The anodic reaction kinetics of zinc electrowinning was investigated on the titanium base RuO2 anode in the system of Zn（Ⅱ）-NH3-NH4Cl-H2O. The effects of stirring speed, ammonium chloride concentration and temperat...The anodic reaction kinetics of zinc electrowinning was investigated on the titanium base RuO2 anode in the system of Zn（Ⅱ）-NH3-NH4Cl-H2O. The effects of stirring speed, ammonium chloride concentration and temperature on anodic reaction rate were studied through the curve measurement of potentiostatic polarization. The results reveal that the electrochemically controlled anodic reaction obeys Tafel equation and the anodic reaction order for ammonium chloride is 1.056, with the apparent activation energy of 40.17 kJ/mol. The general equation of anodic reaction kinetics was obtained.展开更多
The leaching kinetics of low grade zinc oxide ore in NH3-NH4Cl-H2O system was studied. The effects of ore particle size, reaction temperature and the sum concentration of ammonium ion and ammonia on the leaching effic...The leaching kinetics of low grade zinc oxide ore in NH3-NH4Cl-H2O system was studied. The effects of ore particle size, reaction temperature and the sum concentration of ammonium ion and ammonia on the leaching efficiency of zinc were examined. The leaching kinetics of low-grade zinc oxide ore in NH3-NH4Cl-H2O system follows the kinetic law of shrinking-core model. The results show that diffusion through the inert particle pores is the leaching kinetics rate controlling step. The calculated apparent activation energy of the process is about 7.057 kJ/mol. The leaching efficiency of zinc is 92.1% under the conditions of ore particle size of 69 μm, holding at 80 ℃ for 60 min, sum ammonia concentration of 7.5 mol/L, the molar ratio of ammonium to ammonia being 2-1, and the ratio (g/mL) of solid to liquid being 1-10.展开更多
文摘The anodic reaction kinetics of zinc electrowinning was investigated on the titanium base RuO2 anode in the system of Zn（Ⅱ）-NH3-NH4Cl-H2O. The effects of stirring speed, ammonium chloride concentration and temperature on anodic reaction rate were studied through the curve measurement of potentiostatic polarization. The results reveal that the electrochemically controlled anodic reaction obeys Tafel equation and the anodic reaction order for ammonium chloride is 1.056, with the apparent activation energy of 40.17 kJ/mol. The general equation of anodic reaction kinetics was obtained.
基金Project(2007CB613604) supported by the Major State Basic Research Development Program of ChinaProject(50674104) supported by the National Natural Science Foundation of ChinaProject(GJJ08279) supported by the Department of Education of Jiangxi Province
文摘The leaching kinetics of low grade zinc oxide ore in NH3-NH4Cl-H2O system was studied. The effects of ore particle size, reaction temperature and the sum concentration of ammonium ion and ammonia on the leaching efficiency of zinc were examined. The leaching kinetics of low-grade zinc oxide ore in NH3-NH4Cl-H2O system follows the kinetic law of shrinking-core model. The results show that diffusion through the inert particle pores is the leaching kinetics rate controlling step. The calculated apparent activation energy of the process is about 7.057 kJ/mol. The leaching efficiency of zinc is 92.1% under the conditions of ore particle size of 69 μm, holding at 80 ℃ for 60 min, sum ammonia concentration of 7.5 mol/L, the molar ratio of ammonium to ammonia being 2-1, and the ratio (g/mL) of solid to liquid being 1-10.
