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Recovery Stress in a Ni-Ti-Nb Shape Memory Alloy with Wide Transformation Hysteresis 被引量:4
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作者 Wei CAI Chunsheng ZHANG and Liancheng ZHAO(Harbin Institute of Technology, Harbin, 150006, China) 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 1994年第1期27-30,共4页
The effect of deformation on recovery stress of Ni144.7Ti46.3Nb9 alloy has been studjed using tensile test at various temperatures and TEM observation. It ls shown that the recovery stress increases with jncreasing to... The effect of deformation on recovery stress of Ni144.7Ti46.3Nb9 alloy has been studjed using tensile test at various temperatures and TEM observation. It ls shown that the recovery stress increases with jncreasing total strain ET and reaches a maximum value (max) as ET= 9% but the maximum recov erV strain of the alloy is only about 4.6%. This is different from that of Ti-Ni binary alloy in which is obtained usually at maximum recovery strain and the reason of the difference is dis Cussed. Deformation temperature Td has a little effect on recovery stress when Td is less than Ms However, recovery stress decreases sharply when Td is higher than M, and lowers approximately down to zero near Msσ 展开更多
关键词 ti WIDE Recovery Stress in a ni-ti-Nb shape memory alloy with Wide Transformation Hysteresis HL Ni
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EFFECTS OF HEAT TREATMENT ON TENSILE PROPERTIES AND SHAPE MEMORY EFFECTS OF Ni-Ti-Nb ALLOY 被引量:2
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作者 Zheng Yufeng, Cai Wei, Luo Yichun, Zhao Liancheng School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001 《中国有色金属学会会刊:英文版》 CSCD 1997年第4期93-97,共5页
EFFECTSOFHEATTREATMENTONTENSILEPROPERTIESANDSHAPEMEMORYEFFECTSOFNiTiNbALLOY①ZhengYufeng,CaiWei,LuoYichun,Z... EFFECTSOFHEATTREATMENTONTENSILEPROPERTIESANDSHAPEMEMORYEFFECTSOFNiTiNbALLOY①ZhengYufeng,CaiWei,LuoYichun,ZhaoLianchengSchoo... 展开更多
关键词 Ni ti Nb alloy HEAT treatment TENSILE PROPERtiES shape memory effect
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Two-way Shape Memory Effect in a Ti-Ni-Nb Shape Memory Alloy with Wide Hysteresis 被引量:1
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作者 Liming WANG Xianglong MENG Wei CAI and Liancheng ZHAO School of Materials Science and Engineering, Harbin institute of Technology, Harbin 150001, China 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2001年第1期13-14,共2页
A two-way shape memory effect (TWSM E) in the Ti46.3Ni44.7Nb9 alloy has been systematically investigated by means of bending test and transmission electron microscopy (TEM ) observations. Based on the analysis of the ... A two-way shape memory effect (TWSM E) in the Ti46.3Ni44.7Nb9 alloy has been systematically investigated by means of bending test and transmission electron microscopy (TEM ) observations. Based on the analysis of the microstructure after training. the mechanism of TWSME in the Ti46.3 Ni44.7Nb9 alloy has been discussed. 展开更多
关键词 ti NI Two-way shape memory Effect in a ti-ni-Nb shape memory alloy with Wide Hysteresis WIDE
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REVERSIBLE TRANSFORMATION BETWEEN MATRIX AND MARTENSITE IN Ni-Ti SHAPE MEMORY ALLOYS 被引量:1
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作者 HASHIMOTO Hatsujiro 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 1991年第6期453-457,共5页
The reversible transformation between matrix and martensite in Ni-Ti shape memory alloys has been dynamically observed under TEM.The orientation relation between martensite and austenite as well as the structural chan... The reversible transformation between matrix and martensite in Ni-Ti shape memory alloys has been dynamically observed under TEM.The orientation relation between martensite and austenite as well as the structural change near the transition temperature has been also studied with the help of HREM SADP.The results show that the orientation relation between martensite and austenite is[11]_A//[10]_M,[110]_A//[001]_M,(110)_A//(001)_M and the angle between(110)_A and(010)_M is about 6.5°.The crystal defects of martensite are found to be twin and stacking fault,and the twin plane as(100). 展开更多
