Cobalt-free cathode materials are attractive for their high capacity and low cost,yet they still encounter issues with structural and surface instability.AlPO_(4),in particular,has garnered attention as an effective s...Cobalt-free cathode materials are attractive for their high capacity and low cost,yet they still encounter issues with structural and surface instability.AlPO_(4),in particular,has garnered attention as an effective stabilizer for bulk and surface.However,the impact of interfacial reactions and elemental interdiffusion between AlPO_(4) and LiNi_(0.95)Mn_(0.05)O_(2) upon sintering on the bulk and surface remains elusive.In this study,we demonstrate that during the heat treatment process,AlPO_(4) decomposes,resulting in Al doping into the bulk of the cathode through elemental interdiffusion.Simultaneously,PO_(4)^(3-)reacts with the surface Li of material to form a Li_3PO_(4) coating,inducing lithium deficiency,thereby increasing Li/Ni mixing.The suitable Li/Ni mixing,previously overlooked in AlPO_(4) modification,plays a pivotal role in stabilizing the bulk and surface,exceeding the synergy of Al doping and Li_3PO_(4) coating.The presence of Ni^(2+)ions in the lithium layers contributes to the stabilization of the delithiated structure via a structural pillar effect.Moreover,suitable Li/Ni mixing can stabilize the lattice oxygen and electrode-electrolyte interface by increasing oxygen removal energy and reducing the overlap between the Ni^(3+/4+)e_g and O^(2-)2p orbitals.These findings offer new perspectives for the design of stable cobalt-free cathode materials.展开更多
Magnesium and aluminum alloys are widely used in various industries because of their excellent properties,and their reliable connection may increase application of materials.Intermetallic compounds(IMCs)affect the joi...Magnesium and aluminum alloys are widely used in various industries because of their excellent properties,and their reliable connection may increase application of materials.Intermetallic compounds(IMCs)affect the joint performance of Mg/Al.In this study,AZ31 Mg alloy with/without a nickel(Ni)coating layer and 6061 Al alloy were joined by ultrasonic-assisted soldering with Sn-3.0Ag-0.5Cu(SAC)filler.The effects of the Ni coating layer on the microstructure and mechanical properties of Mg/Al joints were systematically investigated.The Ni coating layer had a significant effect on formation of the Mg_(2)Sn IMC and the mechanical properties of Mg/Al joints.The blocky Mg_(2)Sn IMC formed in the Mg/SAC/Al joints without a Ni coating layer.The content of the Mg_(2)Sn IMC increased with increasing soldering temperature,but the joint strength decreased.The joint without a Ni coating layer fractured at the blocky Mg_(2)Sn IMC in the solder,and the maximum shear strength was 32.2 MPa.By pre-plating Ni on the Mg substrate,formation of the blocky Mg_(2)Sn IMC was inhibited in the soldering temperature range 240–280℃and the joint strength increased.However,when the soldering temperature increased to 310℃,the blocky Mg_(2)Sn IMC precipitated again in the solder.Transmission electron microscopy showed that some nano-sized Mg_(2)Sn IMC and the(Cu,Ni)_(6)Sn_(5)phase formed in the Mg(Ni)/SAC/Al joint soldered at 280℃,indicating that the Ni coating layer could no longer prevent diffusion of Mg into the solder when the soldering temperature was higher than 280℃.The maximum shear strength of the Mg(Ni)/SAC/Al joint was 58.2 MPa for a soldering temperature of 280℃,which was 80.7%higher than that of the Mg/SAC/Al joint,and the joint was broken at the Mg(Ni)/SAC interface.Pre-plating Ni is a feasible way to inhibit formation of IMCs when joining dissimilar metals.展开更多
The outermost coating with single phase Ni2Al3 was obtained on copper surface by electrodepositing nickel followed by slurry pack aluminizing at 800 °C for 12 h. The oxidation resistance and microstructure of the...The outermost coating with single phase Ni2Al3 was obtained on copper surface by electrodepositing nickel followed by slurry pack aluminizing at 800 °C for 12 h. The oxidation resistance and microstructure of the coating oxidized in ambient air at 1000 °C for 25-250 h were investigated using SEM, X-ray diffraction and optical microscope methods. The results show that the copper with single phase Ni2Al3 coating possesses the best high temperature oxidation resistance, and the mass gain of the coating is 1/15 that of pure copper and 1/2 that of nickel coating, respectively. The specimen surface after being oxidized for 25 h still comprises Ni2Al3 phase. However, when the time of oxidizing treatment increases to 50 h, the Ni Al phase is formed. It is also found that the Ni2Al3 phase completely turns into Ni Al phase after oxidizing treatment for 100 h and above. The Ni Al coating shows excellent high temperature oxidation resistance when oxidation time is 250 h.展开更多
