Surface notches lower the stiffness of laminated strips, so they lower the buckling loads of the laminated strips, too. In this paper a new method is proposed to predict the buckling loads of the laminated strips with...Surface notches lower the stiffness of laminated strips, so they lower the buckling loads of the laminated strips, too. In this paper a new method is proposed to predict the buckling loads of the laminated strips with a surface notch. The theoretical and experimental results show that the buckling loads decrease as the depth or width of the surface notches increase; when the stacking sequence of the laminated strips is [0°/0°/+ θ/-θ/0°/0°/+θ/-θ] s , the buckling load decrease as θ increases. It proves that the method is reliable and significant.展开更多
Semi-solid powder rolling(SSPR) is a novel strip manufacturing process,which includes the features of semi-solid rolling and powder rolling.In this work,densification process and deformation mechanisms of B4 C and A...Semi-solid powder rolling(SSPR) is a novel strip manufacturing process,which includes the features of semi-solid rolling and powder rolling.In this work,densification process and deformation mechanisms of B4 C and AA2024 mixed powders in the presence of liquid phase were investigated.The relationships between relative densities and rolling forces were analyzed as well.The results show that liquid fraction plays an important role in the densification process which can be divided into three stages.Rolling deformation is the main densification mechanism in deformation area when the liquid fraction is lower than 20%.When the liquid fraction is equal to or higher than 20%,the flowing and filling of liquid phase are the densification mechanisms in deformation area.The relative densities increase with increasing rolling forces.The relative density–rolling force curves are similar at 550 °C and 585 °C.The characteristics of the curve shapes are apparently different at 605 °C and 625 °C.展开更多
In this paper,more than 70 large-scale pullout tests were performed to evaluate the performance of an innovative composite geosynthetic strip(CGS)reinforcement in sandy backfill.The CGS reinforcement is composed of a ...In this paper,more than 70 large-scale pullout tests were performed to evaluate the performance of an innovative composite geosynthetic strip(CGS)reinforcement in sandy backfill.The CGS reinforcement is composed of a geosynthetic strip(GS)and parts of a scrap truck tire as transverse members.The experimental pullout results for the CGS reinforcement were compared with the suggested theoretical equations and ordinary reinforcements,including the GS,the steel strip(SS),and the steel strip with rib(SSR).The pullout test results show that adding three transverse members to the GS reinforcement(CGS3)with S/H?6.6(where S and H are the space and height of the transverse members,respectively)increases pullout resistance by more than 120%,170%,and 50%compared to the GS,the SS,and the SSR,respectively.This result shows that the CGS3(CGS with three transverse members)reinforcement needs at least 55.5%,63%,and 33.3%smaller length compared to the GS,the SS,and the SSR,respectively.In general,implementation of mechanically stabilized earth wall(MSEW)with the proposed strip may help geotechnical engineers prevent costly designs and solve the problem of MSEW implementation in cases where there are limitations of space.展开更多
In this paper an experimental study on damage tolerance behaviour of composite panels with softening strips is carried out. A prediction method of residual strength of panels with softening strips is proposed. The com...In this paper an experimental study on damage tolerance behaviour of composite panels with softening strips is carried out. A prediction method of residual strength of panels with softening strips is proposed. The comparison between estimated and experimental results shows that the prediction method can be applied to design. In this paper the failure mechanisms are described.展开更多
A numerical method of integration of Green's functions of strip element method (SEM) is proposed The response of ultrasonic source generated by a transducer on the surface of a multi ply composite plate contain...A numerical method of integration of Green's functions of strip element method (SEM) is proposed The response of ultrasonic source generated by a transducer on the surface of a multi ply composite plate containing a delamination is analyzed by the use of SEM The numerical results show that the scanning features of the ultrasonic waves may be used to identify the delamination inside the composite plate.展开更多
