期刊文献+
共找到1,105篇文章
< 1 2 56 >
每页显示 20 50 100
Electric-controlled pressure relief valve for enhanced safety in liquid-cooled lithium-ion battery packs
1
作者 Yuhang Song Jidong Hou +6 位作者 Nawei Lyu Xinyuan Luo Jingxuan Ma Shuwen Chen Peihao Wu Xin Jiang Yang Jin 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第3期98-109,I0004,共13页
The liquid-cooled battery energy sto rage system(LCBESS) has gained significant attention due to its superior thermal management capacity.However,liquid-cooled battery pack(LCBP) usually has a high sealing level above... The liquid-cooled battery energy sto rage system(LCBESS) has gained significant attention due to its superior thermal management capacity.However,liquid-cooled battery pack(LCBP) usually has a high sealing level above IP65,which can trap flammable and explosive gases from battery thermal runaway and cause explosions.This poses serious safety risks and challenges for LCBESS.In this study,we tested overcharged battery inside a commercial LCBP and found that the conventionally mechanical pressure relief valve(PRV) on the LCBP had a delayed response and low-pressure relief efficiency.A realistic 20-foot model of an energy storage cabin was constructed using the Flacs finite element simulation software.Comparative studies were conducted to evaluate the pressure relief efficiency and the influence on neighboring battery packs in case of internal explosions,considering different sizes and installation positions of the PRV.Here,a newly developed electric-controlled PRV integrated with battery fault detection is introduced,capable of starting within 50 ms of the battery safety valve opening.Furthermore,the PRV was integrated with the battery management system and changed the battery charging and discharging strategy after the PRV was opened.Experimental tests confirmed the efficacy of this method in preventing explosions.This paper addresses the safety concerns associated with LCBPs and proposes an effective solution for explosion relief. 展开更多
关键词 Pressure relief valve Liquid-cooled battery pack Explosion Flacs
下载PDF
Battery pack capacity estimation for electric vehicles based on enhanced machine learning and field data
2
作者 Qingguang Qi Wenxue Liu +3 位作者 Zhongwei Deng Jinwen Li Ziyou Song Xiaosong Hu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第5期605-618,共14页
Accurate capacity estimation is of great importance for the reliable state monitoring,timely maintenance,and second-life utilization of lithium-ion batteries.Despite numerous works on battery capacity estimation using... Accurate capacity estimation is of great importance for the reliable state monitoring,timely maintenance,and second-life utilization of lithium-ion batteries.Despite numerous works on battery capacity estimation using laboratory datasets,most of them are applied to battery cells and lack satisfactory fidelity when extended to real-world electric vehicle(EV)battery packs.The challenges intensify for large-sized EV battery packs,where unpredictable operating profiles and low-quality data acquisition hinder precise capacity estimation.To fill the gap,this study introduces a novel data-driven battery pack capacity estimation method grounded in field data.The proposed