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NiCrBSi堆焊层的电化学腐蚀失效过程 被引量:1
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作者 赵卫民 王勇 +1 位作者 薛锦 吴开源 《材料保护》 CAS CSCD 北大核心 2005年第4期21-24,31,共5页
在碳钢表面制备NiCrBSi耐蚀合金堆焊层,采用腐蚀浸泡试验和交流阻抗法研究了镍基合金层在3.5%NaCl溶液中的腐蚀失效过程。镍基堆焊层具有良好的耐蚀性能,交流阻抗测试过程中利用恒电位极化进行加速腐蚀。结果发现,夹杂物的存在是堆焊层... 在碳钢表面制备NiCrBSi耐蚀合金堆焊层,采用腐蚀浸泡试验和交流阻抗法研究了镍基合金层在3.5%NaCl溶液中的腐蚀失效过程。镍基堆焊层具有良好的耐蚀性能,交流阻抗测试过程中利用恒电位极化进行加速腐蚀。结果发现,夹杂物的存在是堆焊层发生局部腐蚀的根本原因,减少夹杂物的数目和减小夹杂物的体积可以有效提高堆焊层的耐蚀性能。堆焊层耐蚀性能稳定,阻抗随腐蚀的进行略有下降,腐蚀体系的等效电路为典型的Randles等效电路。如果堆焊层某些局部区域腐蚀严重,表面有基底露出点,则堆焊层阻抗显著减小,体系的等效电路发生变化,堆焊层与基底间即使没有发生宏观的电偶腐蚀也会失效。自然腐蚀电位测试结果证明,可以通过监测结构件电极电位的变化来判断堆焊层的腐蚀失效情况。 展开更多
关键词 金属堆焊 nicrbsi层 腐蚀失效 镍基合金 交流阻抗
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Tribological behavior and mechanism of NiCrBSi-Y_2O_3 composite coatings 被引量:1
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作者 蔡滨 谭业发 +2 位作者 谭华 敬奇锋 张中威 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2013年第7期2002-2010,共9页
The NiCrBSi-Y2O3 composite coatings were prepared on the surface of 45 carbon steel by plasma spray, the microstructure and tribological properties of the coatings were investigated. The results show that the NiCrBSi-... The NiCrBSi-Y2O3 composite coatings were prepared on the surface of 45 carbon steel by plasma spray, the microstructure and tribological properties of the coatings were investigated. The results show that the NiCrBSi-Y2O3 composite coatings are mainly composed of γ-Ni, CrB, Cr7C3 and Y2O3. With addition of Y2O3, hard phases such as CrB, Cr7C3 emerge in composite coating, and the density of the composite coatings also increases. The NiCrBSi-0.5Y2O3 composite coating presents excellent tribological properties. Its friction coefficient is 0.175, which is about 37% of that of the pure NiCrBSi coating. The mass wear loss is 1.2 mg, which is reduced by 43% compared with the pure NiCrBSi coating. When the loads are 6-10 N, the NiCrBSi-0.5Y2O3 composite coating suffers from slight wear and the wear mechanisms are mainly adhesive wear accompany with slight micro-cutting wear and micro-fracture wear. As the load increases to 12 N, the wear mechanisms are adhesive wear and severe micro-cutting wear. 展开更多
关键词 plasma spray composite coating nicrbsi Y2O3 friction WEAR
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不锈钢基体NiCrBSi/NiCrBSi(SiC-Mo)合金层的激光熔敷 被引量:7
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作者 高阳 佟百运 +1 位作者 梁勇 师昌绪 《清华大学学报(自然科学版)》 EI CAS CSCD 北大核心 2003年第6期754-757,共4页
为提高不锈钢叶片的耐磨损和气蚀的性能,在材料表面以激光熔敷NiCrBSi合金层。对合金层的显微结构、与不锈钢基体结合方式和SiC等颗粒增强改性对组织结构的影响进行了研究。采用5kW连续二氧化碳激光器对不锈钢上等离子喷涂预置NiCrBSi... 为提高不锈钢叶片的耐磨损和气蚀的性能,在材料表面以激光熔敷NiCrBSi合金层。对合金层的显微结构、与不锈钢基体结合方式和SiC等颗粒增强改性对组织结构的影响进行了研究。采用5kW连续二氧化碳激光器对不锈钢上等离子喷涂预置NiCrBSi合金层进行表面熔敷。扫描电子显微镜和X射线衍射分析结果表明:涂层显微结构为细化树枝晶,由γ基体与γ/γ′和NiB的共晶组成。合金粉中添加SiC-Mo颗粒后,熔敷层显微组织更加细化,成为与基体具有一定取向关系的枝晶组织,形成过饱和固溶体和极细的共晶体。SiC弥散分布于自溶性镍基合金中,熔敷不出现裂纹,可进一步提高涂层抗磨蚀性。该激光熔敷自溶性NiCrBSi合金挂片在黄河三门峡3号水轮机中环上现场测试结果表现出优良的抗磨蚀性。 展开更多
关键词 不锈钢 激光表面改性 激光熔敷 nicrbsi合金 显微结构 树枝晶 抗磨蚀性
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Microstructure and corrosion properties of laser cladding MoNi based alloy coatings 被引量:4
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作者 LI XinZhi LIU ZongDe WANG YongTian 《Science China(Technological Sciences)》 SCIE EI CAS 2014年第5期980-989,共10页
Mo-based alloys are widely used for their excellent wear and corrosion resistance as well as high temperature resistance.Mo-NiCrBSi and Mo-Ni alloy coatings were prepared on 1020 water wall tube by laser cladding tech... Mo-based alloys are widely used for their excellent wear and corrosion resistance as well as high temperature resistance.Mo-NiCrBSi and Mo-Ni alloy coatings were prepared on 1020 water wall tube by laser cladding technology in the present study.The microstructure and phase compositions were analyzed by means of the scanning electron microscopy(SEM),energy-dispersive spectroscopy(EDS)and X-ray diffractometry(XRD).The corrosion properties of the coatings were evaluated by an electrochemical experiment at room temperature in 3.5 wt.%NaCl electrolyte.With increasing content of Mo,the structure homogeneity in Mo-Ni coatings deteriorated,the grain size increased,the average hardness and the corrosion resistance declined,due to the more content of harmful phases.Compared to the Mo-Ni coatings,the overall performance was better for the Mo-NiCrBSi,which had the higher hardness contributed by the element B and Si as well as the better corrosion resistance due to the addition of Cr. 展开更多
关键词 laser cladding Mo-Ni Mo-nicrbsi corrosion resistance
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