The principle, formula and determination of internal stresses of metal multilayer composite coatings by means of the bending strip method were studied. Using this method, internal stresses of ion-plated metal multilay...The principle, formula and determination of internal stresses of metal multilayer composite coatings by means of the bending strip method were studied. Using this method, internal stresses of ion-plated metal multilayer composite coatings and thick monolayer coating of aluminium bronze, stainless steel and nickel-iron alloy were determined. The reason of decrement in internal stresses of multilayer composite coatings was discussed.展开更多
The graphene-gold nanoparticles composite film modified glassy carbon electrode (EG- AuNPs/GCE) was prepared by one-step coelectrodeposition and employed for determination of trace mercury in environmental water wit...The graphene-gold nanoparticles composite film modified glassy carbon electrode (EG- AuNPs/GCE) was prepared by one-step coelectrodeposition and employed for determination of trace mercury in environmental water with differential pulse stripping voltammetry. Such a nanostructured composite film combined with the advantages of gold nanoparticles and graphene, can greatly promote the electron-transfer process and increase accumulation abil-ity for Hg(Ⅱ), leading to a remarkably improved sensitivity. The linear calibration curve ranged from 0.2 μg/L to 30 μg/L for Hg(Ⅱ) and the detection limit (S/N=3) was found to be 0.03 μg/L at a deposition time of 300 s. Moreover, the stablity of the as-prepared electrode and interferences from other substances were evaluated. The modified electrode was successfully applied to the direct detection of Hg(Ⅱ) in real water samples.展开更多
Electrodeposited Ni matrix/Al microparticles or nanoparticles dispersed composite coatings (termed as EMCCs or ENCCs) are developed from a Ni-based electrolyte bath. The Al microparticles are in a size range of 1 -5 ...Electrodeposited Ni matrix/Al microparticles or nanoparticles dispersed composite coatings (termed as EMCCs or ENCCs) are developed from a Ni-based electrolyte bath. The Al microparticles are in a size range of 1 -5 μm and the Al nanoparticles in an average size of 75 nm. The Al content in coatings increases with increase in the particle content in the bath. Particle size effect on the degree of codeposition is not significant. However, codeposition of Al nanoparticles instead of microparticles promotes more homogenous growth of Ni deposits on {111}, {200} and {220} planes. The oxidation at 1 050 ℃ of the as-deposited composite coatings shows that at a comparable Al content, ENCC of Ni-Al exhibits a better oxidation resistance than EMCC of Ni-Al due to the fast formation of an alumina scale during the transient stage of oxidation.展开更多
Powder charges of micron-size Ni and Al2O3were utilized to deposit nano-structured Ni-Al2O3composite coatings on analuminum plate fixed at the top end of a milling vial using a planetary ball mill.Composite coatings w...Powder charges of micron-size Ni and Al2O3were utilized to deposit nano-structured Ni-Al2O3composite coatings on analuminum plate fixed at the top end of a milling vial using a planetary ball mill.Composite coatings were fabricated using powdermixtures with a wide range of Ni/Al2O3mass ratio varying from1:1to plain Ni.XRD,SEM and TEM techniques were employed tostudy the structural characteristics of the coatings.It was found that the composition of the starting mixture strongly affects the Al2O3content and the microstructure of the final coating.Mixtures containing higher contents of Al2O3yield higher volume fractions of theAl2O3particles in the coating.Though Ni-Al2O3composite coatings with about50%of Al2O3particles were successfully deposited,well-compacted and free of cracks and/or voids coatings included less than20%(volume fraction)of Al2O3particles which weredeposited from powder mixtures with Ni/Al2O3mass ratios of4:1or higher.Moreover,mechanical and metallurgical bondings arethe main mechanisms of the adhesion of the coating to the Al substrate.Finally,functionally graded composite coatings withnoticeable compaction and integrity were produced by deposition of two separate layers under identical coating conditions.展开更多
A novel nickel stripper using ammonia as the key component was developed to substitute cyanide for removing nickel film from iron substrates. Its compositions are: ammonia 150 g/L, hydrogen peroxide 50 g/L, ammonium c...A novel nickel stripper using ammonia as the key component was developed to substitute cyanide for removing nickel film from iron substrates. Its compositions are: ammonia 150 g/L, hydrogen peroxide 50 g/L, ammonium chloride 100 g/L, EDTA 7.5 g/L, copper chloride 15 g/L and glucopyrone 1.2 g/L. The optimum operating conditions are: pH 9.511, temperature 4050 ℃ and stripping time 1 h. It shows many advantages over the traditional cyanide stripper including no toxicity, mild operation, lower cost, larger holding capacity, faster stripping rate and good protection for the base metal, and can meet the technical requirements in industry.展开更多