Ni coating was deposited on carbon steel by a mechanical attrition enhanced electroplating （MAEE） process. During the electroplating, the mechanical attrition（MA） was introduced by impact of glass balls on the sam...Ni coating was deposited on carbon steel by a mechanical attrition enhanced electroplating （MAEE） process. During the electroplating, the mechanical attrition（MA） was introduced by impact of glass balls on the sample surface with a special vibrating frequency. The surface and cross-sectional images of Ni coating were observed with SEM. The microstructure and crystallinity of coating were examined with TEM and XRD. The electrochemical performance of coating was measured with polarization curves and electrochemical impedance spectroscopy （EIS） and its mechanical behaviours, such as tensile strength and hardness, were studied. The results show that the MA has significant effects on the microstructure and property of the electroplated Ni coating. By MA, the coating becomes smooth, compact, thin and has refined grains and is free of cracks and pores. Consequently, the adhesion, tensile strength, hardness and corrosion resistance of coating are improved significantly.展开更多
Immersion experiment results show that corrosion rate of the as deposited RE Ni W P SiC composite coating in HCl solutions increases with the rise of HCl concentration. On the contrary, the corrosion rate of the compo...Immersion experiment results show that corrosion rate of the as deposited RE Ni W P SiC composite coating in HCl solutions increases with the rise of HCl concentration. On the contrary, the corrosion rate of the composite coating after heat treatment decreases with increasing HCl concentration. The corrosion rates of the composite coatings in as deposited state and after heat treatment in H 2SO 4 and H 3PO 4 solutions respectively decrease with the rise of H 2SO 4 and H 3PO 4 concentrations. The corrosion rate of the composite coating as deposited in FeCl 3 solutions decreases with increasing FeCl 3 concentration, while the rate of the composite coating after heat treatment increases with the rise of FeCl 3 concentration. The corrosion rate of 316L stainless steel in the corrosion media of H 2SO 4, HCl, H 3PO 4 and FeCl 3 solutions at different concentrations increases with rising concentration. In addition, the corrosion rate of 316L stainless steel in the corrosion media of H 2SO 4, HCl, H 3PO 4 and FeCl 3 solutions respectively is much greater than that of the RE Ni W P SiC composite coating as deposited and after heat treatment in the same corrosion media. [展开更多
The effects of rare earth (RE) on the composition, phase structures, surface morphologies and hardness of electrodeposited RE Ni W B SiC composite coatings were discussed. The results show that W and SiC contents in t...The effects of rare earth (RE) on the composition, phase structures, surface morphologies and hardness of electrodeposited RE Ni W B SiC composite coatings were discussed. The results show that W and SiC contents in the coatings increase with the increase of RE in the bath. When RE is added in the coatings, the grains are refined and the trend of formation of amorphous coatings is increased. Moreover, the thermal stability of the RE Ni W B SiC composite coatings is enhanced. The hardness of the coatings is increased with the increase of heat treatment temperature, and it reaches the peak value when heated at 400 ℃. Besides, the hardness of the RE Ni W B SiC coatings is higher than that of the Ni W B SiC coatings.展开更多
