Methods of suppressing ion migration in n-i-p perovskite solar cells

In the past 10 years,perovskite solar cells(PSCs)have undergone extremely rapid development,with a record certified power conversion efficiency(PCE)of 26.7%,which is very close to the limit efficiency.However,the inherent instability caused by ion migration impedes the realization of long-term operationally stable PSCs.In this review,the types and mechanisms of ion migration occurring in various functional layers of negative-intrinsic-positive(n-i-p)PSCs are summarized.Additionally,methods of suppressing ion migration are systematically discussed.Finally,the prospects of current challenges and future development directions are proposed to advance the achievement of high-performance regular PSCs with high stability and PCE.

Recent research advances of self-discharge in supercapacitors:Mechanisms and suppressing strategies

Supercapacitors are one of the most promising energy storage devices in the fields of vehicle transportation,flexible electronic devices,aerospace,etc.However,the existed self-discharge that is the spontaneous voltage decay after supercapacitors are fully charged,brings about the wide gap between experimental studies and practical utilization of supercapacitors.Although eliminating the selfdischarge completely is not reachable,suppressing the self-discharge rate to the lowest point is possible and feasible.So far,the significant endeavors have been devoted to achieve this goal.Herein,we summary and discuss the possible mechanisms for the self-discharge and the underlying influence factors.Moreover,the strategies to suppress the self-discharge are systemically summed up by three independent but unified aspects:modifying the electrode,modulating the electrolyte and tuning the separator.Finally,the major challenges to suppress the self-discharge of supercapacitors are concluded and the promising strategies are also pointed out and discussed.This review is presented with the view of serving as a guideline to suppress the self-discharge of supercapacitors and to across-the-board facilitate their widespread application.

A review of fire-extinguishing agent on suppressing lithium-ion batteries fire

Safety issue of lithium-ion batteries(LIBs)such as fires and explosions is a significant challenge for their large scale applications.Considering the continuously increased battery energy density and wider large-scale battery pack applications,the possibility of LIBs fire significantly increases.Because of the fast burning and the easy re-ignition characteristics of LIBs,achieving an efficient and prompt LIBs fire suppression is critical for minimizing the fire hazards.Different from conventional fire hazards,the LIBs fire shows complicated and comprehensive characteristics,and an effective and suitable fire-extinguishing agent particularly designed for LIBs is highly desirable.Considerable efforts have been devoted to this topic,to the best of our knowledge,a comprehensive review on this regard is still rare.Moreover,in practice,a guidance for the design and selections of a proper fire-extinguishing agent for LIBs is urgently needed.Herein,the special mechanisms and characteristics for LIBs fire and the corresponding design principles for LIBs fire-extinguishing agent were introduced.It is revealed that a fire-extinguishing agent developed for LIBs fire will most likely need a high heat capacity,high wetting,low viscosity and low electrical conductivity.After a comprehensive comparison of these agents in terms of these performances,water-based fire-extinguishing agents show best.Several typical fire-extinguishing agents such as gaseous agents,dry powders,water-based and aerosol fire-extinguishing agents were then introduced,and their fire extinguishment mechanisms were presented.Finally,their effectiveness in suppressing the fire were summarized.Water-based fire-extinguishing agents possess high cooling capacity and excellent anti-reflash performance for the fire.We believe this review could shed light on developing an efficient fire-extinguishing agent particularly designed for LIBs.

Numerical simulations of sloshing and suppressing sloshing using the optimization technology method

Sloshing is a common phenomenon in nature and industry, and it is important in many fields, such as marine engineering and aerospace engineering. To reduce the sloshing load on the side walls, the topology optimization and optimal control methods are used to design the shape of the board, which is fixed in the middle of the tank. The results show that the new board shape, which is designed via topology optimization, can significantly reduce the sloshing load on the side wall.

The efficiency and toxicity of dodecafluoro-2-methylpentan-3-one in suppressing lithium-ion battery fire

Currently,the effective and clean suppression of lithium-ion battery(LIB)fires remains a challenge.The present work investigates the use of various inhibitor doses(Xin)of dodecafluoro-2-methylpentan-3-one(C_(6) F_(12)O)in 300 Ah LIBs,and systematically examines the thermal and toxic hazards of the extinguished batteries via real scale combustion and gas analysis.The inhibitor is shown to be completely effective.The inhibition mechanism involves a combination of chemical inhibition and physical cooling.While the chemical inhibition effect tends to saturate with increasing Xin,the physical cooling remains effective at higher inhibitor doses.However,extinguishing the battery fire with a high Xin of C_(6)F_(12)O is found to incur serious toxicity problems.These results are expected to provide a guideline for the design of inhibitor doses for the suppression of LIB fires.