We report the near-stoichiometric Ti:LiNbO3 strip waveguides fabricated by vapour transport equilibration (VTE) at 1060~^{/circ}C for 12 h and co-diffusion of 4--8~/mu m wide, 115-nm thick Ti-strips. Optical stud...We report the near-stoichiometric Ti:LiNbO3 strip waveguides fabricated by vapour transport equilibration (VTE) at 1060~^{/circ}C for 12 h and co-diffusion of 4--8~/mu m wide, 115-nm thick Ti-strips. Optical studies show that these waveguides are monomode at 1.5~/mu m and have losses of 1.3 and 1.1~dB/cm for the TM and TE modes, respectively. In the waveguide width/depth direction, the mode field follows a Gauss/Hermite--Gauss profile. A secondary ion mass spectrometry study reveals that the Ti profile follows a sum of two error functions along the width direction and a complementary error function in the depth direction. Micro-Raman analysis shows that the Li-composition in the depth direction also follows a complementary error function. The mean Li/Nb ratio in the waveguide layer is about 0.98. The inhomogeneous Li-composition profile results in a varied substrate index in the guiding layer, and the refractive index profile in the guiding layer is given.展开更多
To completely solve the problem of fatigue cracking issue of orthotropic steel bridge decks(OSDs),the authors proposed a steel–ultra-high performance concrete(UHPC)lightweight composite deck(LWCD)with closed ribs in ...To completely solve the problem of fatigue cracking issue of orthotropic steel bridge decks(OSDs),the authors proposed a steel–ultra-high performance concrete(UHPC)lightweight composite deck(LWCD)with closed ribs in 2010.Based on the successful application of that LWCD,an adaptation incorporating an innovative composite deck structure,i.e.,the hot-rolled section steel–UHPC composite deck with open ribs(SSD)is proposed in this paper,aiming to simplify the fabrication process as well as to reduce the cost of LWCD.Based on a long-span cable-stayed bridge,a design scheme is proposed and is compared with the conventional OSD scheme.Further,a finite element(FE)calculation is conducted to reflect both the global and local behavior of the SSD scheme,and it is found that the peaked stresses in the SSD components are less than the corresponding allowable values.A static test is performed for an SSD strip specimen to understand the anti-cracking behavior of the UHPC layer under negative bending moments.The static test results indicate that the UHPC layer exhibited a satisfactory tensile toughness,the UHPC tensile strength obtained from the test is 1.8 times the calculated stress by the FE model of the real bridge.In addition,the fatigue stresses of typical fatigue-prone details in the SSD are calculated and evaluated,and the influences of key design parameters on the fatigue performance of the SSD are analyzed.According to the fatigue results,the peaked stress ranges for all of the 10 fatigue-prone details are within the corresponding constant amplitude fatigue limits.Then a fatigue test is carried out for another SSD strip specimen to explore the fatigue behavior of the fillet weld between the longitudinal and transverse ribs.The specimen failed at the fillet weld after equivalent 47.5 million cycles of loading under the design fatigue stress range,indicating that the fatigue performance of the SSD could meet the fatigue design requirement.Theoretical calculations and experiments provide a basis for the promotion and application of this structure in bridge engineering.展开更多
A stable lithium-metal anode is critical for high performance lithium-metal batteries. However, heterogeneous Li plating/stripping may induce lithium dendrites formation on bare lithium-metal anode, which lowers the c...A stable lithium-metal anode is critical for high performance lithium-metal batteries. However, heterogeneous Li plating/stripping may induce lithium dendrites formation on bare lithium-metal anode, which lowers the cell Coulombic efficiency and weakens battery safety. We found that bare Li metal surface becomes bumpy and cratered with numerous pits formation during Li stripping. These pits enhance electric field distortion and heterogeneous ion distribution during plating. Li plating preferentially happens on the edge of the pits, intensifying the voltage variation and Li dendrites growth, which leads to the cell rapid death or separator piercing. Herein, we propose a facile and mass-producible method to homogenize Li plating/stripping via adding lithiophilic particles into Li metal. Zinc particles were uniformly pressed in Li metal by a facile and scalable physical strategy of “rolling”, and transformed into LiZn alloy in situ through Li-Zn alloying at room temperature in a few minutes. The critical role of modified LiZn/Li composite anode in stabilizing electrode surface was revealed by both electrochemical test and simulation. Compared with bare Li anode, the evenly dispersed LiZn alloy particles in Li metal can effectively regulate the Li plating/stripping on electrode surface, reducing deepness of pits during stripping and directionally inducing Li plating to maintain electrode surface stability. On this basis, the pits depth of LiZn/Li composite during Li stripping is reduced to ∼ 15 μm, which is much shallower than that of bare Li metal of ∼ 40 μm. The LiZn/Li composite electrode can stably cycle for 600 h under Li plating/stripping capacity of 1 mAh·cm−2 and current density of 1 mA·cm−2 without any short circuit. Furthermore, assembled LiZn/Li||LiFePO4 full cell presents better cycling stability and rate performances than that of based on bare Li anode.展开更多
