Three A-shaped nitropyrimidine derivatives with benzyl or furfuryl as bridge havebeen synthesized. They possess shorter absorption wavelengths (λ_(cut-off))<400 nm) andhigher βμ values (around 10^(-46) esu). The...Three A-shaped nitropyrimidine derivatives with benzyl or furfuryl as bridge havebeen synthesized. They possess shorter absorption wavelengths (λ_(cut-off))<400 nm) andhigher βμ values (around 10^(-46) esu). The second order nonlinear optical coefficient d_(33) ofpoled BNPMOPMDA/PMMA doped film is 1.2-2.0×10^(-9) esu obtained by in-situ SHGmeasurements. It can be expected that the chromophore-functionalized polymer containinghigher number density of synthesized chromophore as side chain will be the potential blue-light transparent frequency doubling materials.展开更多
基金This work was supported by the grant of theted National Natural Science Foundation of China and by the Chinese Academy of Sciences.
文摘Three A-shaped nitropyrimidine derivatives with benzyl or furfuryl as bridge havebeen synthesized. They possess shorter absorption wavelengths (λ_(cut-off))<400 nm) andhigher βμ values (around 10^(-46) esu). The second order nonlinear optical coefficient d_(33) ofpoled BNPMOPMDA/PMMA doped film is 1.2-2.0×10^(-9) esu obtained by in-situ SHGmeasurements. It can be expected that the chromophore-functionalized polymer containinghigher number density of synthesized chromophore as side chain will be the potential blue-light transparent frequency doubling materials.
