NiFe-based nanostructures on nickel foam as highly efficiently electrocatalysts for oxygen and hydrogen evolution reactions

Water splitting,as an advanced energy conversion technology,consists of two half reactions,including oxygen evolution reaction(OER)and hydrogen evolution reaction(HER).However,the ideal electrocatalysts are noble metal based catalysts.Their high cost and scarcity in earth seriously restrict the large deployments.Ni Fe-based materials have attracted great attention in recent years due to their excellent catalytic properties for OER and HER.Nevertheless,their conductivity and electrochemical stability at high current density are unsatisfactory,resulting in ineffective water splitting due to high impedance and low stability.Recently,a series of catalysts coating Ni Fe-based materials on 3 D nickel foam were found to be extremely stable under the circumstance of high current density.In this review,we summarized the recent advances of NiFe-based materials on nickel foam for OER and HER,respectively,and further provided the perspectives for their future development.

镍铁和镁铁水滑石的合成及热稳定性研究

采用共沉淀法合成了摩尔比一致的镍铁和镁铁水滑石。X 射线晶体结构分析与TG DTA分析表明 ,镍铁与镁铁水滑石晶体两者结构相似 ,但热稳定性存在一定差异。