Mathematical model for mass transfer of chemical reactions on the surface of the smelting bath pit in oxygen top blown smelting furnace was put forward. Additionally, one of two mathematical models for mass transfer o...Mathematical model for mass transfer of chemical reactions on the surface of the smelting bath pit in oxygen top blown smelting furnace was put forward. Additionally, one of two mathematical models for mass transfer of chemical reactions forming copper matte in smelting bath and the other for parameters of smelting process were developed. The verification tests were simultaneously carried out in a pilot scale furnace and the experimental results show that these mathematical models are convincing. Thus, these numerical models are reliable to simulate pyritic smelting process for copper nickel mineral in oxygen top blown furnace.展开更多
The characteristics of previously determined and a number of new,unknown before,mineral phases are presented.On this area in sulphide ores of the Central the Pai-Khoi dolerite bodies.In the process of intrusion format...The characteristics of previously determined and a number of new,unknown before,mineral phases are presented.On this area in sulphide ores of the Central the Pai-Khoi dolerite bodies.In the process of intrusion formation and sulphidic magma crystallization the subtraction of such elements as lead, stibium,cobalt,arsenic,and accordingly migration and concentration of minerals of platinum展开更多
Prospectivity analyses are used to reduce the exploration search space for locating areas prospective for mineral deposits.The scale of a study and the type of mineral system associated with the deposit control the ev...Prospectivity analyses are used to reduce the exploration search space for locating areas prospective for mineral deposits.The scale of a study and the type of mineral system associated with the deposit control the evidence layers used as proxies that represent critical ore genesis processes.In particular,knowledge-driven approaches(fuzzy logic)use a conceptual mineral systems model from which data proxies represent the critical components.These typically vary based on the scale of study and the type of mineral system being predicted.Prospectivity analyses utilising interpreted data to represent proxies for a mineral system model inherit the subjectivity of the interpretations and the uncertainties of the evidence layers used in the model.In the case study presented,the prospectivity for remobilised nickel sulphide(NiS)in the west Kimberley,Western Australia,is assessed with two novel techniques that objectively grade interpretations and accommodate alternative mineralisation scenarios.Exploration targets are then identified and supplied with a robustness assessment that reflects the variability of prospectivity value for each location when all models are considered.The first technique grades the strength of structural interpretations on an individual line-segment basis.Gradings are obtained from an objective measure of feature evidence,which is the quantification of specific patterns in geophysical data that are considered to reveal underlying structure.Individual structures are weighted in the prospectivity model with grading values correlated to their feature evidence.This technique allows interpreted features to contribute prospectivity proportional to their strength in feature evidence and indicates the level of associated stochastic uncertainty.The second technique aims to embrace the systemic uncertainty of modelling complex mineral systems.In this approach,multiple prospectivity maps are each generated with different combinations of confidence values applied to evidence layers to represent the diversity of processes potentially leading to ore deposition.With a suite of prospectivity maps,the most robust exploration targets are the locations with the highest prospectivity values showing the smallest range amongst the model suite.This new technique offers an approach that reveals to the modeller a range of alternative mineralisation scenarios while employing a sensible mineral systems model,robust modelling of prospectivity and significantly reducing the exploration search space for Ni.展开更多
