用正交实验研究了Ni La P电沉积的最佳工艺条件,以此合金作阴极测得析氢阴极极化曲线,结果表明,合金电极上析氢速率比Ni电极上约大10倍,析氢电势正移300～400mV,显示出含稀土La的镍基合金具有较高的析氢电催化活性。根据XPS谱图讨论... 用正交实验研究了Ni La P电沉积的最佳工艺条件,以此合金作阴极测得析氢阴极极化曲线,结果表明,合金电极上析氢速率比Ni电极上约大10倍,析氢电势正移300～400mV,显示出含稀土La的镍基合金具有较高的析氢电催化活性。根据XPS谱图讨论了析氢电催化的机理。展开更多
The electrodeposition of Ni-La-P alloy from aqueous solutions of citric acid,phosphorous acid and ammonium chloride has been studied by linear sweep voltammetry. The electroplating potentials of the metallic ions were...The electrodeposition of Ni-La-P alloy from aqueous solutions of citric acid,phosphorous acid and ammonium chloride has been studied by linear sweep voltammetry. The electroplating potentials of the metallic ions were found shifted to positive region in the presence of complexing agent and phosphorous acid and the Ni2+ ions were favorable for induction of deposition. XPS records indicated the alloy’s composition mass fraction as Ni 92, La 2. 15, and P 5. 85.展开更多
Ni-P and Ni-P-La alloy coatings were prepared by electroplating. Electromagnetic shielding effectiveness under the different components of rare earth or the different operating conditions was tested by the network ana...Ni-P and Ni-P-La alloy coatings were prepared by electroplating. Electromagnetic shielding effectiveness under the different components of rare earth or the different operating conditions was tested by the network analyzer. The results show that electromagnetic shielding effectiveness of Ni-P-La alloy coating varies from 45 dB to 70 dB with the variety of the frequency from 10 MHz to 350 MHz. Corrosion of the salt fog impacts on the electromagnetic shielding effectiveness a little. A small amount of rare earth added to plating bath can not only enhance corrosion resistance of coating, but make electromagnetic shielding effectiveness increase by 1 ~ 5 dB.展开更多
The structure and electrochemical properties of the La0.7Mg0.3Ni3.4-xMn0.1Cox （x=01.05） hydrogen storage alloys were investigated. The crystal structure and the lattice parameters of the alloys were analyzed by X-ra...The structure and electrochemical properties of the La0.7Mg0.3Ni3.4-xMn0.1Cox （x=01.05） hydrogen storage alloys were investigated. The crystal structure and the lattice parameters of the alloys were analyzed by X-ray diffractometry and Rietveld method. Electrochemical properties of the alloys including p—c—t curves, discharge capacity, discharge capacity retention were studied. The results show that （La, Mg）Ni3 and LaNi5 are the main phases of all the alloys. The plateau pressure for hydrogen absorption/desorption decreases and the hydrogen storage capacity firstly increases and subsequently decreases with increasing Co content. The values of the maximum discharge capacity of the alloy electrodes remain in range of 395.3403.1mA·h/g in spite of the change of Co content. The cycling stability of the alloy electrodes is greatly improved with increasing Co content, which is attributed to the suppression of the cell volume expansion during hydriding, leading the pulverization of the alloy particles lowered and the oxidation/corrosion of the active elements reduced.展开更多
文摘The electrodeposition of Ni-La-P alloy from aqueous solutions of citric acid,phosphorous acid and ammonium chloride has been studied by linear sweep voltammetry. The electroplating potentials of the metallic ions were found shifted to positive region in the presence of complexing agent and phosphorous acid and the Ni2+ ions were favorable for induction of deposition. XPS records indicated the alloy’s composition mass fraction as Ni 92, La 2. 15, and P 5. 85.
基金Project supported by Anhui Province Natural Science Foundation (050440603)
文摘Ni-P and Ni-P-La alloy coatings were prepared by electroplating. Electromagnetic shielding effectiveness under the different components of rare earth or the different operating conditions was tested by the network analyzer. The results show that electromagnetic shielding effectiveness of Ni-P-La alloy coating varies from 45 dB to 70 dB with the variety of the frequency from 10 MHz to 350 MHz. Corrosion of the salt fog impacts on the electromagnetic shielding effectiveness a little. A small amount of rare earth added to plating bath can not only enhance corrosion resistance of coating, but make electromagnetic shielding effectiveness increase by 1 ~ 5 dB.
文摘The structure and electrochemical properties of the La0.7Mg0.3Ni3.4-xMn0.1Cox （x=01.05） hydrogen storage alloys were investigated. The crystal structure and the lattice parameters of the alloys were analyzed by X-ray diffractometry and Rietveld method. Electrochemical properties of the alloys including p—c—t curves, discharge capacity, discharge capacity retention were studied. The results show that （La, Mg）Ni3 and LaNi5 are the main phases of all the alloys. The plateau pressure for hydrogen absorption/desorption decreases and the hydrogen storage capacity firstly increases and subsequently decreases with increasing Co content. The values of the maximum discharge capacity of the alloy electrodes remain in range of 395.3403.1mA·h/g in spite of the change of Co content. The cycling stability of the alloy electrodes is greatly improved with increasing Co content, which is attributed to the suppression of the cell volume expansion during hydriding, leading the pulverization of the alloy particles lowered and the oxidation/corrosion of the active elements reduced.