The components and microstructure of the RE Ni W P SiC composite coating were analyzed by means of EPXDS, SEM and XRD. The results showed that the composite coating containing 5%～14%RE, 4%～7%SiC, 12%～15%P and 5%～6...The components and microstructure of the RE Ni W P SiC composite coating were analyzed by means of EPXDS, SEM and XRD. The results showed that the composite coating containing 5%～14%RE, 4%～7%SiC, 12%～15%P and 5%～6%W was obtained by use of appropriate bath composition and plating conditions. The as deposited composite coating is amorphous and it becomes mixture when the temperature is raised from 200 ℃ to 400 ℃. However, the composite coating is crystal when the temperature is over 400 ℃. Scanning electron microscopy indicates that the heat treatment temperature has no effect on the surface morphologies of the RE Ni W P SiC composite coating. This is to say that the composite coating has a better heat stability of microstructure and high temperature oxidation.展开更多
To improve the low thermal conductivities and poor wear resistances of TC4(Ti-6Al-4V)alloy,the most widely used titanium alloy,the surface of TC4 alloys is modified by electroplating deposition of Ni and Cu layers,and...To improve the low thermal conductivities and poor wear resistances of TC4(Ti-6Al-4V)alloy,the most widely used titanium alloy,the surface of TC4 alloys is modified by electroplating deposition of Ni and Cu layers,and then heat-treated to increase the diffusivity at the interface.In this paper,the corrosion behavior of Cu/Ni coatings on TC4 alloy at different heat treatment processes was investigated in 3.5 wt%Na Cl by the electrochemical analysis,and the microstructure and composition of corrosion products was carried out to reveal the corrosion resistance mechanism of Cu/Ni coatings.It was found that the corrosion resistance was significantly influenced by heat treatment temperature.With the increasing diffusion treatment temperature from 500 to 700℃,the corrosion potential positively shifted from-330.87 to-201.14 m V,and the corrosion current density decreased from 4.02×10^-3 to 0.514×10^-3 m A/cm^2.However,when heat treatment temperature increased to 800℃,the corrosion potential negatively shifted to-207.21 m V,and the current density increased to 1.62×10^-3 m A/cm^2.The diffusion behavior of Ti,Ni and Cu elements occurred and small amounts of Ni and Ti elements appeared on the specimen surface under different heat treatment temperature.Especially heattreated at 700℃,the smaller pore size,dense Cu2O film,and highly stable Ti O and Ni O oxide layer were formed,which dramatically enhanced the corrosion resistance of Cu/Ni coatings.Finally,a novel model of corrosion resistance was proposed based on the analysis mentioned above.展开更多
The microstructure,microhardness,and corrosion resistance of laser cladding Ni−WC coating on the surface of AlSi5Cu1Mg alloy were investigated by scanning electron microscopy,X-ray diffraction,microhardness testing,im...The microstructure,microhardness,and corrosion resistance of laser cladding Ni−WC coating on the surface of AlSi5Cu1Mg alloy were investigated by scanning electron microscopy,X-ray diffraction,microhardness testing,immersion corrosion testing,and electrochemical measurement.The results show that a smooth coating containing NiAl,Ni_(3)Al,M_(7)C_(3),M_(23)C_(6)phases(M=Ni,Al,Cr,W,Fe)and WC particles is prepared by laser cladding.Under a laser scanning speed of 120 mm/min,the microhardness of the cladding coating is 9−11 times that of AlSi5Cu1Mg,due to the synergistic effect of excellent metallurgical bond and newly formed carbides.The Ni−WC coating shows higher corrosion potential(−318.09 mV)and lower corrosion current density(12.33μA/cm^(2))compared with the matrix.The crack-free,dense cladding coating obviously inhibits the penetration of Cl^(−)and H^(+),leading to the remarkedly improved corrosion resistance of cladding coating.展开更多
The wetting of molten Sn-3.5Ag-0.5Cu alloy on the Ni-P(-SiC)coated SiCp/Al substrates was investigated by electroless Ni plating process,and the microstructures of the coating and the interfacial behavior of wetting s...The wetting of molten Sn-3.5Ag-0.5Cu alloy on the Ni-P(-SiC)coated SiCp/Al substrates was investigated by electroless Ni plating process,and the microstructures of the coating and the interfacial behavior of wetting systems were analyzed.The SiC particles are evenly distributed in the coating and enveloped with Ni.No reaction layer is observed at the coating/SiCp/Al composite interfaces.The contact angle increases from^19°with the Ni-P coating to 29°,43°and 113°with the corresponding Ni-P-3SiC,Ni-P-6SiC and Ni-P-9SiC coatings,respectively.An interaction layer containing Cu,Ni,Sn and P forms at the Sn-Ag-Cu/Ni-P-(0,3,6)SiC coated SiCp/Al interfaces,and the Cu-Ni-Sn and Ni-Sn-P phases are detected in the interaction layer.Moreover,the molten Sn-Ag-Cu can penetrate into the Ni-P(-SiC)coatings through the Ni-P/SiC interface and dissolve them to contact the SiCp/Al substrate.展开更多
