Ti-Cu films with different Cu concentrations were fabricated by high-power pulsed magnetron sputtering（HPPMS） to release copper ions and catalyze NO to improve the blood compatibility. The Cu concentrations of films...Ti-Cu films with different Cu concentrations were fabricated by high-power pulsed magnetron sputtering（HPPMS） to release copper ions and catalyze NO to improve the blood compatibility. The Cu concentrations of films were 25.7 at% and 68.8 at%. Pure Ti films were also fabricated. Copper release, catalytic release of nitric oxide（NO）, and blood platelet adhesion of Ti-Cu films were studied. Ti-Cu films released copper ions in PBS solution and more Cu ions were released from films with 68.8 at% Cu. Ti-Cu films had excellent ability of catalytical decomposition of exogenous donor S-nitroso-N-acetyl-DL-penicillamine（SNAP） and as a result, nitric oxide（NO） was generated. The NO generation catalyzed by Ti-Cu films was significantly higher than that by pure Ti films. This was more eminent in the Ti-Cu films with 68.8 at% Cu. The platelet adhesion and activation of Ti-Cu films were significantly inhibited compared to that of pure Ti films in the presence of SNAP. The Ti-Cu film fabricated by HPPMS showed the ability of releasing Cu ions to catalyze SNAP to generate NO to inhibit platelet adhesion and activation.展开更多
The Ar-N2 gas tungsten arc(GTA) welding of 10 mm copper thick plates without preheating was investigated.The microstructure of weld metal and joints was observed and mechanical performance of weld metal was tested by ...The Ar-N2 gas tungsten arc(GTA) welding of 10 mm copper thick plates without preheating was investigated.The microstructure of weld metal and joints was observed and mechanical performance of weld metal was tested by using Cu-Ti welding metal with different Ti content.The Ar-N2 GTA weld of copper thick plates can eliminate the nitrogen porosities in the weld metal by adding element Ti in filler metal,which is caused by N2 gas in shield gas.The elimination degree of nitrogen porosities,the distribution of CuTiN intermetallic compound(IMC) and the mechanical performance of joints are associated with the change of the Ti content in the welding materials.And when Ti content is about 5%,nitrogen porosities is eliminated completely and the CuTiN IMC distribute dispersedly,the tensile strength and impact ductility of the joint achieve the best result,which almost reaches the lever of the base metal.展开更多
基金Funded by the National Natural Science Foundation of China(No.31300787)the National Natural Science Foundation of China China Academy of Engineering Physics(NSAF No.U1330113)+1 种基金the Overseas Famous Teacher Program of Chinese Education Ministry(MS2010XNJT070)the Qingmiao Plan of SWJTU 2015(No.A0920502051517-6)
文摘Ti-Cu films with different Cu concentrations were fabricated by high-power pulsed magnetron sputtering（HPPMS） to release copper ions and catalyze NO to improve the blood compatibility. The Cu concentrations of films were 25.7 at% and 68.8 at%. Pure Ti films were also fabricated. Copper release, catalytic release of nitric oxide（NO）, and blood platelet adhesion of Ti-Cu films were studied. Ti-Cu films released copper ions in PBS solution and more Cu ions were released from films with 68.8 at% Cu. Ti-Cu films had excellent ability of catalytical decomposition of exogenous donor S-nitroso-N-acetyl-DL-penicillamine（SNAP） and as a result, nitric oxide（NO） was generated. The NO generation catalyzed by Ti-Cu films was significantly higher than that by pure Ti films. This was more eminent in the Ti-Cu films with 68.8 at% Cu. The platelet adhesion and activation of Ti-Cu films were significantly inhibited compared to that of pure Ti films in the presence of SNAP. The Ti-Cu film fabricated by HPPMS showed the ability of releasing Cu ions to catalyze SNAP to generate NO to inhibit platelet adhesion and activation.
基金Funded by Program of Excellent Team in Harbin Institute of Technology
文摘The Ar-N2 gas tungsten arc(GTA) welding of 10 mm copper thick plates without preheating was investigated.The microstructure of weld metal and joints was observed and mechanical performance of weld metal was tested by using Cu-Ti welding metal with different Ti content.The Ar-N2 GTA weld of copper thick plates can eliminate the nitrogen porosities in the weld metal by adding element Ti in filler metal,which is caused by N2 gas in shield gas.The elimination degree of nitrogen porosities,the distribution of CuTiN intermetallic compound(IMC) and the mechanical performance of joints are associated with the change of the Ti content in the welding materials.And when Ti content is about 5%,nitrogen porosities is eliminated completely and the CuTiN IMC distribute dispersedly,the tensile strength and impact ductility of the joint achieve the best result,which almost reaches the lever of the base metal.