文摘Surface notches lower the stiffness of laminated strips, so they lower the buckling loads of the laminated strips, too. In this paper a new method is proposed to predict the buckling loads of the laminated strips with a surface notch. The theoretical and experimental results show that the buckling loads decrease as the depth or width of the surface notches increase; when the stacking sequence of the laminated strips is [0°/0°/+ θ/-θ/0°/0°/+θ/-θ] s , the buckling load decrease as θ increases. It proves that the method is reliable and significant.
基金Project(2013KJCX0014)supported by the Key Project of Department of Education of Guangdong Province,China
文摘Semi-solid powder rolling(SSPR) is a novel strip manufacturing process,which includes the features of semi-solid rolling and powder rolling.In this work,densification process and deformation mechanisms of B4 C and AA2024 mixed powders in the presence of liquid phase were investigated.The relationships between relative densities and rolling forces were analyzed as well.The results show that liquid fraction plays an important role in the densification process which can be divided into three stages.Rolling deformation is the main densification mechanism in deformation area when the liquid fraction is lower than 20%.When the liquid fraction is equal to or higher than 20%,the flowing and filling of liquid phase are the densification mechanisms in deformation area.The relative densities increase with increasing rolling forces.The relative density–rolling force curves are similar at 550 °C and 585 °C.The characteristics of the curve shapes are apparently different at 605 °C and 625 °C.
文摘In this paper,more than 70 large-scale pullout tests were performed to evaluate the performance of an innovative composite geosynthetic strip(CGS)reinforcement in sandy backfill.The CGS reinforcement is composed of a geosynthetic strip(GS)and parts of a scrap truck tire as transverse members.The experimental pullout results for the CGS reinforcement were compared with the suggested theoretical equations and ordinary reinforcements,including the GS,the steel strip(SS),and the steel strip with rib(SSR).The pullout test results show that adding three transverse members to the GS reinforcement(CGS3)with S/H?6.6(where S and H are the space and height of the transverse members,respectively)increases pullout resistance by more than 120%,170%,and 50%compared to the GS,the SS,and the SSR,respectively.This result shows that the CGS3(CGS with three transverse members)reinforcement needs at least 55.5%,63%,and 33.3%smaller length compared to the GS,the SS,and the SSR,respectively.In general,implementation of mechanically stabilized earth wall(MSEW)with the proposed strip may help geotechnical engineers prevent costly designs and solve the problem of MSEW implementation in cases where there are limitations of space.
文摘In this paper an experimental study on damage tolerance behaviour of composite panels with softening strips is carried out. A prediction method of residual strength of panels with softening strips is proposed. The comparison between estimated and experimental results shows that the prediction method can be applied to design. In this paper the failure mechanisms are described.
基金This project is supported by National Natural Science Foundation of China(No19872011).
文摘A numerical method of integration of Green's functions of strip element method (SEM) is proposed The response of ultrasonic source generated by a transducer on the surface of a multi ply composite plate containing a delamination is analyzed by the use of SEM The numerical results show that the scanning features of the ultrasonic waves may be used to identify the delamination inside the composite plate.
文摘The principle, formula and determination of internal stresses of metal multilayer composite coatings by means of the bending strip method were studied. Using this method, internal stresses of ion-plated metal multilayer composite coatings and thick monolayer coating of aluminium bronze, stainless steel and nickel-iron alloy were determined. The reason of decrement in internal stresses of multilayer composite coatings was discussed.