关键词 ni-ti alloy martensitic transformation shape memory effect
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Relationship between phase composition and corrosion resistance of Ni-Ti-Nb based shape memory alloys
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作者 董治中 刘文西 +1 位作者 贾 堤 王德法 《中国有色金属学报》 EI CAS CSCD 北大核心 2001年第z1期118-120,共5页
The stability and microstructure of Ni Ti Nb based shape memory alloys were investigated after alloyed with elements Zr, Cr and V. In artificial seawater (3.5%NaCl) and physiological solution (5%NaCl+0.1%H 2O 2), the ... The stability and microstructure of Ni Ti Nb based shape memory alloys were investigated after alloyed with elements Zr, Cr and V. In artificial seawater (3.5%NaCl) and physiological solution (5%NaCl+0.1%H 2O 2), the results show that the alloying elements influence the corrosion behavior of Ni Ti Nb alloys. Generally, Zr improves the corrosion resistance of Ni Ti Nb alloy, Cr reduces its corrosion resistance and V does not change the property. In order to investigate the reason of the difference,the relation of the phase components and corrosion resistance of Ni Ti Nb based shape memory alloys were studied by element analysis and SEM. 展开更多
关键词 Ni ti Nb corrosion resistance phase components shape memory alloy
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Incomplete transformation of Ti-Ni-X ternary shape memory alloy
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作者 何向明 张淑芳 +3 位作者 李明升 多树旺 向军淮 张荣发 《中国有色金属学会会刊:英文版》 CSCD 2006年第A02期6-9,共4页
关键词 ti-ni-X三元合金 形状记忆合金 温度记忆效应 不完全转变
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Modeling of Ni_4Ti_3 precipitation during stress-free and stress-assisted aging of bi-crystalline NiTi shape memory alloys
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作者 柯常波 曹姗姗 +1 位作者 马骁 张新平 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2012年第10期2578-2585,共8页
The phase field method was applied to study the microstructure evolution of Ni4Ti3 precipitates during stress-free and stress-assisted aging of bi-crystalline NiTi shape memory alloys (SAMs) with two different initi... The phase field method was applied to study the microstructure evolution of Ni4Ti3 precipitates during stress-free and stress-assisted aging of bi-crystalline NiTi shape memory alloys (SAMs) with two different initial Ni-contents of 51.5% and 52.5% (mole fraction), respectively. The simulation results show that, during stress-free aging of the NiTi alloy with a low supersaturation of Ni (i.e., Ti-51.5%Ni), the Ni4Ti3 precipitates exhibit a heterogeneous distribution with a high number density of particles at the grain boundary, leaving most of the grain interiors free of precipitates; while for the NiTi alloy with a high supersaturation of Ni (i.e., Ti-52.5%Ni), the Ni4Ti3 precipitates show a homogeneous distribution across the entire simulation system. The stress-assisted aging can give rise to homogeneous distribution of the precipitates, regardless of the initial Ni-content; however, the distribution of variant type within the two grains is heterogeneous. 展开更多
关键词 Niti shape memory alloy Ni4ti3 precipitate low-angle grain boundary martensitic transformation phase field simulation
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Martensite Aging Effect and Thermal Cyclic Characteristics in Ti-Pd and Ti-Pd-Ni High Temperature Shape Memory Alloys 被引量:2
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作者 Wei Cai School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 15000k, China Kazuhiro Otsuka Institute of Materials Science, University of Tsukuba, Tsukuba, Ibaraki 305-8573, Japan E-mail: weicai@hope.hit.edu.cn 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2001年第3期359-362,共4页
