The oridation resistance at 1100°C of a dirationally solidified Ni3Al base alloy IC6is substantially improved by the addition of yttriurn or yttrium and silicon. The stress rupture property under 1100°C/80MP...The oridation resistance at 1100°C of a dirationally solidified Ni3Al base alloy IC6is substantially improved by the addition of yttriurn or yttrium and silicon. The stress rupture property under 1100°C/80MPa is increased by adding proper amounts of yttrium, howevef it decreases bg adding 0.3wt% silicon and 0. 1wt% yttrium at the same time, which may be attributed to the formation of a needle like phase rich in nickel and molybdenum.展开更多
The effect of Ce on the oxidation behaviour of undoped and B-doped Ni3 Al has been studied. Ce can refine Al2O3 grains produced in the course of oxidation of polycrystalline Ni3Al, accelerate the diffusion of oxygen a...The effect of Ce on the oxidation behaviour of undoped and B-doped Ni3 Al has been studied. Ce can refine Al2O3 grains produced in the course of oxidation of polycrystalline Ni3Al, accelerate the diffusion of oxygen along Al2O3 grain boundaries,and promote the growth of Al2O3 grains. As a result, the quantity of less-protective NiO decreases. The oxidation resistance of 0.011% Ce-doped alloy is the best of all Ce-doped Ni3Al alloys. Because B is benefitial to the formation of Al2O3 and Ce can refine Al2O3 grains, the oxidation resistance of the alloy containing both B and Ce is the best.展开更多
The effect of boron content(0 to 2.22 at.-% )on isothermal oxidation behaviour of Ni_3Al at 750 to 1150℃ for 3 to 100 h has been studied.The results show that the isothermal oxidation kinetics of Ni_3Al with various ...The effect of boron content(0 to 2.22 at.-% )on isothermal oxidation behaviour of Ni_3Al at 750 to 1150℃ for 3 to 100 h has been studied.The results show that the isothermal oxidation kinetics of Ni_3Al with various B contents at different temperatures obeys the parabolic law. The compounds with 0.52 to 1.37 at.-%B show the best oxidation resistance.The morphology and microstructure of the scales have also been investigated.展开更多
Self propagating high temperature synthesis(SHS) under compression was utilized to obtain an intermetallic compound Ni_3 Al by using elemental powders.The microstructure of the SHS product was observed by optical micr...Self propagating high temperature synthesis(SHS) under compression was utilized to obtain an intermetallic compound Ni_3 Al by using elemental powders.The microstructure of the SHS product was observed by optical microscopy(OM) and scanning electron microscopy(SEM).The results reveal that the SHS Ni3Al is a single-phase polycrystalline alloy wilh LI2 crystal structure.Tensile tests were conducted from room temperature to 800℃ both in air and in vacuum.The results show that the SHS Ni_3Al exhibits an anomalous temperature dependence of ultimate tensile strength.The ultimate tensile strength in vacuum is much higher than that in air over the whole temperature range.Fracture surfaces are characterized by the brittle grain boundary fracture and the intergranular fracture mode can not be affected markedly by the test environment.展开更多
An additive of Y to Ni_3Al based alloy may form a phase YNi_5 which increases in amount with the increase of Y content.It was found that the YNi_5 phase in Ni_3Al alloy could remarkably make its grains finer and its g...An additive of Y to Ni_3Al based alloy may form a phase YNi_5 which increases in amount with the increase of Y content.It was found that the YNi_5 phase in Ni_3Al alloy could remarkably make its grains finer and its grain boundaries more crooked other than straight.If the Y con- tent≥0.1 wt-%,it occurs as solid solution state and is favorable to high temperature compressive properties and oxidation resistance of the alloy.While Y≥0.3 wt-%,the forma- tion of YNi_5 is predominant in the shape of irregular strips inside Ni_3Al grains and along their grain boundaries.This seems to be quite harmful to high temperature strength,ductility and oxidation resistance of the alloy.展开更多