文摘The graphene-gold nanoparticles composite film modified glassy carbon electrode (EG- AuNPs/GCE) was prepared by one-step coelectrodeposition and employed for determination of trace mercury in environmental water with differential pulse stripping voltammetry. Such a nanostructured composite film combined with the advantages of gold nanoparticles and graphene, can greatly promote the electron-transfer process and increase accumulation abil-ity for Hg(Ⅱ), leading to a remarkably improved sensitivity. The linear calibration curve ranged from 0.2 μg/L to 30 μg/L for Hg(Ⅱ) and the detection limit (S/N=3) was found to be 0.03 μg/L at a deposition time of 300 s. Moreover, the stablity of the as-prepared electrode and interferences from other substances were evaluated. The modified electrode was successfully applied to the direct detection of Hg(Ⅱ) in real water samples.
文摘Electrodeposited Ni matrix/Al microparticles or nanoparticles dispersed composite coatings (termed as EMCCs or ENCCs) are developed from a Ni-based electrolyte bath. The Al microparticles are in a size range of 1 -5 μm and the Al nanoparticles in an average size of 75 nm. The Al content in coatings increases with increase in the particle content in the bath. Particle size effect on the degree of codeposition is not significant. However, codeposition of Al nanoparticles instead of microparticles promotes more homogenous growth of Ni deposits on {111}, {200} and {220} planes. The oxidation at 1 050 ℃ of the as-deposited composite coatings shows that at a comparable Al content, ENCC of Ni-Al exhibits a better oxidation resistance than EMCC of Ni-Al due to the fast formation of an alumina scale during the transient stage of oxidation.
文摘Powder charges of micron-size Ni and Al2O3were utilized to deposit nano-structured Ni-Al2O3composite coatings on analuminum plate fixed at the top end of a milling vial using a planetary ball mill.Composite coatings were fabricated using powdermixtures with a wide range of Ni/Al2O3mass ratio varying from1:1to plain Ni.XRD,SEM and TEM techniques were employed tostudy the structural characteristics of the coatings.It was found that the composition of the starting mixture strongly affects the Al2O3content and the microstructure of the final coating.Mixtures containing higher contents of Al2O3yield higher volume fractions of theAl2O3particles in the coating.Though Ni-Al2O3composite coatings with about50%of Al2O3particles were successfully deposited,well-compacted and free of cracks and/or voids coatings included less than20%(volume fraction)of Al2O3particles which weredeposited from powder mixtures with Ni/Al2O3mass ratios of4:1or higher.Moreover,mechanical and metallurgical bondings arethe main mechanisms of the adhesion of the coating to the Al substrate.Finally,functionally graded composite coatings withnoticeable compaction and integrity were produced by deposition of two separate layers under identical coating conditions.
文摘A novel nickel stripper using ammonia as the key component was developed to substitute cyanide for removing nickel film from iron substrates. Its compositions are: ammonia 150 g/L, hydrogen peroxide 50 g/L, ammonium chloride 100 g/L, EDTA 7.5 g/L, copper chloride 15 g/L and glucopyrone 1.2 g/L. The optimum operating conditions are: pH 9.511, temperature 4050 ℃ and stripping time 1 h. It shows many advantages over the traditional cyanide stripper including no toxicity, mild operation, lower cost, larger holding capacity, faster stripping rate and good protection for the base metal, and can meet the technical requirements in industry.
基金supported by the National Natural Science Foundation of China (Grant Nos. 50872089 and 60577012)the Research Grants Council of the Hong Kong Special Administrative Region, China (Grant No. CityU 1194/07)
文摘We report the near-stoichiometric Ti:LiNbO3 strip waveguides fabricated by vapour transport equilibration (VTE) at 1060~^{/circ}C for 12 h and co-diffusion of 4--8~/mu m wide, 115-nm thick Ti-strips. Optical studies show that these waveguides are monomode at 1.5~/mu m and have losses of 1.3 and 1.1~dB/cm for the TM and TE modes, respectively. In the waveguide width/depth direction, the mode field follows a Gauss/Hermite--Gauss profile. A secondary ion mass spectrometry study reveals that the Ti profile follows a sum of two error functions along the width direction and a complementary error function in the depth direction. Micro-Raman analysis shows that the Li-composition in the depth direction also follows a complementary error function. The mean Li/Nb ratio in the waveguide layer is about 0.98. The inhomogeneous Li-composition profile results in a varied substrate index in the guiding layer, and the refractive index profile in the guiding layer is given.
