The bile complexes have been Synthesised by the reaction of rare earth nitrate with 2-[2-3-nitro- 4-methoxylphenyl) vinyl ]-1-methylpyridinium nitrate in ethanol solution and have been characterized by IR. UV and 1H N...The bile complexes have been Synthesised by the reaction of rare earth nitrate with 2-[2-3-nitro- 4-methoxylphenyl) vinyl ]-1-methylpyridinium nitrate in ethanol solution and have been characterized by IR. UV and 1H NMR spectre TG-DTA, molar conductance and X-ray powder diffraction . The results show that the Crystal form of Nd complex containing one molecular water as a ligand is eleven coordinated and is different from the others.展开更多
In our previous work, the colour reactions of quaternary complexes of rare earths with chromazurol S, 5-nitro-1, 10-phenanthroline (5-N-phen) and cetyltrimethyl ammonium bromide (CTAB) were reported. In this paper, th...In our previous work, the colour reactions of quaternary complexes of rare earths with chromazurol S, 5-nitro-1, 10-phenanthroline (5-N-phen) and cetyltrimethyl ammonium bromide (CTAB) were reported. In this paper, the colour reactions of rare earths with eriochrome azurol B(ECB), 5-N-phen and CTAB will be systematically investigated. The results show that the sensitivity of the ECB system is higher than that of the CAS system. It is of interest to note that in the past ECB was only展开更多
文摘The bile complexes have been Synthesised by the reaction of rare earth nitrate with 2-[2-3-nitro- 4-methoxylphenyl) vinyl ]-1-methylpyridinium nitrate in ethanol solution and have been characterized by IR. UV and 1H NMR spectre TG-DTA, molar conductance and X-ray powder diffraction . The results show that the Crystal form of Nd complex containing one molecular water as a ligand is eleven coordinated and is different from the others.
文摘In our previous work, the colour reactions of quaternary complexes of rare earths with chromazurol S, 5-nitro-1, 10-phenanthroline (5-N-phen) and cetyltrimethyl ammonium bromide (CTAB) were reported. In this paper, the colour reactions of rare earths with eriochrome azurol B(ECB), 5-N-phen and CTAB will be systematically investigated. The results show that the sensitivity of the ECB system is higher than that of the CAS system. It is of interest to note that in the past ECB was only
