In recent times, lithium-ion batteries have been widely used owing to their high energy density, extended cycle lifespan, and minimal self-discharge rate. The design of high-speed rechargeable lithium-ion batteries fa...In recent times, lithium-ion batteries have been widely used owing to their high energy density, extended cycle lifespan, and minimal self-discharge rate. The design of high-speed rechargeable lithium-ion batteries faces a significant challenge owing to the need to increase average electric power during charging. This challenge results from the direct influence of the power level on the rate of chemical reactions occurring in the battery electrodes. In this study, the Taguchi optimization method was used to enhance the average electric power during the charging process of lithium-ion batteries. The Taguchi technique is a statistical strategy that facilitates the systematic and efficient evaluation of numerous experimental variables. The proposed method involved varying seven input factors, including positive electrode thickness, positive electrode material, positive electrode active material volume fraction, negative electrode active material volume fraction, separator thickness, positive current collector thickness, and negative current collector thickness. Three levels were assigned to each control factor to identify the optimal conditions and maximize the average electric power during charging. Moreover, a variance assessment analysis was conducted to validate the results obtained from the Taguchi analysis. The results revealed that the Taguchi method was an eff ective approach for optimizing the average electric power during the charging of lithium-ion batteries. This indicates that the positive electrode material, followed by the separator thickness and the negative electrode active material volume fraction, was key factors significantly infl uencing the average electric power during the charging of lithium-ion batteries response. The identification of optimal conditions resulted in the improved performance of lithium-ion batteries, extending their potential in various applications. Particularly, lithium-ion batteries with average electric power of 16 W and 17 W during charging were designed and simulated in the range of 0-12000 s using COMSOL Multiphysics software. This study efficiently employs the Taguchi optimization technique to develop lithium-ion batteries capable of storing a predetermined average electric power during the charging phase. Therefore, this method enables the battery to achieve complete charging within a specific timeframe tailored to a specificapplication. The implementation of this method can save costs, time, and materials compared with other alternative methods, such as the trial-and-error approach.展开更多
Inspired by the function of crucial components in photosystemⅡ(PSⅡ),electrochemical and dyesensitized photoelectrochemical(DSPEC)water oxidation devices were constructed by the selfassembly of well-designed amphipat...Inspired by the function of crucial components in photosystemⅡ(PSⅡ),electrochemical and dyesensitized photoelectrochemical(DSPEC)water oxidation devices were constructed by the selfassembly of well-designed amphipathic Ru(bda)-based catalysts(bda=2,2'-bipyrdine-6,6'-dicarbonoxyl acid)and aliphatic chain decorated electrode surfaces,forming lipid bilayer membrane(LBM)-like structures.The Ru(bda)catalysts on electrode-supported LBM films demonstrated remarkable water oxidation performance with different O-O formation mechanisms.However,compared to the slow charge transfer process,the O-O formation pathways did not determine the PEC water oxidation efficiency of the dyesensitized photoanodes,and the different reaction rates for similar catalysts with different catalytic paths did not determine the PEC performance of the DSPECs.Instead,charge transfer plays a decisive role in the PEC water oxidation rate.When an indolo[3,2-b]carbazole derivative was introduced between the Ru(bda)catalysts and aliphatic chain-modified photosensitizer in LBM films,serving as a charge transfer mediator for the tyrosine-histidine pair in PSⅡ,the PEC water oxidation performance of the corresponding photoanodes was dramatically enhanced.展开更多
Under an in-phase assumption, the complete charging for an energy harvesting system is studied, which consists of a piezoelectric energy harvester(PEH), a bridge rectifier, a filter capacitor, a switch, a controller a...Under an in-phase assumption, the complete charging for an energy harvesting system is studied, which consists of a piezoelectric energy harvester(PEH), a bridge rectifier, a filter capacitor, a switch, a controller and a rechargeable battery. For the transient charging, the results indicate that the voltage across the filter capacitor increases as the charging proceeds, which is consistent with that reported in the literature. However, a new finding shows that the charging rate and energy harvesting efficiency decrease over time after their respective peak values are acquired.For the steady-state charging, the results reveal that the energy harvesting efficiency can be adjusted by altering the critical charging voltage that controls the transition of the system. The optimal energy harvesting efficiency is limited by the optimal efficiency of the transient charging. Finally, the relationship between the critical charging voltage and the equivalent resistance of the controller and rechargeable battery is established explicitly.展开更多