基金The authors gratefully thank the National Natural Science Foundation of China(Grant Nos.52038003 and 51778223)Technology R&D Plan of China Construction Fifth Engineering Division Co.,Ltd.(No.CSCES5b-2022-12)for their financial support.
文摘To completely solve the problem of fatigue cracking issue of orthotropic steel bridge decks(OSDs),the authors proposed a steel–ultra-high performance concrete(UHPC)lightweight composite deck(LWCD)with closed ribs in 2010.Based on the successful application of that LWCD,an adaptation incorporating an innovative composite deck structure,i.e.,the hot-rolled section steel–UHPC composite deck with open ribs(SSD)is proposed in this paper,aiming to simplify the fabrication process as well as to reduce the cost of LWCD.Based on a long-span cable-stayed bridge,a design scheme is proposed and is compared with the conventional OSD scheme.Further,a finite element(FE)calculation is conducted to reflect both the global and local behavior of the SSD scheme,and it is found that the peaked stresses in the SSD components are less than the corresponding allowable values.A static test is performed for an SSD strip specimen to understand the anti-cracking behavior of the UHPC layer under negative bending moments.The static test results indicate that the UHPC layer exhibited a satisfactory tensile toughness,the UHPC tensile strength obtained from the test is 1.8 times the calculated stress by the FE model of the real bridge.In addition,the fatigue stresses of typical fatigue-prone details in the SSD are calculated and evaluated,and the influences of key design parameters on the fatigue performance of the SSD are analyzed.According to the fatigue results,the peaked stress ranges for all of the 10 fatigue-prone details are within the corresponding constant amplitude fatigue limits.Then a fatigue test is carried out for another SSD strip specimen to explore the fatigue behavior of the fillet weld between the longitudinal and transverse ribs.The specimen failed at the fillet weld after equivalent 47.5 million cycles of loading under the design fatigue stress range,indicating that the fatigue performance of the SSD could meet the fatigue design requirement.Theoretical calculations and experiments provide a basis for the promotion and application of this structure in bridge engineering.
基金This work is financially supported by the China Postdoctoral Science Foundation(No.2020M672268)the National Natural Science Foundations of China(Nos.5190070667,51807180,and 52002358).
文摘A stable lithium-metal anode is critical for high performance lithium-metal batteries. However, heterogeneous Li plating/stripping may induce lithium dendrites formation on bare lithium-metal anode, which lowers the cell Coulombic efficiency and weakens battery safety. We found that bare Li metal surface becomes bumpy and cratered with numerous pits formation during Li stripping. These pits enhance electric field distortion and heterogeneous ion distribution during plating. Li plating preferentially happens on the edge of the pits, intensifying the voltage variation and Li dendrites growth, which leads to the cell rapid death or separator piercing. Herein, we propose a facile and mass-producible method to homogenize Li plating/stripping via adding lithiophilic particles into Li metal. Zinc particles were uniformly pressed in Li metal by a facile and scalable physical strategy of “rolling”, and transformed into LiZn alloy in situ through Li-Zn alloying at room temperature in a few minutes. The critical role of modified LiZn/Li composite anode in stabilizing electrode surface was revealed by both electrochemical test and simulation. Compared with bare Li anode, the evenly dispersed LiZn alloy particles in Li metal can effectively regulate the Li plating/stripping on electrode surface, reducing deepness of pits during stripping and directionally inducing Li plating to maintain electrode surface stability. On this basis, the pits depth of LiZn/Li composite during Li stripping is reduced to ∼ 15 μm, which is much shallower than that of bare Li metal of ∼ 40 μm. The LiZn/Li composite electrode can stably cycle for 600 h under Li plating/stripping capacity of 1 mAh·cm−2 and current density of 1 mA·cm−2 without any short circuit. Furthermore, assembled LiZn/Li||LiFePO4 full cell presents better cycling stability and rate performances than that of based on bare Li anode.