDA)following natural weathering processes,whilst the typical indicators of soil formation are still uncertain.Residue samples were collected from the...Vegetation encroachment occurred in bauxite residue disposal area(BRDA)following natural weathering processes,whilst the typical indicators of soil formation are still uncertain.Residue samples were collected from the BRDA in Central China,and related physical,chemical and biological indicators of bauxite residue with different storage years were determined.The indicators of soil formation in bauxite residue were selected using principal component analysis,factor analysis,and comprehensive evaluation to establish soil quality diagnostic index model on disposal areas.Following natural weathering processes,the texture of bauxite residue changed from silty loam to sandy loam.The pH and EC decreased,whilst porosity,nutrient element content and microbial biomass increased.The identified minimum data set(MDS)included available phosphorus(AP),moisture content(MC),C/N,sand content,total nitrogen(TN),microbial biomass carbon(MBC),and pH.The soil quality index of bauxite residue increased,and the relative soil quality index decreased from 1.89 to 0.15,which indicated that natural weathering had a significant effect on improveing the quality of bauxite residue and forming a new soil-like matrix.The diagnostic model of bauxite residue was established to provide data support for the regeneration on disposal area.展开更多
The huge volumes of crop residues generated during the production,processing,and consumption of farm products constitute an ecological nuisance when ineffectively managed.The conversion of crop residues to green hydro...The huge volumes of crop residues generated during the production,processing,and consumption of farm products constitute an ecological nuisance when ineffectively managed.The conversion of crop residues to green hydrogen is one of the sustainable management strategies for ubiquitous crop residues.Production of green hydrogen from crop residue sources will contribute to deepening access to clean and affordable energy,mitigating climate change,and ensuring environmental sustainability.However,the deployment of conventional thermochemical technologies for the conversion of crop residues to green hydrogen is costly,requires long residence time,produces low-quality products,and therefore needs to be upgraded.The current review examines the conventional,advanced,and integrated thermochemical conversion technologies for crop residues for green hydrogen production.After a brief overview of the conventional thermochemical techniques,the review delves into the broad narration of advanced thermochemical technologies including catalytic pyrolysis,microwave pyrolysis,co-pyrolysis,hyropyrolysis,and autothermal pyrolysis.The study advocates the deployment of integrated pyrolysis,anaerobic digestion,pyrolysis,and gasification technologies will ensure scalability,decomposition of recalcitrant feedstocks,and generation of high grade green hydrogen.The outlook provides suggestions for future research into cost-saving and sustainable integrated technologies for green hydrogen production towards achieving carbon neutrality and a circular bio-economy.展开更多
A model of continuous-time insider trading in which a risk-neutral in-sider possesses two imperfect correlated signals of a risky asset is studied.By conditional expectation theory and filtering theory,we first establ...A model of continuous-time insider trading in which a risk-neutral in-sider possesses two imperfect correlated signals of a risky asset is studied.By conditional expectation theory and filtering theory,we first establish three lemmas:normal corre-lation,equivalent pricing and equivalent profit,which can guarantee to turn our model into a model with insider knowing full information.Then we investigate the impact of the two correlated signals on the market equilibrium consisting of optimal insider trading strategy and semi-strong pricing rule.It shows that in the equilibrium,(1)the market depth is constant over time;(2)if the two noisy signals are not linerly correlated,then all private information of the insider is incorporated into prices in the end while the whole information on the asset value can not incorporated into prices in the end;(3)if the two noisy signals are linear correlated such that the insider can infer the whole information of the asset value,then our model turns into a model with insider knowing full information;(4)if the two noisy signals are the same then the total ex ant profit of the insider is increasing with the noise decreasing,while down to O as the noise going up to infinity;(5)if the two noisy signals are not linear correlated then with one noisy signal fixed,the total ex ante profit of the insider is single-peaked with a unique minimum with respect to the other noisy signal value,and furthermore as the noisy value going to O it gets its maximum,the profit in the case that the real value is observed.展开更多
基金Projects(41877511,41842020)supported by the National Natural Science Foundation of ChinaProject(502221703)supported by the Innovative Project of Independent Exploration of Central South University,China
文摘Bauxite residue deposit area(BRDA)is a typical abandoned mining wasteland representing extreme hostile environment with increased alkalinity.Microbially-driven neutralization of bauxite residue,based on the microbial acid producing metabolisms,is a novel strategy for achieving rapid pH neutralization and thus improving its environmental outcomes.The hypothesis was that these extreme conditions promote microbial communities which are capable of novel ecologically relevant functions.Several alkaliphilic acid producing bacteria were isolated in this study.One strain was selected for its superior growth pattern and acid metabolism(termed EEEL02).Based on the phylogenetic analysis,this strain was identified as Bacillus thuringiensis.The optimized fermentation conditions were as follows:pH 10;NaCl concentration 5%;temperature 25℃;EEEL02 preferred glucose and peptone as carbon and nitrogen sources,respectively.Based on optimal fermentation conditions,EEEL02 induced a significant pH reduction from 10.26 to 5.62 in 5-day incubation test.Acetic acid,propionic acid and CO2(g)were the major acid metabolites of fermentation,suggesting that the pH reduction in bauxite residue may be caused by acid neutralization derived from microbial metabolism.This finding provided the basis of a novel strategy for achieving rapid pH neutralization of bauxite residue.
