In this work, the effect of electrical discharge on nitrate concentration is considered in aqueous solution. The atmospheric pressure plasma was produced by a high-voltage power supply at 27 k Hz using pin-to-pin conf...In this work, the effect of electrical discharge on nitrate concentration is considered in aqueous solution. The atmospheric pressure plasma was produced by a high-voltage power supply at 27 k Hz using pin-to-pin configuration. Air, argon,and argon/methane mixture were used to study the working gas effect. UV-VIS spectroscopy and ion chromatography were used to analyze the effect of the electrical discharge on nitrate concentration in deionized water. Optical emission spectroscopy（OES） was applied to diagnose active species inside and on the surface of the deionized water solution. The results of the present work showed that the atmospheric pressure electric discharge with air increases nitrate concentration while it remains constant using argon and argon/methane electrical discharges. It was also revealed that in the presence of air, the electrical discharge reduces p H, acidifying the solution and increasing solution conductivity due to production of extra nitrate ions. On the other hand, argon electrical discharge increases p H and conductivity due to production of OHion in water.展开更多
Viscosities were measured for the ternary systems Y（NO3）3＋La（NO3）3＋H2O, La（NO3）3＋Ce（NO3）3＋H2O, and La（NO3）3＋Nd（NO3）3＋ H2O and their binary subsystems Y（NO3）3＋H2O, La（NO3）3＋H2O, Ce（NO3）3＋H2O,...Viscosities were measured for the ternary systems Y（NO3）3＋La（NO3）3＋H2O, La（NO3）3＋Ce（NO3）3＋H2O, and La（NO3）3＋Nd（NO3）3＋ H2O and their binary subsystems Y（NO3）3＋H2O, La（NO3）3＋H2O, Ce（NO3）3＋H2O, and Nd（NO3）3＋H2O at 293.15, 298.15 and 308.15 K. The results were used to test the applicability of simple equations for the viscosity of the mixed solutions. The predictions agreed well with measured values, implying that the viscosities of the examined electrolyte solutions could be related to those of their constituent binary solutions using these simple equations.展开更多
文摘In this work, the effect of electrical discharge on nitrate concentration is considered in aqueous solution. The atmospheric pressure plasma was produced by a high-voltage power supply at 27 k Hz using pin-to-pin configuration. Air, argon,and argon/methane mixture were used to study the working gas effect. UV-VIS spectroscopy and ion chromatography were used to analyze the effect of the electrical discharge on nitrate concentration in deionized water. Optical emission spectroscopy（OES） was applied to diagnose active species inside and on the surface of the deionized water solution. The results of the present work showed that the atmospheric pressure electric discharge with air increases nitrate concentration while it remains constant using argon and argon/methane electrical discharges. It was also revealed that in the presence of air, the electrical discharge reduces p H, acidifying the solution and increasing solution conductivity due to production of extra nitrate ions. On the other hand, argon electrical discharge increases p H and conductivity due to production of OHion in water.
基金Project supported by the National Natural Science Foundation of China (20976189, 21076224 and 21036008)the Science Foundation of China University of Petroleum (qzdx-2011-01) for financial sup-port
文摘Viscosities were measured for the ternary systems Y（NO3）3＋La（NO3）3＋H2O, La（NO3）3＋Ce（NO3）3＋H2O, and La（NO3）3＋Nd（NO3）3＋ H2O and their binary subsystems Y（NO3）3＋H2O, La（NO3）3＋H2O, Ce（NO3）3＋H2O, and Nd（NO3）3＋H2O at 293.15, 298.15 and 308.15 K. The results were used to test the applicability of simple equations for the viscosity of the mixed solutions. The predictions agreed well with measured values, implying that the viscosities of the examined electrolyte solutions could be related to those of their constituent binary solutions using these simple equations.