The effect of thermal cycling and aging in martensitic state in Ti-Pd-Ni alloys were investigated by DSC and TEM observations. It is shown that the thermal cycling causes the decreases in M, and Af temperatures in Ti5... The effect of thermal cycling and aging in martensitic state in Ti-Pd-Ni alloys were investigated by DSC and TEM observations. It is shown that the thermal cycling causes the decreases in M, and Af temperatures in Ti50Pd50-xNix (x=10, 20, 30) alloys, but no obvious thermal cycling effect was observed in Ti50Pd50Pd40Ni10 alloys and the aging effect shows a curious feature, i.e., the Af temperature does not saturate even after relatively long time aging, which is considered to be due to the occurrence of recovery recrystallization during aging. 展开更多
关键词 ti Martensite Aging Effect and Thermal Cyclic Characteristics in ti-Pd and ti-Pd-Ni High Temperature shape memory alloys PD Ni
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Transformation behavior and shape memory effect of Ti_(50-x)Ni_(48)Fe_2Nb_x alloys by aging treatment 被引量:5
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作者 Xu, Qing Liu, Fushun 《Rare Metals》 SCIE EI CAS CSCD 2012年第4期311-317,共7页
The influence of aging treatment on transformation behavior and shape memory of the Ti 50_x Ni_(48) Fe_2 Nb_x(x=0,0.6,0.8,1.0,and 1.2) alloys was investigated using differential scanning calorimeter(DSC),mechanical dr... The influence of aging treatment on transformation behavior and shape memory of the Ti 50_x Ni_(48) Fe_2 Nb_x(x=0,0.6,0.8,1.0,and 1.2) alloys was investigated using differential scanning calorimeter(DSC),mechanical drawing machine,and microhardness tester in this paper.It is indicated that the aging treatment has a significant effect on the phase transformation temperatures(M_s,M_f,M_p,A_s,A_f,and A_p) and microhardness of the samples.The phase transformation temperatures are found to decrease initially with the increasing aging temperature from 300 to 500 ℃ and increase with further increase of the aging temperature.The aging treatment at intermediate temperature between 400 and 500 ℃ results in an improved shape memory effect.In addition,the highest microhardness value is also obtained. 展开更多
关键词 ti-ni-Fe-Nb shape memory alloys martensitic transformation aging treatment phase transformation temperature
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Effect of Pre-strain on the Transformation and Recovery Behaviours of a Ti_(44)Ni_(47)Nb_9 Shape Memory Alloy 被引量:2
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作者 Wei JIN, Mingzhou GAO, Rui YANG and Zhuangqi HU Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China E-mail: wjin@imr.ac.cn 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2001年第3期318-320,共3页
The recovery strain, stress and transformation temperature of different pre-strained specimens of Ti44Ni47Nb9 were investigated by tensile test and electrical resistance measurement. The results indicated that pre-str... The recovery strain, stress and transformation temperature of different pre-strained specimens of Ti44Ni47Nb9 were investigated by tensile test and electrical resistance measurement. The results indicated that pre-strain increases the reverse martensitic transformation temperature (A ' (s)) and hysteresis (A(s) - M-s). The recovery strain and stress are higher if the specimens are pre-strained between M-s and A(s) temperature than outside this temperature range. There exists an optimal pre-strain value, about 10%, at which the specimen exhibits maximum recovery strain and stress. 展开更多
关键词 Nb9 shape memory alloy Effect of Pre-strain on the Transformation and Recovery Behaviours of a ti Ni
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Characteristics of Deformation and Recovery in Shape Memory Alloy 被引量:1
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作者 WeiJLN YingYAN +2 位作者 JianWANG MingzhouCAO RuiYANG 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2004年第5期605-608,共4页