The oxidation behavior of Al2O3-30%TiCN-0.2%Y2O3 composite and its effect on high temperature bending strength was studied. The result indicates that the mass gain during static oxidation of the material under normal ...The oxidation behavior of Al2O3-30%TiCN-0.2%Y2O3 composite and its effect on high temperature bending strength was studied. The result indicates that the mass gain during static oxidation of the material under normal atmosphere follows the parabolic law. Oxide increases with increasing temperature and prolonging time. It has good oxidation resistance. The product of oxidation of the material is TiO2. Therefore, the volume of the material expands. The oxide film is destroyed because residual stress inside the oxide film is released. Proper oxidation is beneficial to the improvement of bending strength of Al2O3-30%TiCN-0.2%Y2O3 composite. The strength increase is up to 4.5%.展开更多
In this study,the cyclic oxidation tests of the Ni3Al-based single-crystal super alloy IC21 were carried out at 800,900,950,1000,1050 and 1100℃in air.The present study shows that the complex oxide scale on the surfac...In this study,the cyclic oxidation tests of the Ni3Al-based single-crystal super alloy IC21 were carried out at 800,900,950,1000,1050 and 1100℃in air.The present study shows that the complex oxide scale on the surface of the alloy is made up of an outer columnar NiO layer,an intermediate mixture of NiO and NiAl2O4layer with a small amount of Mo oxides and an inner continuous layer ofα-Al_(2)O_(3).The cyclic oxidation kinetics curves show that oxidation resistance at 800,900,950,1000 and1050℃seems to follow a similar law and is better than that at 1100℃.The overall weight changes at 1100℃follows a parabolic law.Spallation and severe rumpling of the oxide scale are observed on the surface of the alloy at1100℃,revealing the occurrence of disastrous oxidation.展开更多
Research work and recent progress made toward the industrial applications of the Ni_3Al in CISRI are discussed in present paper. The development of a Ni_3Al base alloy named MX-246 hardened by carbides and fine disper...Research work and recent progress made toward the industrial applications of the Ni_3Al in CISRI are discussed in present paper. The development of a Ni_3Al base alloy named MX-246 hardened by carbides and fine dispersion of disordered γ is summaried. This alloy,with higher peak temperature of yield strength and higher strain hardening rate than alloyIC-218,has been successfully used as the material of rolling guider at elevated temperatures and in wear conditions. The Ni3Al base alloy of GH264 has been made into welding electrodes by horizontal continuous casting process, and recently successfully surfacing welded on hydraulic blades as cavitation erosion resistance material. The process of remelting Ni3Al base alloy in air was also developed. The processes of producing welding electrodes and remelting in air set the base of industrial applications of Ni3Al in welding, repairing and casting in mass production and into components of large size. Another application of the compound, manufacturing the jet engine rivets used at about 1300℃ , can be attributed to its excellent oxidation resistance and still keeping high strength up to the melting point.展开更多
文摘The oridation resistance at 1100°C of a dirationally solidified Ni3Al base alloy IC6is substantially improved by the addition of yttriurn or yttrium and silicon. The stress rupture property under 1100°C/80MPa is increased by adding proper amounts of yttrium, howevef it decreases bg adding 0.3wt% silicon and 0. 1wt% yttrium at the same time, which may be attributed to the formation of a needle like phase rich in nickel and molybdenum.
文摘The effect of Ce on the oxidation behaviour of undoped and B-doped Ni3 Al has been studied. Ce can refine Al2O3 grains produced in the course of oxidation of polycrystalline Ni3Al, accelerate the diffusion of oxygen along Al2O3 grain boundaries,and promote the growth of Al2O3 grains. As a result, the quantity of less-protective NiO decreases. The oxidation resistance of 0.011% Ce-doped alloy is the best of all Ce-doped Ni3Al alloys. Because B is benefitial to the formation of Al2O3 and Ce can refine Al2O3 grains, the oxidation resistance of the alloy containing both B and Ce is the best.