The nickel deposits mainly distributed in 19 provinces and autonomous regions in China are 339 ore deposits/occurrences, including 4 super large-scale deposits, 14 large-scale deposits, 26 middle- scale deposits, 75 s...The nickel deposits mainly distributed in 19 provinces and autonomous regions in China are 339 ore deposits/occurrences, including 4 super large-scale deposits, 14 large-scale deposits, 26 middle- scale deposits, 75 small-scale deposits, and 220 mineralized occurrences. The prediction types of mineral resources of nickel deposits are magmatic type, marine sedimentary type and regolith type. The formation age is from the Neoarchean to the Cenozoic with two peaks in the Neoproterozoic and the late Paleozoic. The nickel deposits formed in the Neoproterozoic are located on the margin of the North China Block and Yangtze Block, and those formed in the late Paleozoic are mainly distributed in the Central Asian Orogenic Belt (CAOB), Emeishan and the Tarim Large Igneous Provinces (LIPs). Magmatic nickel deposits are mainly related with broken-up continental margin, post-collision extension of the orogenic belt and mantle plume. According to different tectonic backgrounds and main characteristics of magmatism, the Ni-Cu-Co-PGE metallogenie series types of ore deposits related with mantle-derived mafic-ultramafic rocks can be divided into 4 subtypes: (1) the Ni-Cu-Co- PGE metallogenic series subtype of ore deposits related with mantle-derived mafic-ultramafic rocks in the broken-up continental margin, (2) the Ni-Cu-Co-PGE metallogenic series subtype of ore deposits related with mantle-derived mafic-ultramafic rocks in mantle plume magmatism, (3) the Ni-Cu-Co- PGE metallogenic series subtype of ore deposits related with mantle-derived mafic-ultramafic rocks in the subduction of the orogenic belt, and (4) the Ni-Cu-Co-PGE metallogenic series subtype of ore deposits related with mantle-derived mafic-ultramafic rocks in post-collision extension of the orogenic belt. We have discussed in this paper the typical characteristics and metaliogenic models for Neoproterozoic Ni-Cu-(PGE) deposits related with broken-up continental margin, Cambrian marine sedimentary Ni-Mo-V deposits related with black shale, early Permian Ni-Cu deposits related with post-collision extension of the orogenic belt, late Permian Ni-Cu-(PGE) deposits related with Large Igneous Provinces (LIPs), and Cenozoic Ni-Au deposits related with regolith. The broken-up continental margin, mantle plume and post-collision extension of the orogenic belt are important ore- forming geological backgrounds, and the discordogenic fault, mafic-ultramafic intrusion, high MgO primitive magma (high-MgO basaltic magma), deep magmatism, sulfur saturation and sulfide segregation are 6 important geological conditions for the magmatic nickel deposits.展开更多
In the practical use for the production of the α-olefins, it is highly desired to develop a novel heterogeneous catalyst system. The metal complexes immobilized into the clay interlayers show a great potential as het...In the practical use for the production of the α-olefins, it is highly desired to develop a novel heterogeneous catalyst system. The metal complexes immobilized into the clay interlayers show a great potential as heterogeneous catalysts due to their excellent processability. In this study, nine types of heterogeneous procatalyst Ln/Ni2+-micas were synthesized via a one-pot preparation method, which includes both the condensation reaction of the ligand derivatives and the intercalation of the ligands into the Ni2+ ion-exchanged fluorotetrasilicic mica interlayer. The ligand structures of the prepared procatalysts were [Ln: R-N = C(Nap)-C(Nap) = N-R] [(Nap = 1,8-naphthdiyl) (L1, R = 2-MePh;L2, R = 2-FPh;L3, R = 2-BrPh;L4, R = 4-MePh;L5, R = 4-FPh;L6, R = 4-BrPh;L7, R = 2,4-F2Ph;L8, R = 2,4-Br2Ph;L9, R = 2,6-F2Ph). At 50℃ and 0.7 MPaethylene pressure, the triisobutylaluminum-activated L1-L6/Ni2+-mica showed a catalytic activity for the ethylene oligo-/polymerization in the range of 334 - 549 g-ethylene•g-cat–1•h–1. A high catalyst activity was obtained when the substituent having a larger steric bulk than that of a methyl substituent was introduced at the ortho-position of the aryl rings. The introduction of the fluorine substituent as a strong electron-withdrawing group to the para-position also increased the catalytic activity. The L2, L4, L5, and L6/Ni2+-micas showed moderate selectivities to oligomers consisting of C4-C20 in the range of 19.9 - 41.6 wt% at 50℃. The calculated Schulz-Flory constants α based on the mole fraction of C12 and C14 were within 0.61 - 0.78.展开更多
文摘Mathematical model for mass transfer of chemical reactions on the surface of the smelting bath pit in oxygen top blown smelting furnace was put forward. Additionally, one of two mathematical models for mass transfer of chemical reactions forming copper matte in smelting bath and the other for parameters of smelting process were developed. The verification tests were simultaneously carried out in a pilot scale furnace and the experimental results show that these mathematical models are convincing. Thus, these numerical models are reliable to simulate pyritic smelting process for copper nickel mineral in oxygen top blown furnace.