Based on the externality theory and the environmental value theory, the hypothesis of charging for waste dumping of open-pit metal mines was put forth. The charging methods were designed according to the characteristi...Based on the externality theory and the environmental value theory, the hypothesis of charging for waste dumping of open-pit metal mines was put forth. The charging methods were designed according to the characteristics of waste dumping of openpit metal mines, including charging based on the dumping amount of the total waste, multi-charging factors, exceeding standard punishment charging, and so on. The main charging parameter is based on the dumping area rather than the total amount of waste dumping. The charging model of waste dumping of open-pit mines was formulated, and the charging rate was divided into two parts, i.e., the standard charging rate and the differential charging rate. The standard charging rate was derived using the equilibrium dynamic model, whereas the differential one was obtained by establishing the fuzzy synthesized evaluation model.展开更多
Carbon-based electric double layer capacitors(EDLCs)hold tremendous potentials due to their high-power performance and excellent cycle stability.However,the practical use of EDLCs is limited by the low energy density ...Carbon-based electric double layer capacitors(EDLCs)hold tremendous potentials due to their high-power performance and excellent cycle stability.However,the practical use of EDLCs is limited by the low energy density in aqueous electrolyte and sluggish diffusion kinetics in organic or/and ionic liquids electrolyte.Herein,3D carbon frameworks(3DCFs)constructed by interconnected nanocages(10-20 nm)with an ultrathin wall of ca.2 nm have been fabricated,which possess high specific surface area,hierarchical porosity and good conductive network.After deoxidization,the deoxidized 3DCF(3DCFDO)exhibits a record low IR drop of 0.064 V at 100 A g^−1 and ultrafast charge/discharge rate up to 10 V s^−1.The related device can be charged up to 77.4%of its maximum capacitance in 0.65 s at 100 A g^−1 in 6 M KOH.It has been found that the 3DCF-DO has a great affinity to EMIMBF4,resulting in a high specific capacitance of 174 F g^−1 at 1 A g^−1,and a high energy density of 34 Wh kg^−1 at an ultrahigh power density of 150 kW kg^−1 at 4 V after a fast charge in 1.11 s.This work provides a facile fabrication of novel 3D carbon frameworks for supercapacitors with ultrafast charge/discharge rate and high energy-power density.展开更多
In the micro-grid photovoltaic systems, the random changes of solar radiation enable lead-acid batteries to experience low SOC (State of Charge) or overcharged for periods of time if directly charged with such traditi...In the micro-grid photovoltaic systems, the random changes of solar radiation enable lead-acid batteries to experience low SOC (State of Charge) or overcharged for periods of time if directly charged with such traditional methods as decreased charging current, which will reduce lifetime of batteries. What’s more, it’s difficult to find a proper reduction coefficient in decreasing charging current. To adapt to the random changes of circumstance and avoid selecting the reduction coefficient, a new fast charging method named decreased charging current based on SOC is proposed to apply into micro-grid photovoltaic systems. It combines batteries’ SOC with the maximum charging voltage to determine the charging rate without strictly selecting reduction coefficient. By close-loop current control strategy and related scheme, the experiment proves the new method is feasible and verifies that, comparing with decreased charging current, the improved method make batteries’ SOC reach 100% in shorter time as well as the temperature of batteries raise more slowly.展开更多
Atomic radiative data such as excitation energies, transition wavelengths, radiative rates, and level lifetimes with high precision are the essential parameters for the abundance analysis, simulation, and diagnostics ...Atomic radiative data such as excitation energies, transition wavelengths, radiative rates, and level lifetimes with high precision are the essential parameters for the abundance analysis, simulation, and diagnostics in fusion and astrophysical plasmas. In this work, we mainly focus on reviewing our two projects performed in the past decade. One is about the ions with Z■30 that are generally of astrophysical interest, and the other one is about the highly charged krypton(Z = 36)and tungsten(Z = 74) ions that are relevant in research of magnetic confinement fusion. Two different and independent methods, namely, multiconfiguration Dirac–Hartree–Fock(MCDHF) and