The φ pH diagram of Ni B H 2O system was drawn, and the mechanism of electrodepositing Ni B SiC composite coatings was discussed. The results show that the deposition of Ni and B occurs prior to that of H 2 because o...The φ pH diagram of Ni B H 2O system was drawn, and the mechanism of electrodepositing Ni B SiC composite coatings was discussed. The results show that the deposition of Ni and B occurs prior to that of H 2 because of the over potential of H 2 evolution on the Fe substrate. Boron can not singly deposit in aqueous solution. Nickel and boron can co deposit in the form of Ni 4B 3 without evolution of hydrogen when the cathodical potential is kept to be -1.415 ～ -1.700?V.展开更多
基金financial support from the Natural Science Foundation of Shandong Province (ZR2022QB140)the PhD Initiation Program of Liaocheng University (318052138)the Natural Science Foundation of Shandong Province (ZR2023MB002 and ZR2021MB114)。
文摘Cobalt-free cathode materials are attractive for their high capacity and low cost,yet they still encounter issues with structural and surface instability.AlPO_(4),in particular,has garnered attention as an effective stabilizer for bulk and surface.However,the impact of interfacial reactions and elemental interdiffusion between AlPO_(4) and LiNi_(0.95)Mn_(0.05)O_(2) upon sintering on the bulk and surface remains elusive.In this study,we demonstrate that during the heat treatment process,AlPO_(4) decomposes,resulting in Al doping into the bulk of the cathode through elemental interdiffusion.Simultaneously,PO_(4)^(3-)reacts with the surface Li of material to form a Li_3PO_(4) coating,inducing lithium deficiency,thereby increasing Li/Ni mixing.The suitable Li/Ni mixing,previously overlooked in AlPO_(4) modification,plays a pivotal role in stabilizing the bulk and surface,exceeding the synergy of Al doping and Li_3PO_(4) coating.The presence of Ni^(2+)ions in the lithium layers contributes to the stabilization of the delithiated structure via a structural pillar effect.Moreover,suitable Li/Ni mixing can stabilize the lattice oxygen and electrode-electrolyte interface by increasing oxygen removal energy and reducing the overlap between the Ni^(3+/4+)e_g and O^(2-)2p orbitals.These findings offer new perspectives for the design of stable cobalt-free cathode materials.
基金financial support from the National Natural Science Foundation of China(grant numbers 52275385 and U2167216)the Sichuan Province Science and Technology Support Program(grant number 2022YFG0086)。
文摘Magnesium and aluminum alloys are widely used in various industries because of their excellent properties,and their reliable connection may increase application of materials.Intermetallic compounds(IMCs)affect the joint performance of Mg/Al.In this study,AZ31 Mg alloy with/without a nickel(Ni)coating layer and 6061 Al alloy were joined by ultrasonic-assisted soldering with Sn-3.0Ag-0.5Cu(SAC)filler.The effects of the Ni coating layer on the microstructure and mechanical properties of Mg/Al joints were systematically investigated.The Ni coating layer had a significant effect on formation of the Mg_(2)Sn IMC and the mechanical properties of Mg/Al joints.The blocky Mg_(2)Sn IMC formed in the Mg/SAC/Al joints without a Ni coating layer.The content of the Mg_(2)Sn IMC increased with increasing soldering temperature,but the joint strength decreased.The joint without a Ni coating layer fractured at the blocky Mg_(2)Sn IMC in the solder,and the maximum shear strength was 32.2 MPa.By pre-plating Ni on the Mg substrate,formation of the blocky Mg_(2)Sn IMC was inhibited in the soldering temperature range 240–280℃and the joint strength increased.However,when the soldering temperature increased to 310℃,the blocky Mg_(2)Sn IMC precipitated again in the solder.Transmission electron microscopy showed that some nano-sized Mg_(2)Sn IMC and the(Cu,Ni)_(6)Sn_(5)phase formed in the Mg(Ni)/SAC/Al joint soldered at 280℃,indicating that the Ni coating layer could no longer prevent diffusion of Mg into the solder when the soldering temperature was higher than 280℃.The maximum shear strength of the Mg(Ni)/SAC/Al joint was 58.2 MPa for a soldering temperature of 280℃,which was 80.7%higher than that of the Mg/SAC/Al joint,and the joint was broken at the Mg(Ni)/SAC interface.Pre-plating Ni is a feasible way to inhibit formation of IMCs when joining dissimilar metals.