基金Project(50621063)supported by the National Natural Science Foundation of ChinaProject(2004CB619205)supported by the National Basic Research Program of ChinaProject(2007AA060902)supported by the High-tech Research and Development Program of China
文摘The characteristics of previously determined and a number of new,unknown before,mineral phases are presented.On this area in sulphide ores of the Central the Pai-Khoi dolerite bodies.In the process of intrusion formation and sulphidic magma crystallization the subtraction of such elements as lead, stibium,cobalt,arsenic,and accordingly migration and concentration of minerals of platinum
基金supported by the Geological Society of Australia(Honours Endowment Fund)the Australian Institute of Geoscientists(Honours Bursary)by ARC LP140100267
文摘Prospectivity analyses are used to reduce the exploration search space for locating areas prospective for mineral deposits.The scale of a study and the type of mineral system associated with the deposit control the evidence layers used as proxies that represent critical ore genesis processes.In particular,knowledge-driven approaches(fuzzy logic)use a conceptual mineral systems model from which data proxies represent the critical components.These typically vary based on the scale of study and the type of mineral system being predicted.Prospectivity analyses utilising interpreted data to represent proxies for a mineral system model inherit the subjectivity of the interpretations and the uncertainties of the evidence layers used in the model.In the case study presented,the prospectivity for remobilised nickel sulphide(NiS)in the west Kimberley,Western Australia,is assessed with two novel techniques that objectively grade interpretations and accommodate alternative mineralisation scenarios.Exploration targets are then identified and supplied with a robustness assessment that reflects the variability of prospectivity value for each location when all models are considered.The first technique grades the strength of structural interpretations on an individual line-segment basis.Gradings are obtained from an objective measure of feature evidence,which is the quantification of specific patterns in geophysical data that are considered to reveal underlying structure.Individual structures are weighted in the prospectivity model with grading values correlated to their feature evidence.This technique allows interpreted features to contribute prospectivity proportional to their strength in feature evidence and indicates the level of associated stochastic uncertainty.The second technique aims to embrace the systemic uncertainty of modelling complex mineral systems.In this approach,multiple prospectivity maps are each generated with different combinations of confidence values applied to evidence layers to represent the diversity of processes potentially leading to ore deposition.With a suite of prospectivity maps,the most robust exploration targets are the locations with the highest prospectivity values showing the smallest range amongst the model suite.This new technique offers an approach that reveals to the modeller a range of alternative mineralisation scenarios while employing a sensible mineral systems model,robust modelling of prospectivity and significantly reducing the exploration search space for Ni.