the relativistic many-body perturbation theory(RMBPT) are usually used in our studies. As a complement/extension to our previous works for highly charged tungsten ions with open M-shell and open N-shell, we also mainly focus on presenting and discussing our complete RMBPT and MCDHF calculations for the excitation energies, wavelengths, electric dipole(E1), magnetic dipole(M1), electric quadrupole(E2), and magnetic quadrupole(M2) transition properties, and level lifetimes for the lowest 148 levels belonging to the 3l3configurations in Al-like W61+. We also summarize the uncertainties of our systematical theoretical calculations, by cross-checking/validating our datasets from our RMBPT and MCDHF calculations, and by detailed comparisons with available accurate observations and other theoretical calculations. The data are openly available in Science Data Bank at https://doi.org/10.57760/sciencedb.10569.展开更多
This study employed numerical simulations to explore the impact of varying ice nucleation processes on the microphysics and electrification within thunderstorm clouds.A two-dimensional cumulus model,incorporating both...This study employed numerical simulations to explore the impact of varying ice nucleation processes on the microphysics and electrification within thunderstorm clouds.A two-dimensional cumulus model,incorporating both noninductive and inductive charge separation schemes,was utilized.The findings revealed that the freezing nucleation mechanism significantly influenced the microphysical development,electrification,and charge structure of thunderstorms.Homogeneous freezing generated a large quantity of small ice crystals near the cloud tops,which were primarily responsible for the development of positive charge regions through a non-inductive charging process.Conversely,heterogeneous freezing resulted in larger ice crystals,enhancing graupel formation and leading to a more rapid and intense charge separation rate of around-15°C.Ice crystals formed heterogeneously and charged negatively during the development stage,resulting in an inverted dipole charge structure.When both immersion and homogeneous freezing processes were considered,the competition between these two distinct freezing processes resulted in reduced cloud water content and weaker electrification.Under conditions of low cloud water content at lower storm levels,graupel particles were negatively charged through non-inductive charging,causing the charge structure to quickly revert to a normal dipole structure.展开更多
文摘In recent times, lithium-ion batteries have been widely used owing to their high energy density, extended cycle lifespan, and minimal self-discharge rate. The design of high-speed rechargeable lithium-ion batteries faces a significant challenge owing to the need to increase average electric power during charging. This challenge results from the direct influence of the power level on the rate of chemical reactions occurring in the battery electrodes. In this study, the Taguchi optimization method was used to enhance the average electric power during the charging process of lithium-ion batteries. The Taguchi technique is a statistical strategy that facilitates the systematic and efficient evaluation of numerous experimental variables. The proposed method involved varying seven input factors, including positive electrode thickness, positive electrode material, positive electrode active material volume fraction, negative electrode active material volume fraction, separator thickness, positive current collector thickness, and negative current collector thickness. Three levels were assigned to each control factor to identify the optimal conditions and maximize the average electric power during charging. Moreover, a variance assessment analysis was conducted to validate the results obtained from the Taguchi analysis. The results revealed that the Taguchi method was an eff ective approach for optimizing the average electric power during the charging of lithium-ion batteries. This indicates that the positive electrode material, followed by the separator thickness and the negative electrode active material volume fraction, was key factors significantly infl uencing the average electric power during the charging of lithium-ion batteries response. The identification of optimal conditions resulted in the improved performance of lithium-ion batteries, extending their potential in various applications. Particularly, lithium-ion batteries with average electric power of 16 W and 17 W during charging were designed and simulated in the range of 0-12000 s using COMSOL Multiphysics software. This study efficiently employs the Taguchi optimization technique to develop lithium-ion batteries capable of storing a predetermined average electric power during the charging phase. Therefore, this method enables the battery to achieve complete charging within a specific timeframe tailored to a specificapplication. The implementation of this method can save costs, time, and materials compared with other alternative methods, such as the trial-and-error approach.