基金Projects(CKJB201205,QKJB201202,YJK201307)supported by the Nanjing Institute of Technology,China
文摘The outermost coating with single phase Ni2Al3 was obtained on copper surface by electrodepositing nickel followed by slurry pack aluminizing at 800 °C for 12 h. The oxidation resistance and microstructure of the coating oxidized in ambient air at 1000 °C for 25-250 h were investigated using SEM, X-ray diffraction and optical microscope methods. The results show that the copper with single phase Ni2Al3 coating possesses the best high temperature oxidation resistance, and the mass gain of the coating is 1/15 that of pure copper and 1/2 that of nickel coating, respectively. The specimen surface after being oxidized for 25 h still comprises Ni2Al3 phase. However, when the time of oxidizing treatment increases to 50 h, the Ni Al phase is formed. It is also found that the Ni2Al3 phase completely turns into Ni Al phase after oxidizing treatment for 100 h and above. The Ni Al coating shows excellent high temperature oxidation resistance when oxidation time is 250 h.
基金Project (51172102/E020801) supported by the National Natural Science Foundation of ChinaProject (31805) supported by Doctoral Fund of Liaocheng University, China
文摘Ni coating was deposited on carbon steel by a mechanical attrition enhanced electroplating （MAEE） process. During the electroplating, the mechanical attrition（MA） was introduced by impact of glass balls on the sample surface with a special vibrating frequency. The surface and cross-sectional images of Ni coating were observed with SEM. The microstructure and crystallinity of coating were examined with TEM and XRD. The electrochemical performance of coating was measured with polarization curves and electrochemical impedance spectroscopy （EIS） and its mechanical behaviours, such as tensile strength and hardness, were studied. The results show that the MA has significant effects on the microstructure and property of the electroplated Ni coating. By MA, the coating becomes smooth, compact, thin and has refined grains and is free of cracks and pores. Consequently, the adhesion, tensile strength, hardness and corrosion resistance of coating are improved significantly.
文摘Immersion experiment results show that corrosion rate of the as deposited RE Ni W P SiC composite coating in HCl solutions increases with the rise of HCl concentration. On the contrary, the corrosion rate of the composite coating after heat treatment decreases with increasing HCl concentration. The corrosion rates of the composite coatings in as deposited state and after heat treatment in H 2SO 4 and H 3PO 4 solutions respectively decrease with the rise of H 2SO 4 and H 3PO 4 concentrations. The corrosion rate of the composite coating as deposited in FeCl 3 solutions decreases with increasing FeCl 3 concentration, while the rate of the composite coating after heat treatment increases with the rise of FeCl 3 concentration. The corrosion rate of 316L stainless steel in the corrosion media of H 2SO 4, HCl, H 3PO 4 and FeCl 3 solutions at different concentrations increases with rising concentration. In addition, the corrosion rate of 316L stainless steel in the corrosion media of H 2SO 4, HCl, H 3PO 4 and FeCl 3 solutions respectively is much greater than that of the RE Ni W P SiC composite coating as deposited and after heat treatment in the same corrosion media. [
文摘The effects of rare earth (RE) on the composition, phase structures, surface morphologies and hardness of electrodeposited RE Ni W B SiC composite coatings were discussed. The results show that W and SiC contents in the coatings increase with the increase of RE in the bath. When RE is added in the coatings, the grains are refined and the trend of formation of amorphous coatings is increased. Moreover, the thermal stability of the RE Ni W B SiC composite coatings is enhanced. The hardness of the coatings is increased with the increase of heat treatment temperature, and it reaches the peak value when heated at 400 ℃. Besides, the hardness of the RE Ni W B SiC coatings is higher than that of the Ni W B SiC coatings.
文摘The components and microstructure of the RE Ni W P SiC composite coating were analyzed by means of EPXDS, SEM and XRD. The results showed that the composite coating containing 5%～14%RE, 4%～7%SiC, 12%～15%P and 5%～6%W was obtained by use of appropriate bath composition and plating conditions. The as deposited composite coating is amorphous and it becomes mixture when the temperature is raised from 200 ℃ to 400 ℃. However, the composite coating is crystal when the temperature is over 400 ℃. Scanning electron microscopy indicates that the heat treatment temperature has no effect on the surface morphologies of the RE Ni W P SiC composite coating. This is to say that the composite coating has a better heat stability of microstructure and high temperature oxidation.
基金Funded by Key Projects of Shaanxi Natural Science Foundation(No.2019JZ-27)Shaanxi Natural Science Basic Research Program-Shaanxi Coal(No.2019JLM-47)Fundamental Research Funds for the Central Universities CHD(No.300102319304).