approach begins by determining labeled capacity through an innovative combination of the inverse ampere-hour integral,open circuit voltage-based,and resistance-based correction methods.Then,multiple health features are extracted from incremental capacity curves,voltage curves,equivalent circuit model parameters,and operating temperature to thoroughly characterize battery aging behavior.A feature selection procedure is performed to determine the optimal feature set based on the Pearson correlation coefficient.Moreover,a convolutional neural network and bidirectional gated recurrent unit,enhanced by an attention mechanism,are employed to estimate the battery pack capacity in real-world EV applications.Finally,the proposed method is validated with a field dataset from two EVs,covering approximately 35,000 kilometers.The results demonstrate that the proposed method exhibits better estimation performance with an error of less than 1.1%compared to existing methods.This work shows great potential for accurate large-sized EV battery pack capacity estimation based on field data,which provides significant insights into reliable labeled capacity calculation,effective features extraction,and machine learning-enabled health diagnosis. 展开更多
关键词 Electricvehicle Lithium-ion battery pack Capacity estimation Machine learning Field data
下载PDF
A hierarchical enhanced data-driven battery pack capacity estimation framework for real-world operating conditions with fewer labeled data
3
作者 Sijia Yang Caiping Zhang +4 位作者 Haoze Chen Jinyu Wang Dinghong Chen Linjing Zhang Weige Zhang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第4期417-432,共16页
Battery pack capacity estimation under real-world operating conditions is important for battery performance optimization and health management,contributing to the reliability and longevity of batterypowered systems.Ho... Battery pack capacity estimation under real-world operating conditions is important for battery performance optimization and health management,contributing to the reliability and longevity of batterypowered systems.However,complex operating conditions,coupling cell-to-cell inconsistency,and limited labeled data pose great challenges to accurate and robust battery pack capacity estimation.To address these issues,this paper proposes a hierarchical data-driven framework aimed at enhancing the training of machine learning models with fewer labeled data.Unlike traditional data-driven methods that lack interpretability,the hierarchical data-driven framework unveils the“mechanism”of the black box inside the data-driven framework by splitting the final estimation target into cell-level and pack-level intermediate targets.A generalized feature matrix is devised without requiring all cell voltages,significantly reducing the computational cost and memory resources.The generated intermediate target labels and the corresponding features are hierarchically employed to enhance the training of two machine learning models,effectively alleviating the difficulty of learning the relationship from all features due to fewer labeled data and addressing the dilemma of requiring extensive labeled data for accurate estimation.Using only 10%of degradation data,the proposed