基金conducted by the Fundamental Research Center of Artificial Photosynthesis(FReCAP)financially supported by the National Natural Science Foundation of China(22172011 and 22088102)+1 种基金the National Key R&D Program of China(2022YFA0911904)the Fundamental Research Funds for the Central Universities(DUT22LK06,DUT22QN213 and DUT23LAB611)。
文摘Inspired by the function of crucial components in photosystemⅡ(PSⅡ),electrochemical and dyesensitized photoelectrochemical(DSPEC)water oxidation devices were constructed by the selfassembly of well-designed amphipathic Ru(bda)-based catalysts(bda=2,2'-bipyrdine-6,6'-dicarbonoxyl acid)and aliphatic chain decorated electrode surfaces,forming lipid bilayer membrane(LBM)-like structures.The Ru(bda)catalysts on electrode-supported LBM films demonstrated remarkable water oxidation performance with different O-O formation mechanisms.However,compared to the slow charge transfer process,the O-O formation pathways did not determine the PEC water oxidation efficiency of the dyesensitized photoanodes,and the different reaction rates for similar catalysts with different catalytic paths did not determine the PEC performance of the DSPECs.Instead,charge transfer plays a decisive role in the PEC water oxidation rate.When an indolo[3,2-b]carbazole derivative was introduced between the Ru(bda)catalysts and aliphatic chain-modified photosensitizer in LBM films,serving as a charge transfer mediator for the tyrosine-histidine pair in PSⅡ,the PEC water oxidation performance of the corresponding photoanodes was dramatically enhanced.
基金Supported by the National Natural Science Foundation of China(No.51205302)Fundamental Research Funds for the Central Universities(No.K5051304011)
文摘Under an in-phase assumption, the complete charging for an energy harvesting system is studied, which consists of a piezoelectric energy harvester(PEH), a bridge rectifier, a filter capacitor, a switch, a controller and a rechargeable battery. For the transient charging, the results indicate that the voltage across the filter capacitor increases as the charging proceeds, which is consistent with that reported in the literature. However, a new finding shows that the charging rate and energy harvesting efficiency decrease over time after their respective peak values are acquired.For the steady-state charging, the results reveal that the energy harvesting efficiency can be adjusted by altering the critical charging voltage that controls the transition of the system. The optimal energy harvesting efficiency is limited by the optimal efficiency of the transient charging. Finally, the relationship between the critical charging voltage and the equivalent resistance of the controller and rechargeable battery is established explicitly.
文摘Based on the externality theory and the environmental value theory, the hypothesis of charging for waste dumping of open-pit metal mines was put forth. The charging methods were designed according to the characteristics of waste dumping of openpit metal mines, including charging based on the dumping amount of the total waste, multi-charging factors, exceeding standard punishment charging, and so on. The main charging parameter is based on the dumping area rather than the total amount of waste dumping. The charging model of waste dumping of open-pit mines was formulated, and the charging rate was divided into two parts, i.e., the standard charging rate and the differential charging rate. The standard charging rate was derived using the equilibrium dynamic model, whereas the differential one was obtained by establishing the fuzzy synthesized evaluation model.
基金the financial support from the National Natural Science Foundation of China(51672033,U1610255,U1703251).
文摘Carbon-based electric double layer capacitors(EDLCs)hold tremendous potentials due to their high-power performance and excellent cycle stability.However,the practical use of EDLCs is limited by the low energy density in aqueous electrolyte and sluggish diffusion kinetics in organic or/and ionic liquids electrolyte.Herein,3D carbon frameworks(3DCFs)constructed by interconnected nanocages(10-20 nm)with an ultrathin wall of ca.2 nm have been fabricated,which possess high specific surface area,hierarchical porosity and good conductive network.After deoxidization,the deoxidized 3DCF(3DCFDO)exhibits a record low IR drop of 0.064 V at 100 A g^−1 and ultrafast charge/discharge rate up to 10 V s^−1.The related device can be charged up to 77.4%of its maximum capacitance in 0.65 s at 100 A g^−1 in 6 M KOH.It has been found that the 3DCF-DO has a great affinity to EMIMBF4,resulting in a high specific capacitance of 174 F g^−1 at 1 A g^−1,and a high energy density of 34 Wh kg^−1 at an ultrahigh power density of 150 kW kg^−1 at 4 V after a fast charge in 1.11 s.This work provides a facile fabrication of novel 3D carbon frameworks for supercapacitors with ultrafast charge/discharge rate and high energy-power density.
