With the continuous Promotion of the Belt and Road Initiative in China,the requirements for oral English competence of college graduates have been becoming increasingly important.However,the oral English instruction o...With the continuous Promotion of the Belt and Road Initiative in China,the requirements for oral English competence of college graduates have been becoming increasingly important.However,the oral English instruction of many colleges still lacks interaction and most students have few opportunities to speak English in class.In order to enhance the effectiveness of English teaching,this paper aims to introduce Non-directive Teaching Theory of Rogers,an American humanistic psychologist,and micro-media environment and create a better dynamic and interactive classroom atmosphere and authentic environment to speak English through group discussion,English debate,and situation learning and so on.展开更多
Quenching experiments were performed at different cooling rates under non-directional solidification by differential thermal analysis, and the morphologic variation of primary phase, phase transition temperature and h...Quenching experiments were performed at different cooling rates under non-directional solidification by differential thermal analysis, and the morphologic variation of primary phase, phase transition temperature and hardness change at the same quenching temperature were investigated. The experimental results show that, with the gradual decrease of the cooling rate from 25 K/min, the morphology of ferrite starts to transform experiencing the dendrite, radial pattern, Widmanstatten-like and wire-net. Sample starts to present the Widmanstatten-like microstructure at 10 K/min which does not exist at higher or lower cooling rates, and this microstructure is detrimental to the mechanical property. Except 10 K/min, the hardness decreases with decreasing cooling rate.展开更多
Palladium-catalyzed non-directed C-H functionalization provides an efficient approach for direct functionalization of arenes, but it usually suffers from poor site selectivity, limiting its wide application.Herein, it...Palladium-catalyzed non-directed C-H functionalization provides an efficient approach for direct functionalization of arenes, but it usually suffers from poor site selectivity, limiting its wide application.Herein, it is reported for the first time that the carboxylic acid ligand of 3,5-dimethyladamantane-1-carboxylic acid(1-DMAd CO_(2)H) can affect the site selectivity during the C-H activation step in palladiumcatalyzed non-directed C-H functionalization, leading to highly para-selective C-H olefination of TIPSprotected phenols. This transformation displayed good generality in realizing various other para-selective C-H functionalization reactions such as halogenation, and allylation reactions. A wide variety of phenol derivatives including bioactive molecules of triclosan, thymol, and propofol, were compatible substrates,leading to the corresponding para-selective products in moderate to good yields. A preliminary mechanism study revealed that the spatial repulsion factor between carboxylic acid ligand and bulky protecting group resulted in the selective C-H activation at the less sterically hindered para-position. This new model non-directed para-selective C-H functionalization can provide a straightforward route for remote site-selective C-H activations.展开更多
The fast and accurate detection of the single-phaseto-ground fault is of great significance for the reliability and safety of the power supply.In this paper,novel algorithms for distribution network protection were pr...The fast and accurate detection of the single-phaseto-ground fault is of great significance for the reliability and safety of the power supply.In this paper,novel algorithms for distribution network protection were proposed with distributed parameters analysis in non-direct grounded systems.At first,novel generating mechanisms of zero-sequence voltage and residual current were proposed.Then the compositions of residue parameters,including residual current and residual admittances,were decomposed in detail.After that,an improved algorithm for a fault resistance calculation of a single phase-to-earth fault was also proposed,and the algorithm is much more convenient as it only needs to measure the variation of the zero-sequence voltage and does not need the prerequisites of the faulty feeder selection.Furthermore,the fault feeder can also be selected by an improved calculation algorithm of zero-sequence admittance of the faulty feeder,which cannot be affected by the asymmetry of the network.Theoretical analysis and the MATALB/Simulink simulation results demonstrate the effectiveness of the proposed algorithms.展开更多
文摘With the continuous Promotion of the Belt and Road Initiative in China,the requirements for oral English competence of college graduates have been becoming increasingly important.However,the oral English instruction of many colleges still lacks interaction and most students have few opportunities to speak English in class.In order to enhance the effectiveness of English teaching,this paper aims to introduce Non-directive Teaching Theory of Rogers,an American humanistic psychologist,and micro-media environment and create a better dynamic and interactive classroom atmosphere and authentic environment to speak English through group discussion,English debate,and situation learning and so on.
基金Funded by the National Natural Science Foundation of China(No.2010DFB70630)
文摘Quenching experiments were performed at different cooling rates under non-directional solidification by differential thermal analysis, and the morphologic variation of primary phase, phase transition temperature and hardness change at the same quenching temperature were investigated. The experimental results show that, with the gradual decrease of the cooling rate from 25 K/min, the morphology of ferrite starts to transform experiencing the dendrite, radial pattern, Widmanstatten-like and wire-net. Sample starts to present the Widmanstatten-like microstructure at 10 K/min which does not exist at higher or lower cooling rates, and this microstructure is detrimental to the mechanical property. Except 10 K/min, the hardness decreases with decreasing cooling rate.
基金supported by the National Natural Science Foundation of China(No.21772139)the Jiangsu Province Natural Science Found for Distinguished Young Scholars(No.BK20180041)+1 种基金the PAPD Projectsupported by the Open Research Fund of the School of Chemistry and Chemical Engineering,Henan Normal University。
文摘Palladium-catalyzed non-directed C-H functionalization provides an efficient approach for direct functionalization of arenes, but it usually suffers from poor site selectivity, limiting its wide application.Herein, it is reported for the first time that the carboxylic acid ligand of 3,5-dimethyladamantane-1-carboxylic acid(1-DMAd CO_(2)H) can affect the site selectivity during the C-H activation step in palladiumcatalyzed non-directed C-H functionalization, leading to highly para-selective C-H olefination of TIPSprotected phenols. This transformation displayed good generality in realizing various other para-selective C-H functionalization reactions such as halogenation, and allylation reactions. A wide variety of phenol derivatives including bioactive molecules of triclosan, thymol, and propofol, were compatible substrates,leading to the corresponding para-selective products in moderate to good yields. A preliminary mechanism study revealed that the spatial repulsion factor between carboxylic acid ligand and bulky protecting group resulted in the selective C-H activation at the less sterically hindered para-position. This new model non-directed para-selective C-H functionalization can provide a straightforward route for remote site-selective C-H activations.
基金This work was supported in part by the National Natural Science Foundation of China(No.51177039)in part by the Fundamental Research Funds for the Central Universities(2018B06314)the 111 Intelligence project(B14022).
文摘The fast and accurate detection of the single-phaseto-ground fault is of great significance for the reliability and safety of the power supply.In this paper,novel algorithms for distribution network protection were proposed with distributed parameters analysis in non-direct grounded systems.At first,novel generating mechanisms of zero-sequence voltage and residual current were proposed.Then the compositions of residue parameters,including residual current and residual admittances,were decomposed in detail.After that,an improved algorithm for a fault resistance calculation of a single phase-to-earth fault was also proposed,and the algorithm is much more convenient as it only needs to measure the variation of the zero-sequence voltage and does not need the prerequisites of the faulty feeder selection.Furthermore,the fault feeder can also be selected by an improved calculation algorithm of zero-sequence admittance of the faulty feeder,which cannot be affected by the asymmetry of the network.Theoretical analysis and the MATALB/Simulink simulation results demonstrate the effectiveness of the proposed algorithms.