Nanoscale bimetallic Ni/Fe particles were synthesized from the reaction of sodium borohydride (NaBH4) with reduction of Ni^2+ and Fe^2+ in aqueous solution. The obtained Ni/Fe particles were characterized by TEM ...Nanoscale bimetallic Ni/Fe particles were synthesized from the reaction of sodium borohydride (NaBH4) with reduction of Ni^2+ and Fe^2+ in aqueous solution. The obtained Ni/Fe particles were characterized by TEM (transmission electron microscope), XRD (X-ray diffractometer), and N2-BET. The dechlorination activity of the Ni/Fe was investigated using p-chlorophenol (p-CP) as a probe agent. Results demonstrated that the nanoscale Ni/Fe could effectively dechlorinate p-CP at relatively low metal to solution ratio of 0.4 g/L (Ni 5 wt%). The target with initial concentration ofp-CP 0.625 mmol/L was dechlorinted completely in 60 rain under ambient temperature and pressure. Factors affecting dechlorination efficiency, including reaction temperature, pH, Ni loading percentage over Fe, and metal to solution ratio, were investigated. The possible mechanism of dechlorination ofp-CP was proposed and discussed. The pseudo-first- order reaction took place on the surface of the Ni/Fe bimetallic particles, and the activation energy of the dechlorination reaction was determined to be 21.2 kJ/mol at the temperature rang of 287-313 K.展开更多
基金Project supported by the National Basic Research Program (973) of China(No. 2003CB415006)the National Natural Science Foundation of China (No. 20337020)
文摘Nanoscale bimetallic Ni/Fe particles were synthesized from the reaction of sodium borohydride (NaBH4) with reduction of Ni^2+ and Fe^2+ in aqueous solution. The obtained Ni/Fe particles were characterized by TEM (transmission electron microscope), XRD (X-ray diffractometer), and N2-BET. The dechlorination activity of the Ni/Fe was investigated using p-chlorophenol (p-CP) as a probe agent. Results demonstrated that the nanoscale Ni/Fe could effectively dechlorinate p-CP at relatively low metal to solution ratio of 0.4 g/L (Ni 5 wt%). The target with initial concentration ofp-CP 0.625 mmol/L was dechlorinted completely in 60 rain under ambient temperature and pressure. Factors affecting dechlorination efficiency, including reaction temperature, pH, Ni loading percentage over Fe, and metal to solution ratio, were investigated. The possible mechanism of dechlorination ofp-CP was proposed and discussed. The pseudo-first- order reaction took place on the surface of the Ni/Fe bimetallic particles, and the activation energy of the dechlorination reaction was determined to be 21.2 kJ/mol at the temperature rang of 287-313 K.
基金Project(51974048) supported by the National Natural Science Foundation of ChinaProject(CQBX202225) supported by Postdoctoral Innovation Talent Program of Chongqing,ChinaProject(CSTB2023NSCQ-BHX0166) supported by Natural Science Foundation of Chongqing,China。