文摘In the micro-grid photovoltaic systems, the random changes of solar radiation enable lead-acid batteries to experience low SOC (State of Charge) or overcharged for periods of time if directly charged with such traditional methods as decreased charging current, which will reduce lifetime of batteries. What’s more, it’s difficult to find a proper reduction coefficient in decreasing charging current. To adapt to the random changes of circumstance and avoid selecting the reduction coefficient, a new fast charging method named decreased charging current based on SOC is proposed to apply into micro-grid photovoltaic systems. It combines batteries’ SOC with the maximum charging voltage to determine the charging rate without strictly selecting reduction coefficient. By close-loop current control strategy and related scheme, the experiment proves the new method is feasible and verifies that, comparing with decreased charging current, the improved method make batteries’ SOC reach 100% in shorter time as well as the temperature of batteries raise more slowly.
基金the support from the National Natural Science Foundation of China (Grant Nos. 12074081 and 12104095)。
文摘Atomic radiative data such as excitation energies, transition wavelengths, radiative rates, and level lifetimes with high precision are the essential parameters for the abundance analysis, simulation, and diagnostics in fusion and astrophysical plasmas. In this work, we mainly focus on reviewing our two projects performed in the past decade. One is about the ions with Z■30 that are generally of astrophysical interest, and the other one is about the highly charged krypton(Z = 36)and tungsten(Z = 74) ions that are relevant in research of magnetic confinement fusion. Two different and independent methods, namely, multiconfiguration Dirac–Hartree–Fock(MCDHF) and the relativistic many-body perturbation theory(RMBPT) are usually used in our studies. As a complement/extension to our previous works for highly charged tungsten ions with open M-shell and open N-shell, we also mainly focus on presenting and discussing our complete RMBPT and MCDHF calculations for the excitation energies, wavelengths, electric dipole(E1), magnetic dipole(M1), electric quadrupole(E2), and magnetic quadrupole(M2) transition properties, and level lifetimes for the lowest 148 levels belonging to the 3l3configurations in Al-like W61+. We also summarize the uncertainties of our systematical theoretical calculations, by cross-checking/validating our datasets from our RMBPT and MCDHF calculations, and by detailed comparisons with available accurate observations and other theoretical calculations. The data are openly available in Science Data Bank at https://doi.org/10.57760/sciencedb.10569.
基金National Natural Science Foundation of China (41805002)Joint Funds of the Zhejiang Provincial Natural Science Foundation of China (LZJMZ24D050009)+1 种基金Startup Foundation for Introducing Talent of NUIST (2016r042)Hubei Provincial Natural Science Foundation of China (2021CFB571)。
文摘This study employed numerical simulations to explore the impact of varying ice nucleation processes on the microphysics and electrification within thunderstorm clouds.A two-dimensional cumulus model,incorporating both noninductive and inductive charge separation schemes,was utilized.The findings revealed that the freezing nucleation mechanism significantly influenced the microphysical development,electrification,and charge structure of thunderstorms.Homogeneous freezing generated a large quantity of small ice crystals near the cloud tops,which were primarily responsible for the development of positive charge regions through a non-inductive charging process.Conversely,heterogeneous freezing resulted in larger ice crystals,enhancing graupel formation and leading to a more rapid and intense charge separation rate of around-15°C.Ice crystals formed heterogeneously and charged negatively during the development stage,resulting in an inverted dipole charge structure.When both immersion and homogeneous freezing processes were considered,the competition between these two distinct freezing processes resulted in reduced cloud water content and weaker electrification.Under conditions of low cloud water content at lower storm levels,graupel particles were negatively charged through non-inductive charging,causing the charge structure to quickly revert to a normal dipole structure.