framework outperforms the state-of-the-art battery pack capacity estimation methods,achieving mean absolute percentage errors of 0.608%,0.601%,and 1.128%for three battery packs whose degradation load profiles represent real-world operating conditions.Its high accuracy,adaptability,and robustness indicate the potential in different application scenarios,which is promising for reducing laborious and expensive aging experiments at the pack level and facilitating the development of battery technology. 展开更多
关键词 Lithium-ion battery pack Capacity estimation Label generation Multi-machine learning model Real-world operating
下载PDF
动力电池PACK智能制造复合型人才定向培养研究
4
作者 马艳 《武汉工程职业技术学院学报》 2023年第2期100-103,共4页
分析了新能源汽车核心能量源——动力电池PACK制造的现状,根据当前动力电池PACK智能制造人才培养的现状,对动力电池PACK智能制造复合型人才定向培养路径进行了研究,为其他跨专业领域的复合型人才培养提供启示。
关键词 动力电池pack 智能制造 高职教育 复合型人才 定向培养
下载PDF
Analysis on the capacity degradation mechanism of a series lithium-ion power battery pack based on inconsistency of capacity 被引量:2
5
作者 王震坡 刘鹏 王丽芳 《Chinese Physics B》 SCIE EI CAS CSCD 2013年第8期746-755,共10页
The lithium-ion battery has been widely used as an energy source. Charge rate, discharge rate, and operating tem- perature are very important factors for the capacity degradations of power batteries and battery packs.... The lithium-ion battery has been widely used as an energy source. Charge rate, discharge rate, and operating tem- perature are very important factors for the capacity degradations of power batteries and battery packs. Firstly, in this paper we make use of an accelerated life test and a statistical analysis method to establish the capacity accelerated degradation model under three constant stress parameters according to the degradation data, which are charge rate, discharge rate, and operating temperature, and then we propose a capacity degradation model according to the current residual capacity of a Li-ion cell under dynamic stress parameters. Secondly, we analyze the charge and discharge process of a series power battery pack and interpret the correlation between the capacity degradations of the battery pack and its charge/discharge rate. According to this cycling condition, we establish a capacity degradation model of a series power battery pack under inconsistent capacity of cells, and analyze the degradation mechanism with capacity variance and operating temperature difference. The comparative analysis of test results shows that the inconsistent operating temperatures of cells in the series power battery pack are the main cause of its degradation; when the difference between inconsistent temperatures is narrowed by 5 ℃, the cycle life can be improved by more than 50%. Therefore, it effectively improves the cycle life of the series battery pack to reasonably assemble the batteries according to their capacities and to narrow the differences in operating temperature among cells. 展开更多
关键词 lithium-ion battery pack SERIES capacity degradation dynamic stress
下载PDF
Lifetime and Aging Degradation Prognostics for Lithium-ion Battery Packs Based on a Cell to Pack Method 被引量:4
6
作者 Yunhong Che Zhongwei Deng +3 位作者 Xiaolin Tang Xianke Lin Xianghong Nie Xiaosong Hu 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2022年第1期192-207,共16页