基金funded by the National Natural Science Fund for Youth (Grant No.41402070,41372101)grant from Chinese Geological Survey Grants (Grant No.1212010633903,1212011220369,12120114039601,1212011121037)open funds from the key laboratory of western mineral resources and geological engineering of ministry of education,Chang’an university (Grant No.310826151138)
文摘The nickel deposits mainly distributed in 19 provinces and autonomous regions in China are 339 ore deposits/occurrences, including 4 super large-scale deposits, 14 large-scale deposits, 26 middle- scale deposits, 75 small-scale deposits, and 220 mineralized occurrences. The prediction types of mineral resources of nickel deposits are magmatic type, marine sedimentary type and regolith type. The formation age is from the Neoarchean to the Cenozoic with two peaks in the Neoproterozoic and the late Paleozoic. The nickel deposits formed in the Neoproterozoic are located on the margin of the North China Block and Yangtze Block, and those formed in the late Paleozoic are mainly distributed in the Central Asian Orogenic Belt (CAOB), Emeishan and the Tarim Large Igneous Provinces (LIPs). Magmatic nickel deposits are mainly related with broken-up continental margin, post-collision extension of the orogenic belt and mantle plume. According to different tectonic backgrounds and main characteristics of magmatism, the Ni-Cu-Co-PGE metallogenie series types of ore deposits related with mantle-derived mafic-ultramafic rocks can be divided into 4 subtypes: (1) the Ni-Cu-Co- PGE metallogenic series subtype of ore deposits related with mantle-derived mafic-ultramafic rocks in the broken-up continental margin, (2) the Ni-Cu-Co-PGE metallogenic series subtype of ore deposits related with mantle-derived mafic-ultramafic rocks in mantle plume magmatism, (3) the Ni-Cu-Co- PGE metallogenic series subtype of ore deposits related with mantle-derived mafic-ultramafic rocks in the subduction of the orogenic belt, and (4) the Ni-Cu-Co-PGE metallogenic series subtype of ore deposits related with mantle-derived mafic-ultramafic rocks in post-collision extension of the orogenic belt. We have discussed in this paper the typical characteristics and metaliogenic models for Neoproterozoic Ni-Cu-(PGE) deposits related with broken-up continental margin, Cambrian marine sedimentary Ni-Mo-V deposits related with black shale, early Permian Ni-Cu deposits related with post-collision extension of the orogenic belt, late Permian Ni-Cu-(PGE) deposits related with Large Igneous Provinces (LIPs), and Cenozoic Ni-Au deposits related with regolith. The broken-up continental margin, mantle plume and post-collision extension of the orogenic belt are important ore- forming geological backgrounds, and the discordogenic fault, mafic-ultramafic intrusion, high MgO primitive magma (high-MgO basaltic magma), deep magmatism, sulfur saturation and sulfide segregation are 6 important geological conditions for the magmatic nickel deposits.
文摘In the practical use for the production of the α-olefins, it is highly desired to develop a novel heterogeneous catalyst system. The metal complexes immobilized into the clay interlayers show a great potential as heterogeneous catalysts due to their excellent processability. In this study, nine types of heterogeneous procatalyst Ln/Ni2+-micas were synthesized via a one-pot preparation method, which includes both the condensation reaction of the ligand derivatives and the intercalation of the ligands into the Ni2+ ion-exchanged fluorotetrasilicic mica interlayer. The ligand structures of the prepared procatalysts were [Ln: R-N = C(Nap)-C(Nap) = N-R] [(Nap = 1,8-naphthdiyl) (L1, R = 2-MePh;L2, R = 2-FPh;L3, R = 2-BrPh;L4, R = 4-MePh;L5, R = 4-FPh;L6, R = 4-BrPh;L7, R = 2,4-F2Ph;L8, R = 2,4-Br2Ph;L9, R = 2,6-F2Ph). At 50℃ and 0.7 MPaethylene pressure, the triisobutylaluminum-activated L1-L6/Ni2+-mica showed a catalytic activity for the ethylene oligo-/polymerization in the range of 334 - 549 g-ethylene•g-cat–1•h–1. A high catalyst activity was obtained when the substituent having a larger steric bulk than that of a methyl substituent was introduced at the ortho-position of the aryl rings. The introduction of the fluorine substituent as a strong electron-withdrawing group to the para-position also increased the catalytic activity. The L2, L4, L5, and L6/Ni2+-micas showed moderate selectivities to oligomers consisting of C4-C20 in the range of 19.9 - 41.6 wt% at 50℃. The calculated Schulz-Flory constants α based on the mole fraction of C12 and C14 were within 0.61 - 0.78.