基金supported by the National Key Research and Development Program of China(No.2019YFC1803604)the National Natural Science Foundation of China(Nos.41877511+1 种基金21707135)the Fundamental Research Funds for the Central Universities of Central South University。
文摘Bauxite residues,a large volume solid waste,are in urgent need of effective disposal and management.Especially,strategies to alleviate the high alkalinity of bauxite residue remain a big challenge.Here,we developed a synergistic pyrolysis to neutralize the alkalinity of bauxite residue and upgrade the structure of biomass simultaneously.By cooperating the catalytic feature from bauxite residue,rice straw,a cellulose-enriched biomass,could prefer to produce acidic components under a hypothermal pyrolysis temperature(below 250℃)and partial oxygen-contained atmosphere as evidenced by the synchronous TGA-FTIR analysis.In return,these in-situ produced acidic components neutralized the bauxite residue profoundly(pH decreased from 11.5 to 7.2)to obtain a neutral product with long-term water leaching stability.Also,a higher pyrolysis temperature led to neutral biochar-based products with well-defined carbonization characteristics.Thus,the biomass-driven pyrolysis strategy provides a potential to dispose the alkalinity issue of bauxite residue and further opportunities for the sustainable reuse and continuing management of bauxite residue.
文摘Aluminum is an important basic raw material for national economic development.The alumina industry has been expanding rapidly due to the increasing demand for aluminum.Bauxite residue is a highly alkaline solid by-product generated when alumina is extracted from bauxite ore in alumina refineries[1,2].
基金Project(41877511)supported by the National Natural Science Foundation of China
文摘Bauxite residue disposal areas(BRDAs)are physically degraded and hostile to plant growth.Nevertheless,natural plant colonization was observed in an abandoned BRDA in Central China.The pioneer plant species at the disposal area were identified,whilst distribution characteristics of salt ions such as Na^+,K^+,and Ca^2+in plant tissues and rhizosphere residues were investigated.The mean concentration of exchangeable Na^+in the rhizosphere soils was 19.5 cmol/kg,which suggested that these pioneer plants had relatively high salinity resistance.Sodium content varied from 0.84 cmol/kg(Digitaria sanguinalis)to 39.7 cmol/kg(Kochia scoparia),whilst K to Na ratio varied from 0.71(Myricaria bracteata)to 32.39(Digitaria sanguinalis)in the shoots,which demonstrated that the salinity tolerance mechanisms of these pioneer species differed significantly.Accumulation factors of Na^+in local plant species ranged from 0.04(D.sanguinalis)to 3.29(M.bracteata),whilst the translocation factor varied from 0.13(D.sanguinalis)to 2.92(M.bracteata).The results suggested that four pioneer plant species including K.scoparia,M.bracteate,Cynodon dactylon and D.sanguinalis could be suitable for revegetation at other disposal areas.