文摘To improve the low thermal conductivities and poor wear resistances of TC4(Ti-6Al-4V)alloy,the most widely used titanium alloy,the surface of TC4 alloys is modified by electroplating deposition of Ni and Cu layers,and then heat-treated to increase the diffusivity at the interface.In this paper,the corrosion behavior of Cu/Ni coatings on TC4 alloy at different heat treatment processes was investigated in 3.5 wt%Na Cl by the electrochemical analysis,and the microstructure and composition of corrosion products was carried out to reveal the corrosion resistance mechanism of Cu/Ni coatings.It was found that the corrosion resistance was significantly influenced by heat treatment temperature.With the increasing diffusion treatment temperature from 500 to 700℃,the corrosion potential positively shifted from-330.87 to-201.14 m V,and the corrosion current density decreased from 4.02×10^-3 to 0.514×10^-3 m A/cm^2.However,when heat treatment temperature increased to 800℃,the corrosion potential negatively shifted to-207.21 m V,and the current density increased to 1.62×10^-3 m A/cm^2.The diffusion behavior of Ti,Ni and Cu elements occurred and small amounts of Ni and Ti elements appeared on the specimen surface under different heat treatment temperature.Especially heattreated at 700℃,the smaller pore size,dense Cu2O film,and highly stable Ti O and Ni O oxide layer were formed,which dramatically enhanced the corrosion resistance of Cu/Ni coatings.Finally,a novel model of corrosion resistance was proposed based on the analysis mentioned above.
文摘The microstructure,microhardness,and corrosion resistance of laser cladding Ni−WC coating on the surface of AlSi5Cu1Mg alloy were investigated by scanning electron microscopy,X-ray diffraction,microhardness testing,immersion corrosion testing,and electrochemical measurement.The results show that a smooth coating containing NiAl,Ni_(3)Al,M_(7)C_(3),M_(23)C_(6)phases(M=Ni,Al,Cr,W,Fe)and WC particles is prepared by laser cladding.Under a laser scanning speed of 120 mm/min,the microhardness of the cladding coating is 9−11 times that of AlSi5Cu1Mg,due to the synergistic effect of excellent metallurgical bond and newly formed carbides.The Ni−WC coating shows higher corrosion potential(−318.09 mV)and lower corrosion current density(12.33μA/cm^(2))compared with the matrix.The crack-free,dense cladding coating obviously inhibits the penetration of Cl^(−)and H^(+),leading to the remarkedly improved corrosion resistance of cladding coating.
基金Projects(51572112,51401034)supported by the National Natural Science Foundation of ChinaProject(BK20151340)supported by the Natural Science Foundation of Jiangsu Province,China+3 种基金Projects(2014-XCL-002,TD-XCL-004)supported by the Six Talent Peaks Project of Jiangsu Province,ChinaProject(BRA2017387)supported by the 333 Talents Project of Jiangsu Province,ChinaProject([2015]26)supported by the Innovation/Entrepreneurship Program of Jiangsu Province,ChinaProject([2016]15)supported by the Qing Lan Project,China
文摘The wetting of molten Sn-3.5Ag-0.5Cu alloy on the Ni-P(-SiC)coated SiCp/Al substrates was investigated by electroless Ni plating process,and the microstructures of the coating and the interfacial behavior of wetting systems were analyzed.The SiC particles are evenly distributed in the coating and enveloped with Ni.No reaction layer is observed at the coating/SiCp/Al composite interfaces.The contact angle increases from^19°with the Ni-P coating to 29°,43°and 113°with the corresponding Ni-P-3SiC,Ni-P-6SiC and Ni-P-9SiC coatings,respectively.An interaction layer containing Cu,Ni,Sn and P forms at the Sn-Ag-Cu/Ni-P-(0,3,6)SiC coated SiCp/Al interfaces,and the Cu-Ni-Sn and Ni-Sn-P phases are detected in the interaction layer.Moreover,the molten Sn-Ag-Cu can penetrate into the Ni-P(-SiC)coatings through the Ni-P/SiC interface and dissolve them to contact the SiCp/Al substrate.
文摘The φ pH diagram of Ni B H 2O system was drawn, and the mechanism of electrodepositing Ni B SiC composite coatings was discussed. The results show that the deposition of Ni and B occurs prior to that of H 2 because of the over potential of H 2 evolution on the Fe substrate. Boron can not singly deposit in aqueous solution. Nickel and boron can co deposit in the form of Ni 4B 3 without evolution of hydrogen when the cathodical potential is kept to be -1.415 ～ -1.700?V.