Aging diagnosis of batteries is essential to ensure that the energy storage systems operate within a safe region.This paper proposes a novel cell to pack health and lifetime prognostics method based on the combination... Aging diagnosis of batteries is essential to ensure that the energy storage systems operate within a safe region.This paper proposes a novel cell to pack health and lifetime prognostics method based on the combination of transferred deep learning and Gaussian process regression.General health indicators are extracted from the partial discharge process.The sequential degradation model of the health indicator is developed based on a deep learning framework and is migrated for the battery pack degradation prediction.The future degraded capacities of both battery pack and each battery cell are probabilistically predicted to provide a comprehensive lifetime prognostic.Besides,only a few separate battery cells in the source domain and early data of battery packs in the target domain are needed for model construction.Experimental results show that the lifetime prediction errors are less than 25 cycles for the battery pack,even with only 50 cycles for model fine-tuning,which can save about 90%time for the aging experiment.Thus,it largely reduces the time and labor for battery pack investigation.The predicted capacity trends of the battery cells connected in the battery pack accurately reflect the actual degradation of each battery cell,which can reveal the weakest cell for maintenance in advance. 展开更多
关键词 Lithium-ion battery packs Lifetime prediction Degradation prognostic Model migration Machine learning
下载PDF
Thermal Management of Air-Cooling Lithium-Ion Battery Pack 被引量:5
7
作者 Jianglong Du Haolan Tao +3 位作者 Yuxin Chen Xiaodong Yuan Cheng Lian Honglai Liu 《Chinese Physics Letters》 SCIE CAS CSCD 2021年第11期77-82,共6页
Lithium-ion battery packs are made by many batteries, and the difficulty in heat transfer can cause many safety issues. It is important to evaluate thermal performance of a battery pack in designing process. Here, a m... Lithium-ion battery packs are made by many batteries, and the difficulty in heat transfer can cause many safety issues. It is important to evaluate thermal performance of a battery pack in designing process. Here, a multiscale method combining a pseudo-two-dimensional model of individual battery and three-dimensional computational fluid dynamics is employed to describe heat generation and transfer in a battery pack. The effect of battery arrangement on the thermal performance of battery packs is investigated. We discuss the air-cooling effect of the pack with four battery arrangements which include one square arrangement, one stagger arrangement and two trapezoid arrangements. In addition, the air-cooling strategy is studied by observing temperature distribution of the battery pack. It is found that the square arrangement is the structure with the best air-cooling effect, and the cooling effect is best when the cold air inlet is at the top of the battery pack. We hope that this work can provide theoretical guidance for thermal management of lithium-ion battery packs. 展开更多
关键词 Thermal Management of Air-Cooling Lithium-Ion battery pack
下载PDF