The mechanical behavior and the effect of pre-strain on recovery behavior of Ti50Ni47Fe3 (at. pct) alloy were investigated systematically by tensile and recovered tests accompanied by electrical resistance measurement... The mechanical behavior and the effect of pre-strain on recovery behavior of Ti50Ni47Fe3 (at. pct) alloy were investigated systematically by tensile and recovered tests accompanied by electrical resistance measurement. Ti50Ni47Fe3 alloy has different deformation behaviors at different temperature ranges, the deformation curves in different temperature range can be classified into four kinds. The start temperature of recovery increases with the increase of pre-strain. There exists an optimal deformation condition, at which the specimen exhibits maximum free recovery strain. With increasing pre-strain the recovery stress increases and reaches the maximum at 8% pre-strain. R-phase to parent transition offered about 0.2% recovery strain. With pre-strain increasing the recovery stress increases and reaches to the maximum at 8% pre-strain. The recovery stress is corresponding with the critical stress of stress-induced martensitic transformation. 展开更多
关键词 DEFORMAtiON Recovery stress Recovery strain ti50Ni47Fe3 shape memory alloy
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Shape Memory Effect of As-aged Fe-14Mn-5Si-8Cr-4Ni-0.2C Alloy 被引量:1
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作者 Yuhua WEN, Ning LI and Mingjing TU (Department of Materials Shaping and Controlling Engineering, Sichuan University, Chengdu 610065, China) 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2000年第4期424-426,共3页
The effects of aging temperature on shape memory effect, mechanical properties and microstruc-ture of Fe-14Mn-5Si-8Cr-4Ni-0.2C shape memory alloy have been studied. The results showed that the second phase particles r... The effects of aging temperature on shape memory effect, mechanical properties and microstruc-ture of Fe-14Mn-5Si-8Cr-4Ni-0.2C shape memory alloy have been studied. The results showed that the second phase particles rich in chromium, manganese and silicon precipitate during aging, and thereby increase the hardness and strength of the alloy. The shape recovery ratio can be remarkably improved by aging and a maximum value can be obtained at 1223 K, which is 68% higher than that of the specimen in solid solution state. When the aging temperature is below 1223 K, the amount of second phase particles increases as the aging temperature increases. The size of austenite grain increases with increasing aging temperature. When the temperature is over 1223 K, the second phase particles can not precipitate. The lack of second phase particles and the increase of grain size make the hardness and shape recovery ratio drastically decrease, when the temperature is over 1223 K. 展开更多
关键词 MN shape memory Effect of As-aged Fe-14Mn-5Si-8Cr-4ni-0.2C alloy As FE CR NI Si
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Thermal stability and high-temperature shape memory characteristics of Ti-20Zr-10Ta alloy 被引量:1
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作者 郑晓航 隋解和 +2 位作者 张欣 杨哲一 蔡伟 《Chinese Physics B》 SCIE EI CAS CSCD 2014年第1期466-469,共4页
The microstructure, martensite transformation behavior, thermal stability and shape memory behavior of Ti–20Zr– 10Ta high temperature shape memory alloy were investigated. The Ti–20Zr–10Ta alloy exhibited a revers... The microstructure, martensite transformation behavior, thermal stability and shape memory behavior of Ti–20Zr– 10Ta high temperature shape memory alloy were investigated. The Ti–20Zr–10Ta alloy exhibited a reversible transformation with the high martensite transformation temperature of 500oC and good thermal stability. The alloy displayed the elongation of 15% and a maximum recovery stain of 5.5% with 8% pre-strain. 展开更多
关键词 ti–Zr–Ta alloy martensite transformation high temperature shape memory effect thermal stabil-ity
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Microstructure and Mechanical Properties of Cross-rolled Ti_(50)Ni_(47)Fe_3 Shape Memory Alloy
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作者 ZHAO Li-xiao LIU Fu-shun XU Hui-bin 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2006年第B12期224-227,共4页
The microstructures, the phase transformation characteristics, and the mechanical properties of the Ti50Ni47Fe3 alloy in as-forged and as-cross-rolled states were investigated. It is found that, after cross-rolling, t... The microstructures, the phase transformation characteristics, and the mechanical properties of the Ti50Ni47Fe3 alloy in as-forged and as-cross-rolled states were investigated. It is found that, after cross-rolling, the phase transformation temperature (Ms) of the alloy decreases drastically and the grains get refined. Moreover, its yield strength and fracture strength after cross-rolling hit 540 MPa and 687 MPa respectively, up by about 200 MPa over those in as-forged state. 展开更多