Evidence of X-mode heating suppressing O-mode heating

In this study,we present three experiments carried out at the EISCAT(European Incoherent Scatter Scientific Association)heating facility on October 29 and 30,2015.The results from the first experiment showed overshoot during the O-mode heating period.The second experiment,which used cold-start X-mode heating,showed the generation of parametric decay instability,whereas overshoot was not observed.The third experiment used power-stepped X-mode heating with noticeable O-mode wave leakage.Parametric decay instability and oscillating two-stream instability were generated at the O-mode reflection height without the overshoot effect,which implies suppression of the thermal parametric instability with X-mode heating.We propose that the electron temperature increased because X-mode heating below the upper hybrid height decreased the growth rate of the thermal parametric instability.

Retrofitting Sprinkler Systems for Suppressing Dust Generated by Moving Vehicles Inside Farms

Fugitive dust is one of the well known problems in agriculture and it affects both humans and machine producing quality. Dust problems can seriously cause harmful diseases to workers and ruin expensive equipments. In this study, a dust formation generated in open environment by vehicles was analyzed on unpaved roads. Formed dust was measured by calculating total forces on the PM10 （airborne particles smaller than 10 mm） of dust particles, such as air velocity, gravity forces and air turbulence generated by the moving vehicle. The water fogger nozzle discharge was measured to determine the approximate droplets quantity in the air. The foggers were used to suppress the generated dust in an open environment via installing a proposed automatic suppression system which opens automatically when vehicles pass under the system. The relationship between water droplet speed and ability of collecting fugitive dust showed that high air temperature above 40oC and wind speed above 10 m s-1 have negative effects on the system’s ability of collecting dust due to evaporation of small radius droplets and/or drifting water droplets away from the effective area. The overall system efficiency was found to be 85% and the proposed dust suppression system was found to be a satisfying solution for reducing fugitive dust hazards.

Suppressing random noise to broaden the useful bandwidth of seismic reflection data

The signal-to-noise ratio （SNR） of seismic reflection data in many areas is rather poor and conventional two-dimensional filters designed to suppress noise with different moveout from the signal tend to generate artifacts. We have extended a method of multichannel filtering, based on the hypothesis that signals on adjacent channels are similar, for enhancing the SNR on stacked sections. Using only the mid-range frequencies where the SNR is highest, the event trend is found for overlapping windows on the section and the average signal vector is calculated. Then the data from the full bandwidth section are projected onto the spatially varying unit similarity vectors and the results are merged for the overlapping windows. Application of the method to synthetic data containing steeply dipping events and to a stacked section for a marine 2D line has produced good results. The modifications we have introduced carry a small overhead in computing time but they should enable the method to be used effectively even on sections containing steep dips.

Suppressing secondary reactions of coal pyrolysis by reducing pressure and mounting internals in fixed-bed reactor

Pyrolysis of Shenmu coal was performed in fixed-bed reactors indirectly heated by reducing operating pressure and mounting internals in the reactor to explore their synergetic effects on coal pyrolysis. Mounting internals particularly designed greatly improved the heat transfer inside coal bed and raised the yield of tar production.Reducing pressure further facilitated the production of tar through its suppression of secondary reactions occurring in the reactor. The absolute increase in tar yield reached 3.33 wt% in comparison with the pyrolysis in the reactor without internals under atmospheric pressure. The obtained tar yield in the reactor with internals under reduced pressure was even higher than the yield of Gray–King assay. Through experiments in a laboratory fixed bed reactor, it was also clarified that the effect of reducing pressure is related to volatile release rate in pyrolysis. It did not obviously vary tar yield at pyrolysis temperatures below 600 ℃, while the effect was evident at 650 and 700 ℃ but became limited again above 800 ℃. Under reduced pressure the produced tar contained more aliphatics and phenols but less aromatics.

Suppressing Charge Recombination in ZnO-Nanorod-Based Perovskite Solar Cells with Atomic-Layer-Deposition TiO2

ZnO nanorods are passivated with a TiO2 interracial layer and applied in the CH3NH3PbI3 perovskite solar cell, which prepared by the atomic layer deposition method show a positive effect on the tiff factor and power conversion efficiency. With TiO2 interracial passivation, the charge recombination in the ZnO/CH3NH3PbI3 interface is effectively suppressed and the maximum power conversion efficiency is enhanced from 11.9% to 13.4%.

Cavity-Suppressing Electrode Integrated with Multi-Quantum Well Emitter:A Universal Approach Toward High-Performance Blue TADF Top Emission OLED

A novel device structure for thermally activated delayed fluorescence(TADF)top emission organic light-emitting diodes(TEOLEDs)that improves the viewing angle characteristics and reduces the efficiency roll-off is presented.Furthermore,we describe the design and fabrication of a cavity-suppressing electrode(CSE),Ag(12 nm)/WO_(3)(65 nm)/Ag(12 nm)that can be used as a transparent cathode.While the TADF-TEOLED fabricated using the CSE exhibits higher external quantum efficiency(EQE)and improved angular dependency than the device fabricated using the microcavity-based Ag electrode,it suffers from low color purity and severe efficiency roll-off.These drawbacks can be reduced by using an optimized multi-quantum well emissive layer(MQW EML).The CSE-based TADF-TEOLED with an MQW EML fabricated herein exhibits a high EQE(18.05%),high color purity(full width at half maximum~59 nm),reduced efficiency roll-off(~46%at 1000 cd m^(−2)),and low angular dependence.These improvements can be attributed to the synergistic effect of the CSE and MQW EML.An optimized transparent CSE improves charge injection and light outcoupling with low angular dependence,and the MQW EML effectively confines charges and excitons,thereby improving the color purity and EQE significantly.The proposed approach facilitates the optimization of multiple output characteristics of TEOLEDs for future display applications.