Low-Temperature Hydrogen Storage Alloy and Its Application in Ni-MH Battery 被引量:1
8
作者 陶明大 陈云贵 +2 位作者 吴朝玲 付春艳 涂铭旌 《Journal of Rare Earths》 SCIE EI CAS CSCD 2004年第6期882-886,共5页
Rare earth compositions, La, Ce and Pr in Mm(NiCoMnAl)(5) hydrogen storage alloy, were arranged by uniform design method. The discharge performances and kinetics parameters including capacity, exchange current density... Rare earth compositions, La, Ce and Pr in Mm(NiCoMnAl)(5) hydrogen storage alloy, were arranged by uniform design method. The discharge performances and kinetics parameters including capacity, exchange current density, symmetry factor and hydrogen diffusion coefficient of the alloy at -40degreesC, were tested in standard tri-electrode cell. And linear regression method was used to analyze the effect of rare earth compositions on the performances of hydrogen storage alloys. The results show that the capacities of the alloys are positively correlative to the square of Ce content at -40degreesC and under both 0.4 and 0.2C rate. The kinetics parameters and hydrogen diffusion coefficient indicate that the low-temperature performances of the alloys are mainly controlled by hydrogen diffusion process, and the surface electrochemical reaction affects the low-temperature performances to a certain extent. The low-temperature discharge capacities of the battery were also tested. The results show excellent low-temperature performances. The battery delivers 69.6% of its room-temperature capacity at -40degreesC and 0.2C rate, 77.7% at -40degreesC and 0.4C rate, 59.1% at -45degreesC and 0.2C rate. 展开更多
关键词 hydrogen storage alloy low-temperature performances aggression analysis ni-mh battery rare earths
下载PDF
Modeling and Optimization of Heat Dissipation Structure of EV Battery Pack 被引量:1
9
作者 Xinggang Li Rui Xiong 《Journal of Beijing Institute of Technology》 EI CAS 2018年第1期29-35,共7页
In order to solve the problems of high temperature and inconsistency in the operation of electric vehicle( EV) battery pack,computational fluid dynamics( CFD) simulation method is used to simulate and optimize the... In order to solve the problems of high temperature and inconsistency in the operation of electric vehicle( EV) battery pack,computational fluid dynamics( CFD) simulation method is used to simulate and optimize the heat dissipation of battery pack. The heat generation rate at different discharge magnifications is identified by establishing the heat generation model of the battery. In the forced air cooling mode,the Fluent software is used to compare the effects of different inlet and outlet directions,inlet angles,outlet angles,outlet sizes and inlet air speeds on heat dissipation. The simulation results show that the heat dissipation effect of the structure with the inlet and outlet on the same side is better than that on the different sides; the appropriate inlet angle and outlet width can improve the uniformity of temperature field; the increase of the inlet speed can improve the heat dissipation effect significantly. Compared with the steady temperature field of the initial structure,the average temperature after structure optimization is reduced by 4. 8℃ and the temperature difference is reduced by 15. 8℃,so that the battery can work under reasonable temperature and temperature difference. 展开更多