关键词 ti50Ni47Fe3 shape memory alloy cross-rolled mechanical properties
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ORDERING OF VACANCIES IN RAPIDLYQUENCHED TiNi SHAPE MEMORY ALLOY
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作者 WANG Shidong LAM Cheungching +2 位作者 SHEN Guangjun ZHANG Jinping WU Xiaozhen (Southeast University, Nanjing,China)(City Polytechnic of Hong Kong, Hong Kong) 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 1995年第3期162-166,共5页
The modification of the electron diffraction pattern(EDP) of B2 in an as rapidly quenched then short time aged Ti Ni shape memory alloy(SMA) has been studied systematically using TEM. It was found that the diffusio... The modification of the electron diffraction pattern(EDP) of B2 in an as rapidly quenched then short time aged Ti Ni shape memory alloy(SMA) has been studied systematically using TEM. It was found that the diffusion scattering rings in EDP of an as rapidly quenched Ti-Ni SMA is associated with short range order (SRO) of vancancies in parent B2. After aging at 450℃ for 5 min the diffusion scattering rings are replaced by 1/2 {001} and 1 / 4 {012} extra reflections. It indicates that the SRO of vacancies has transformed into long range order (LRO) of vacancies,moreover,the LRO of vacancies exists in microdomains. 展开更多
关键词 ti Ni shape memory alloy vacancy order electron diffraction
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Thermodynamic Analysis on Relation Between T_0 and σ_M in a Ti_(44)Ni_(47)Nb_9 Shape Memory Alloy
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作者 WeiJIN ShaoyuQIU 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2002年第6期538-540,共3页
The effect of heat treatment on martensitic transformation behavior has been investigated in Ti44Ni47Nb9 alloy. The relation between transformation temperatures and critical stress of stress induced martensitic transf... The effect of heat treatment on martensitic transformation behavior has been investigated in Ti44Ni47Nb9 alloy. The relation between transformation temperatures and critical stress of stress induced martensitic transformation is interpreted in terms of thermodynamic theory. It is shown that the decrease in transformation temperature in specimens of slow cooling rate or low temperature aging after solution heat treatment results from the changes of Ni/Ti ratio in the matrix. The increase of critical stress of stress induced martensitic transformation is a consequence of the decrease of transformation temperatures. 展开更多
关键词 ti44Ni47Nb9 shape memory alloy TRANSFORMAtiON THERMODYNAMICS
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Experimental investigation of the cyclic degradation of the one-way shape memory effect of NiTi alloys
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作者 Tian-xing Zhao Guo-zheng Kang +1 位作者 Chao Yu Qian-hua Kan 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2019年第12期1539-1550,共12页
Based on stress-and strain-controlled cyclic tension-unloading-heat-cooling tests,cyclic degradation of the one-way shape memory effect(OWSME)of NiTi shape memory alloys(SMAs)was investigated.It was seen,in thermo-mec... Based on stress-and strain-controlled cyclic tension-unloading-heat-cooling tests,cyclic degradation of the one-way shape memory effect(OWSME)of NiTi shape memory alloys(SMAs)was investigated.It was seen,in thermo-mechanical coupled cyclic tests,that residual strain after each cycle accumulated,but the martensite reorientation stress and dissipation energy-per-cycle decreased as the number of cycles increased.Meanwhile,the cyclic degradation of OWSME was aggravated by increasing the stress/strain amplitude.In addition,the stress-strain response of NiTi SMAs was further investigated by performing simultaneous thermo-mechanical coupled cyclic tests with various phase-angle differences between the mechanical and thermal cyclic loadings.It can be concluded that such cyclic response depends significantly on prescribed phase-angle differences.Obtained experimental results are helpful for both the development of constitutive models and engineering applications of NiTi SMAs. 展开更多
