Laser-induced fluorescence excitation spectra of jet-cooled NiC1 molecules were recorded in the energy range of 12900-15000 cm-1. Six vibronic bands with rotational structure have been observed and assigned to the [13...Laser-induced fluorescence excitation spectra of jet-cooled NiC1 molecules were recorded in the energy range of 12900-15000 cm-1. Six vibronic bands with rotational structure have been observed and assigned to the [13.0]2II3/2(v'=0-5)-X2II3/2(v"=0) transition progression. The relevant rotational constants, significant isotopic shifts, and (equilibrium) molecular parameters have been determined. In addition, the lifetimes of the observed bands have also been measured.展开更多
基金This work was supported by the National Natural Science Foundation of China (No.21273212, No.20873133, and No.21173205), the National Key Basic Research Program of China (No.2010CB923302), the Chinese Academy of Sciences (No.KJCX2-YW-N24), the FRFCUC (No.WK2340000012), and the USTC-NSRL Joint Funds (No.KY2340000021).
文摘Laser-induced fluorescence excitation spectra of jet-cooled NiC1 molecules were recorded in the energy range of 12900-15000 cm-1. Six vibronic bands with rotational structure have been observed and assigned to the [13.0]2II3/2(v'=0-5)-X2II3/2(v"=0) transition progression. The relevant rotational constants, significant isotopic shifts, and (equilibrium) molecular parameters have been determined. In addition, the lifetimes of the observed bands have also been measured.