关键词 electric vehicle(EV) battery pack cooling computational fluid dynamics(CFD) air cooling
下载PDF
Research on Fuzzy PID Charging Control of Battery Pack
10
作者 Xiaoyan Xu 《World Journal of Engineering and Technology》 2017年第3期421-427,共7页
Battery groups are widely used in production and life. Optimal charging can not only shorten the charge time, but also improve the performance and life of the battery pack. A constant current or constant voltage charg... Battery groups are widely used in production and life. Optimal charging can not only shorten the charge time, but also improve the performance and life of the battery pack. A constant current or constant voltage charging method is commonly used. This type of method cannot adjust the charge capacity in time according to the change of charging capacity of storage battery, and the charge performance is not high. This paper designs a fuzzy PID controller. In the case of variable load and interference, the battery group can still be charged by the optimal charging current. Through the simulation results, the fuzzy PID controller works well and verifies the feasibility of the charging controller. 展开更多
关键词 battery pack CHARGE Management FUZZY PID Control
下载PDF
Comparative study of the thermal insulation performance of steel and aluminum battery packs in high-and low-temperature environments
11
作者 YANG Zhihui XU Dongkai XIAO Hua 《Baosteel Technical Research》 CAS 2022年第1期12-23,共12页
As the only power source of pure electric vehicles,the performance of battery packs is easily affected by the temperature,and too high or too low temperature will make the performance of battery packs decline.In this ... As the only power source of pure electric vehicles,the performance of battery packs is easily affected by the temperature,and too high or too low temperature will make the performance of battery packs decline.In this study,the thermal analysis finite element modeling of a cast aluminum battery pack and steel battery pack of a pure electric vehicle is established to compare the thermal insulation performance of two kinds of battery packs under high-and low-temperature conditions.The simulation results show that the thermal insulation performance of the two kinds of battery packs meets the design requirements under high-and low-temperature conditions.The external environment of the cell and battery pack mainly transmits heat through heat conduction.Aiming at the problem that the uniform temperature performance of the steel battery pack is lower than that of the cast aluminum battery pack,several optimization solutions are put forward for the insulation design of the steel battery pack,and the optimal solution is obtained by comparing the simulation results. 展开更多
关键词 battery pack thermal management INSULATION finite element analysis
下载PDF
New Composite Equalization Strategy for Lithium Battery Packs
12
作者 Jiacheng Ni Shichuan Wang Kai Wu 《Open Journal of Applied Sciences》 2019年第4期172-180,共9页