基金Project(41701587)supported by the National Natural Science Foundation of ChinaProject(PM-zx703-201803-057)supported by Basic Scientific Research Business of Central Institutes of Environmental Protection,China
文摘Revegetation on bauxite residue disposal areas is the most promising strategy to reduce its potential ecological risk during stacking or disposing.Migration of salt ions in bauxite residue is one of the major issues to stimulate soil formation to support plant growth.21 residue samples were collected and the related parameters including exchangeable cations,soluble ions,total salt,pH,electrical conductivity(EC)and exchangeable sodium percentage(ESP)were selected to evaluate alkalization and salinization of bauxite residue.High levels of ions,cation exchange capacity(TOC),total salt,exchangeable sodium percentage(ESP)and cation exchange capacity(CEC)in bauxite residue were detected with greater coefficient of variation(CV),which indicated that distribution characteristics of salt ions varied significantly.The percentage of sulfate-chloride-soda type in the residues accounted for 71.43%.The mean value of pH was 10.10,whilst mean value of ESP was 52.05%.It indicated that the residues in this case study belonged to sulfate-chloride-soda saline and alkaline soil.The research results could provide theoretical basis for soil formation in bauxite residue.
基金Projects(41877551,41842020)supported by the National Natural Science Foundation of China
文摘Vegetation encroachment occurred in bauxite residue disposal area(BRDA)following natural weathering processes,whilst the typical indicators of soil formation are still uncertain.Residue samples were collected from the BRDA in Central China,and related physical,chemical and biological indicators of bauxite residue with different storage years were determined.The indicators of soil formation in bauxite residue were selected using principal component analysis,factor analysis,and comprehensive evaluation to establish soil quality diagnostic index model on disposal areas.Following natural weathering processes,the texture of bauxite residue changed from silty loam to sandy loam.The pH and EC decreased,whilst porosity,nutrient element content and microbial biomass increased.The identified minimum data set(MDS)included available phosphorus(AP),moisture content(MC),C/N,sand content,total nitrogen(TN),microbial biomass carbon(MBC),and pH.The soil quality index of bauxite residue increased,and the relative soil quality index decreased from 1.89 to 0.15,which indicated that natural weathering had a significant effect on improveing the quality of bauxite residue and forming a new soil-like matrix.The diagnostic model of bauxite residue was established to provide data support for the regeneration on disposal area.
文摘The huge volumes of crop residues generated during the production,processing,and consumption of farm products constitute an ecological nuisance when ineffectively managed.The conversion of crop residues to green hydrogen is one of the sustainable management strategies for ubiquitous crop residues.Production of green hydrogen from crop residue sources will contribute to deepening access to clean and affordable energy,mitigating climate change,and ensuring environmental sustainability.However,the deployment of conventional thermochemical technologies for the conversion of crop residues to green hydrogen is costly,requires long residence time,produces low-quality products,and therefore needs to be upgraded.The current review examines the conventional,advanced,and integrated thermochemical conversion technologies for crop residues for green hydrogen production.After a brief overview of the conventional thermochemical techniques,the review delves into the broad narration of advanced thermochemical technologies including catalytic pyrolysis,microwave pyrolysis,co-pyrolysis,hyropyrolysis,and autothermal pyrolysis.The study advocates the deployment of integrated pyrolysis,anaerobic digestion,pyrolysis,and gasification technologies will ensure scalability,decomposition of recalcitrant feedstocks,and generation of high grade green hydrogen.The outlook provides suggestions for future research into cost-saving and sustainable integrated technologies for green hydrogen production towards achieving carbon neutrality and a circular bio-economy.
文摘A model of continuous-time insider trading in which a risk-neutral in-sider possesses two imperfect correlated signals of a risky asset is studied.By conditional expectation theory and filtering theory,we first establish three lemmas:normal corre-lation,equivalent pricing and equivalent profit,which can guarantee to turn our model into a model with insider knowing full information.Then we investigate the impact of the two correlated signals on the market equilibrium consisting of optimal insider trading strategy and semi-strong pricing rule.It shows that in the equilibrium,(1)the market depth is constant over time;(2)if the two noisy signals are not linerly correlated,then all private information of the insider is incorporated into prices in the end while the whole information on the asset value can not incorporated into prices in the end;(3)if the two noisy signals are linear correlated such that the insider can infer the whole information of the asset value,then our model turns into a model with insider knowing full information;(4)if the two noisy signals are the same then the total ex ant profit of the insider is increasing with the noise decreasing,while down to O as the noise going up to infinity;(5)if the two noisy signals are not linear correlated then with one noisy signal fixed,the total ex ante profit of the insider is single-peaked with a unique minimum with respect to the other noisy signal value,and furthermore as the noisy value going to O it gets its maximum,the profit in the case that the real value is observed.