文摘The effect of boron content(0 to 2.22 at.-% )on isothermal oxidation behaviour of Ni_3Al at 750 to 1150℃ for 3 to 100 h has been studied.The results show that the isothermal oxidation kinetics of Ni_3Al with various B contents at different temperatures obeys the parabolic law. The compounds with 0.52 to 1.37 at.-%B show the best oxidation resistance.The morphology and microstructure of the scales have also been investigated.
文摘Self propagating high temperature synthesis(SHS) under compression was utilized to obtain an intermetallic compound Ni_3 Al by using elemental powders.The microstructure of the SHS product was observed by optical microscopy(OM) and scanning electron microscopy(SEM).The results reveal that the SHS Ni3Al is a single-phase polycrystalline alloy wilh LI2 crystal structure.Tensile tests were conducted from room temperature to 800℃ both in air and in vacuum.The results show that the SHS Ni_3Al exhibits an anomalous temperature dependence of ultimate tensile strength.The ultimate tensile strength in vacuum is much higher than that in air over the whole temperature range.Fracture surfaces are characterized by the brittle grain boundary fracture and the intergranular fracture mode can not be affected markedly by the test environment.
文摘An additive of Y to Ni_3Al based alloy may form a phase YNi_5 which increases in amount with the increase of Y content.It was found that the YNi_5 phase in Ni_3Al alloy could remarkably make its grains finer and its grain boundaries more crooked other than straight.If the Y con- tent≥0.1 wt-%,it occurs as solid solution state and is favorable to high temperature compressive properties and oxidation resistance of the alloy.While Y≥0.3 wt-%,the forma- tion of YNi_5 is predominant in the shape of irregular strips inside Ni_3Al grains and along their grain boundaries.This seems to be quite harmful to high temperature strength,ductility and oxidation resistance of the alloy.
文摘The oxidation behavior of Al2O3-30%TiCN-0.2%Y2O3 composite and its effect on high temperature bending strength was studied. The result indicates that the mass gain during static oxidation of the material under normal atmosphere follows the parabolic law. Oxide increases with increasing temperature and prolonging time. It has good oxidation resistance. The product of oxidation of the material is TiO2. Therefore, the volume of the material expands. The oxide film is destroyed because residual stress inside the oxide film is released. Proper oxidation is beneficial to the improvement of bending strength of Al2O3-30%TiCN-0.2%Y2O3 composite. The strength increase is up to 4.5%.
基金financially supported by the National Natural Science Foundation of China(No.51371014)。
文摘In this study,the cyclic oxidation tests of the Ni3Al-based single-crystal super alloy IC21 were carried out at 800,900,950,1000,1050 and 1100℃in air.The present study shows that the complex oxide scale on the surface of the alloy is made up of an outer columnar NiO layer,an intermediate mixture of NiO and NiAl2O4layer with a small amount of Mo oxides and an inner continuous layer ofα-Al_(2)O_(3).The cyclic oxidation kinetics curves show that oxidation resistance at 800,900,950,1000 and1050℃seems to follow a similar law and is better than that at 1100℃.The overall weight changes at 1100℃follows a parabolic law.Spallation and severe rumpling of the oxide scale are observed on the surface of the alloy at1100℃,revealing the occurrence of disastrous oxidation.
文摘Research work and recent progress made toward the industrial applications of the Ni_3Al in CISRI are discussed in present paper. The development of a Ni_3Al base alloy named MX-246 hardened by carbides and fine dispersion of disordered γ is summaried. This alloy,with higher peak temperature of yield strength and higher strain hardening rate than alloyIC-218,has been successfully used as the material of rolling guider at elevated temperatures and in wear conditions. The Ni3Al base alloy of GH264 has been made into welding electrodes by horizontal continuous casting process, and recently successfully surfacing welded on hydraulic blades as cavitation erosion resistance material. The process of remelting Ni3Al base alloy in air was also developed. The processes of producing welding electrodes and remelting in air set the base of industrial applications of Ni3Al in welding, repairing and casting in mass production and into components of large size. Another application of the compound, manufacturing the jet engine rivets used at about 1300℃ , can be attributed to its excellent oxidation resistance and still keeping high strength up to the melting point.