In order to improve the working efficiency of the power battery pack and prolong the service life, there is a problem of inconsistency among the individual cells. Based on the centralized equalization structure of the... In order to improve the working efficiency of the power battery pack and prolong the service life, there is a problem of inconsistency among the individual cells. Based on the centralized equalization structure of the multi-output winding transformer, a three-stage hybrid equalization control strategy is designed for equalization. The equalization scheme realizes that the high voltage single battery transfers the energy to the low voltage battery cell during the charging of the battery pack, improving not only charging efficiency and energy use loss, but also the high voltage battery transferring the power to the low voltage battery cell when the pressure difference is greater than 10 mv during the discharge. Between 5 mv and 10 mv, it performs passive equalization, reducing the output fluctuation of the power battery pack and achieving the balance purpose. During the standing time, the maximum active balancing operation within the battery pack is performed in order to achieve intra-group optimum consistency. It is proved by experiments that the equalization control method can realize the quick and effective equalization in the battery pack, and the energy balance of each single battery. 展开更多
关键词 Inconsistencies ACTIVE EQUALIZATION Energy BALANCE Power battery pack
下载PDF
动力电池模组和PACK装配线的工艺技术应用研究 被引量:1
13
作者 王飞 张强先 《蓄电池》 CAS 2023年第2期82-86,共5页
随着电动自行车共享换电的市场占有率越来越大,各大新能源电池生产企业纷纷建设了动力电池模组线和PACK装配线。为了提高共享换电的动力电池模组和PACK装配组装的工艺水平和生产效率,笔者以某新能源电池包模组和PACK装配线项目为例,介... 随着电动自行车共享换电的市场占有率越来越大,各大新能源电池生产企业纷纷建设了动力电池模组线和PACK装配线。为了提高共享换电的动力电池模组和PACK装配组装的工艺水平和生产效率,笔者以某新能源电池包模组和PACK装配线项目为例,介绍了模组和装配线的结构组成,阐述了模组和装配线工艺技术的应用,并对各模块应用做了简要的概述,为相似项目的解决方案提供了参考和依据。 展开更多
关键词 共享换电 新能源 锂离子 动力电池 模组 pack装配线
下载PDF
基于安全、轻量化、可靠性多目标的新能源汽车电池包壳体开发 被引量:3
14
作者 冯毅 张德良 高翔 《汽车工程学报》 2024年第2期155-167,共13页
电池包作为新能源汽车的动力源,是新能源汽车最重要的部件之一,而电池包壳体对电池包乃至整车起重要保护作用,是新能源汽车的关键部件。电池包壳体质量占整车的2%~6%,电池包壳体对汽车轻量化同样起到重要作用。基于全球汽车产业的节能... 电池包作为新能源汽车的动力源,是新能源汽车最重要的部件之一,而电池包壳体对电池包乃至整车起重要保护作用,是新能源汽车的关键部件。电池包壳体质量占整车的2%~6%,电池包壳体对汽车轻量化同样起到重要作用。基于全球汽车产业的节能减排发展目标,从安全性、轻量化、可靠性3个角度出发,论述了新能源汽车电池包壳体开发的行业发展现状,展望其未来的发展趋势,同时针对这一领域存在的共性关键技术问题进行了讨论。 展开更多
关键词 新能源汽车 电池包 安全 轻量化 可靠性
下载PDF
基于Buck-Boost的锂电池双层均衡方法研究 被引量:1
15
作者 徐元中 郭纯 +1 位作者 吴铁洲 付越凯 《电源技术》 CAS 北大核心 2024年第1期120-125,共6页
由于锂电池组的不一致性导致电池组使用寿命缩短和可用容量减少,为提高均衡速度,设计了一种基于Buck-Boost的分层均衡拓扑。以单体电池荷电状态(SOC)作为均衡变量,采用平均值比较法的均衡策略,将电池组分为两层来进行均衡。根据提出的... 由于锂电池组的不一致性导致电池组使用寿命缩短和可用容量减少,为提高均衡速度,设计了一种基于Buck-Boost的分层均衡拓扑。以单体电池荷电状态(SOC)作为均衡变量,采用平均值比较法的均衡策略,将电池组分为两层来进行均衡。根据提出的均衡拓扑和相应的均衡策略,采用4节锂电池单体在MATLAB/Simulink实验平台做了双层均衡仿真实验,同时将其与传统均衡拓扑进行对比分析,经实验证明,所设计的均衡拓扑可以提高均衡速度和能量转移效率。 展开更多
关键词 锂电池组 双层均衡 均衡速度 能量转移效率
下载PDF
基于电化学-热-力耦合模型的锂离子电池热失控研究 被引量:1
16
作者 张赛 汪振毅 胡世旺 《安全与环境学报》 CAS CSCD 北大核心 2024年第2期551-559,共9页
为提升锂离子电池的安全性能,减少由热失控导致的安全事故,分析电池温升的原因并有效降低其温度,依据电化学反应中浓度、电势与热模型中温度的相互影响关系,建立电化学-热-力耦合模型。通过模拟单电池和电池组温度分布的实时情况,分析... 为提升锂离子电池的安全性能,减少由热失控导致的安全事故,分析电池温升的原因并有效降低其温度,依据电化学反应中浓度、电势与热模型中温度的相互影响关系,建立电化学-热-力耦合模型。通过模拟单电池和电池组温度分布的实时情况,分析单电池温度不均匀分布和电池组温度正态分布情况的原因,探讨换热面积和流通量对散热量的影响,研究电池组中单体电池的位置分布及不同传热介质的散热情况。研究结果显示:低温和相对高温环境下,欧姆热、极化热及电化学反应热产热占比不同,但产热最高温度未达到电极材料与电解液分解反应的临界温度420 K;高温环境下,电池温度持续升高接近临界温度,出现热失控趋势,对流换热系数对电池影响较大。电池组间隙为10 mm和20 mm时,整体温度比间隙为0时分别降低了1.1%和1.8%;与无间隙电池组相比,以铜板和铝板为传热介质的电池组温度分别降低了2.0%和1.6%。 展开更多