关键词 NIti shape memory alloys one-way shape memory effect CYCLIC degradation THERMO-MECHANICAL coupling MARTENSITE orientation
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HIGH TEMPERATURE SHAPE MEMORY EFFECT AND PRE-DEFORMATION FOR Ti_(50) Ni_(13) Pd_(37) ALLOY
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作者 LI Yongsen JIN Yongbai YU Ronghai Institute of Metal Research,Academia Sinica,Shenyang,China Associate Professor,Institute of Metal Research,Academia Sinica,110015 Shenyang 110015,China 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 1990年第5期338-341,共4页
The dependence of high temperature shape memory effect on the pre-deformation tempera- ture of the Ti_(50)Ni_3Pd_(37) alloy has been studied.This alloy,of which the reverse transformation start temperature on heating ... The dependence of high temperature shape memory effect on the pre-deformation tempera- ture of the Ti_(50)Ni_3Pd_(37) alloy has been studied.This alloy,of which the reverse transformation start temperature on heating is 620 K,has both one-way and two-way shape memory effects. The maximum shape memory strain of the ahoy may be obtained under pre-deformation in the range of 620 to 640 K.This seems to be related to the minimum recoverable strain energy emerged from the above mentioned temperature range. 展开更多
关键词 ti-ni-Pd alloy shape memory effect shape memory strain recoverable strain energy
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Electrochemical behavior of Ti-Ni shape memory alloy in fibrinogen solution
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作者 梁成浩 郭海霞 陈邦义 《中国有色金属学会会刊:英文版》 CSCD 2004年第1期33-36,共4页
Electrochemical behaviors of Ti Ni shape memory alloy in fibrinogen solution were studied by electrochemical techniques. The results indicate that the addition of the fibrinogen has no obvious effect on the corrosion ... Electrochemical behaviors of Ti Ni shape memory alloy in fibrinogen solution were studied by electrochemical techniques. The results indicate that the addition of the fibrinogen has no obvious effect on the corrosion potential, but decreases the pitting potential markedly and increases the passive current densities. The analysis of energy dispersive X ray for samples adsorbing fibrinogen exhibits that the elements of O, C and N exist on the surface of Ti Ni alloy. Furthermore, the scanning electron microscope micrographs confirm that the configuration of the adsorbing fibrinogen concentrating on surface defects is like cluster and the fibrinogen adsorption concentration is 96.67 mg/m 2 through ultroviolet ray absorption method. Fibrinogen combined with Ti Ni alloy surface by complex band and its electrochemical transfer accelerated the corrosion of alloy. 展开更多
关键词 ti-NI合金 形状记忆合金 金属间化合物 电化学性能 血纤维蛋白原溶液 腐蚀
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R-phase transformation of aged Ti-Ni shape memory alloy
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作者 宫长伟 王轶农 +1 位作者 杨大智 刘晓鹏 《中国有色金属学会会刊:英文版》 EI CSCD 2005年第6期1237-1241,共5页
Ti-50.6Ni(molar fraction, %) shape memory alloy solution treated at 850℃ for 1h followed by ageing treatment at 450℃ for 3h was studied with differential scanning calorimetry(DSC), X-ray diffractometry(XR... Ti-50.6Ni(molar fraction, %) shape memory alloy solution treated at 850℃ for 1h followed by ageing treatment at 450℃ for 3h was studied with differential scanning calorimetry(DSC), X-ray diffractometry(XRD) and transmission electron microscopy(TEM). DSC measurement reveals two separate transformation peaks. XRD and TEM demonstrate that a three-stage transformation occurs. The Ti3Ni4 precipitates are coherent with the R-phase. The crystal structure of R-phase was analyzed by two diffraction patterns method. The diffraction patterns of R-phase were obtained in detail from the same region. 展开更多
关键词 ti-NI合金 形状记忆合金 R相转变 钛合金
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