关键词 安全工程 电化学-热-力耦合 间隙电池组 对流换热系数 热失控
下载PDF
基于DFD-DBSCAN的高速列车电池组多故障诊断方法
17
作者 向超群 席振 +3 位作者 左明洁 毕福亮 成庶 于天剑 《铁道科学与工程学报》 EI CAS CSCD 北大核心 2024年第7期2980-2988,共9页
高速列车电池作为备用电源,被广泛应用于辅助供电系统以维持高速列车控制系统的正常运转,其可靠性涉及行车安全。列车频繁起停、频繁加减速以及震动等多种复杂运行环境易导致电池单体故障和连接故障。为了保证高速列车的安全运行,高速... 高速列车电池作为备用电源,被广泛应用于辅助供电系统以维持高速列车控制系统的正常运转,其可靠性涉及行车安全。列车频繁起停、频繁加减速以及震动等多种复杂运行环境易导致电池单体故障和连接故障。为了保证高速列车的安全运行,高速列车电池组的状态检测与多故障诊断研究备受关注。目前,针对高速列车电池组的多故障诊断方法的研究尚属空白,提出一种基于改进离散弗雷歇距离(Discrete Fréchet Distance, DFD)和自适应密度聚类(Density-Based Spatial Clustering of Applications with Noise, DBSCAN)的高速列车电池组的实时多故障诊断方法,以准确识别电池组的连接故障和单体故障。以高速列车电池作为研究对象,通过设计适用于高速列车电池组的电压交叉测量方法,使得电池电压和连接板电压与不同的电压传感器相关联,并通过DFD算法对电池组的故障特征进行提取,将电压偏移率与DFD共同作为故障诊断模型的参数输入以提高算法的鲁棒性与可靠性,接着引入DBSCAN算法自动对故障诊断并定位。为了保证算法的实时性,利用基于滑动窗口的遗忘机制实时地对采样数据进行诊断。通过实验对所提出的方法进行验证,结果表明该方法可及时有效地诊断电池组的单体故障与连接故障并准确定位,弥补了高速列车电池组多故障诊断方法研究的缺失,对提高轨道列车的行车安全具有工程实用意义。 展开更多
关键词 高速列车 电池组 故障诊断 弗雷歇距离 DBSCAN算法
下载PDF
阴离子密堆二次电池正极材料中离子宿住迁移与能量存蓄机制晶体化学新探索
18
作者 梁叔全 郭珊 +4 位作者 何伟 曹鑫鑫 马君剑 周江 方国赵 《中国有色金属学报》 EI CAS CSCD 北大核心 2024年第6期1769-1785,共17页
在二次电池电极材料中,有一类性能优良的材料具有阴离子密堆或近密堆方式构筑的晶体结构。宿住阳离子在密堆留下的空隙空间中宿住、迁移,从而实现能量转换与存储。相关过程微观机理的研究由于涉及原子尺度的微观结构辨析和电子层面的分... 在二次电池电极材料中,有一类性能优良的材料具有阴离子密堆或近密堆方式构筑的晶体结构。宿住阳离子在密堆留下的空隙空间中宿住、迁移,从而实现能量转换与存储。相关过程微观机理的研究由于涉及原子尺度的微观结构辨析和电子层面的分析,实验研究难度较大。因此,更多是通过晶体学理论分析与晶体场理论和量子力学第一性原理计算结合展开。已有的理论从过渡金属配位体晶体场分析展开,但宿住离子宿住迁移中电子相互作用关注相对不足。本文根据已有的实验事实,在精准描述最具代表性的阴离子(氧离子)面心立方紧密堆积(FCC)结构中空隙空间准确形态和微分几何方法准确解析空腔真实体积的基础上,结合空隙空腔独特形态,对经典晶体学中Pauling第一规则的分析方法作了拓展。根据新的理解,提出了宿住阳离子在空隙空腔宿住和徒迁拓扑形变新模式,及其可能拥有的电子形态学新特征,提出了空隙空腔中宿住阳离子体积与密堆阴离子半径间的新关系。为了进一步说明住宿离子电子形态特征,通过第一性原理计算获得了典型FCC结构LiMn_(2)O_(4)尖晶石中电子密度等势图,构造了锂离子宿住四面体空隙空腔的电子密度等势特征分布的三维形态,与晶体学分析中获得的电子形态新特征变化一致。通过夹在两个密排面间的{110}面族电子云密度分布分析,首次清晰地揭示了LiMn_(2)O_(4)中锂离子的“S”形徒迁途径,及其对附近锰离子配位多面体电子云密度分布的影响。依据宿住离子脱/嵌新特征,提出阴离子拓扑多面体晶体场对宿住阳离子电子云压缩发生拓扑变形实现能量转换储蓄的新思路,据此计算了典型紧密堆积构造的电极材料新的理论能量密度,并和传统方法计算的理论值进行了比较,二者十分接近,为从晶体学和量子力学理解二次电池能量储存提供了新视角。 展开更多
关键词 二次电池 密堆积正极材料 离子迁移 能量存蓄机制 晶体化学分析 第一性原理计算
下载PDF
碳纤维电池包箱体的设计与铺层优化研究
19
作者 徐峰祥 毛锐 《汽车技术》 CSCD 北大核心 2024年第9期1-9,共9页
为实现电池包箱体的轻量化设计,采用碳纤维复合材料取代传统金属构建电池包箱体结构。首先对碳纤维电池包的动静态性能开展有限元分析,并基于性能要求对上盖板依次进行形貌优化和尺寸优化,对下箱体进行结构优化,使下箱体质量减轻31.1%,... 为实现电池包箱体的轻量化设计,采用碳纤维复合材料取代传统金属构建电池包箱体结构。首先对碳纤维电池包的动静态性能开展有限元分析,并基于性能要求对上盖板依次进行形貌优化和尺寸优化,对下箱体进行结构优化,使下箱体质量减轻31.1%,且一阶固有频率提升至50.63 Hz,然后,开展了箱体铺层优化分析,基于Isight平台对下箱体的质量和一阶固有频率进行多目标优化,利用熵-优劣解距离法(TOPSIS)确定最优铺层设计方案,并综合考虑层合板铺覆工艺对铺层顺序进行全面优化,优化分析结果表明,下箱体实现质量减轻58.9%,且各工况下的最大位移和最大应力均有所减小,电池包箱体动静态性能均得到提升。 展开更多
关键词 电池包箱体 碳纤维复合材料 铺层 多目标优化 轻量化设计
下载PDF
基于频域和时域法的电池包随机振动疲劳计算对比研究
20
作者 吴光强 李超 +1 位作者 丁丰 章蕾 《湖南大学学报(自然科学版)》 EI CAS CSCD 北大核心 2024年第2期208-218,共11页
针对频域法和时域法在随机振动疲劳计算中的适用性问题,以某型号电池包为研究对象,综合研究了2种方法的计算精度和计算效率.首先,建立电池包有限元模型,并通过模态试验进行验证;其次,以国标GB 38031―2020加速度功率谱密度(PSD)载荷谱... 针对频域法和时域法在随机振动疲劳计算中的适用性问题,以某型号电池包为研究对象,综合研究了2种方法的计算精度和计算效率.首先,建立电池包有限元模型,并通过模态试验进行验证;其次,以国标GB 38031―2020加速度功率谱密度(PSD)载荷谱作为频域载荷输入,并利用傅里叶逆变换技术将其转换为加速度时域载荷;最后,分别基于频域法和时域法计算电池包的振动加速度、应力和疲劳寿命,并进行了计算精度、效率的对比分析和精度的试验验证.结果表明,在电池包总振级和应力均方根值(RMS)方面,频域法和时域法计算结果相近,相对误差小于16%;在加速度和应力峰值方面,频域法“3σ”计算结果与时域法差距较大,若采用“4σ”或“5σ”原则,计算结果与时域法相近,相对误差小于15%;在振动疲劳方面,频域法计算寿命约为时域法的3~6倍,主要原因包括Dirlik模型和应力响应PSD谱差异,其中Dirlik模型造成的差距小于1.5倍;在计算效率方面,频域法比时域法高约134倍.试验数据表明,时域法计算精度更高,适用于结构危险位置振动疲劳的精确计算,而频域法计算效率更高,适用于结构危险位置的快速预测. 展开更多
关键词 电池包 随机振动 疲劳寿命 时域分析 频域分析
下载PDF
上一页 1 2 56 下一页 到第
使用帮助 返回顶部