Effect of suppressing dust by multi-direction whirling air curtain on fully mechanized mining face

A combined method of numerical simulation and field testing was adopted in this study in the interest of solving the problem of hard to control high concentrate dusts on a fully mechanized mining face. In addi- tion, the dust suppression effect of a multi-direction whirling air curtain was studied in this paper. Under the influence of the wall attachment effect, the compressed air which blows out from the two-phase or three-phase radial outlets on the generator of the air curtain can form a multi-direction whirling air curtain, which can cover the whole roadway section of a fully mechanized mining face. The traditional method of controlling dust is a forcing system with exhaust overlap which has the major disadvantage of lacking a jet effect and consequently results in poor dust control. It is difficult to form the air flow field within the range of Lp ≤ 5√S. However, due to the effect of this novel system, the radial airflow can be turned into axial airflow allowing fresh air to flow through the length of the heading. The air flow field which is good at controlling dust diffusion can be formed 12.8 m from the heading face. Furthermore, the field measurement results show that before the application of a multi-direction whirling air curtain, the dust concentration is 348.6 mg/m^3 and 271.4 mg/m^3 respectively at the roadway cross-section measurement points which are 5 m and 10 m from the heading face. However, after the application of the multi-direction whirling air curtain, the dust concentration is only 61.2 mg/m3 and 14.8 mg/m^3, respectively. Therefore, the dust control effect of a multi-direction whirling air curtain is obvious.

Simultaneously Suppressing Low-Frequency and Relaxation Oscillation Intensity Noise in a DBR Single-Frequency Phosphate Fiber Laser

Effective multiple optoelectronic feedback circuits for simultaneously suppressing low-frequency and relaxation oscillation intensity noise in a single-frequency phosphate fiber laser are demonstrated. The forward transfer function, which relates the laser output intensity to the pump modulations, is measured and analyzed. A custom two-path feedback system operating at different frequency bands is designed to adjust the pump current directly. The relative intensity noise is decreased by 20dB from 0.2 to 5kHz and over lOdB from 5 to lOkHz. The relaxation oscillation peak is suppressed by 22dB. In addition, a long term （24h） laser instability of less than 0.05% is achieved.

Experimental study of suppressing the unbalanced response vibration of rotor system with a G-type integral squeeze film damper

Conventional squeeze film dampers have numerous challenges including lock up,bistable response and incoordinate precession.In order to resolve these nonlinear problems,a novel G-type integral squeeze film damper(GISFD)is proposed in this research.The experimental test rig is provided to investigate the rotor system with an unbalanced single disk.Numerical simulation results show that the structural design of GISFD is reasonable,which can ensure its safe and stable operation.The influence of different support stiffnesses on the first-order speed of the rotor system is analyzed.Experimental results show that GISFD can effectively suppress the unbalanced response vibration of the rotor.In a certain range,it is found that the suppression effect of GISFD increases with the increase in the kinematic viscosity of the damping fluid.When the silicone oil with kinematic viscosity coefficients v=30.0 cm^(2)/s is employed,the vibration reduction of GISFD is approximately 71.51%.Furthermore,the experimental results show that with the increase of the unbalance,there is a linear relationship between the unbalance and the corresponding amplitude of the unbalanced response.It is concluded that GISFD has excellent linear damping characteristics and reduces the sensitivity of the rotor system to the unbalanced mass.

Modeling and game strategy analysis of suppressing IADS for multiple fighters' cooperation

This paper addresses the problem of suppression of the integrated air defense system(IADS) by multiple fighters’ cooperation. Considering the dynamic changing of the number of the nodes in the operational process, a profit model for the influence of the mission’s cost for the whole system is developed for both offense and defensive sides. The scenario analysis is given for the process of suppressing the IADS by multiple fighters. Based on this scenario analysis, the modeling method and the specific expression for the payoff function are proposed in four cases for each node. Moreover, a distributed virtual learning algorithm is designed for the n-person and n-strategy game, and the mixed strategy Nash equilibrium(MSNE) of this game can be solved from the n × m × 3-dimensional profit space. Finally, the simulation examples are provided to demonstrate the effectiveness of the proposed model and the game algorithm.

Suppressed Internal Intrinsic Stress Engineering in High-Performance Ni-Rich Cathode Via Multi layered In Situ Coating Structure

LiNi_(x)Co_(y)Al_(z)O_(2)(NCA)cathode materials are drawing widespread attention,but the huge gap between the ideal and present cyclic stability still hinders their further commercial application,especially for the Ni-rich LiNi_(x)Co_(y)Al_(z)O_(2)(x>0.8,x+y+z=1)cathode material,which is owing to the structural degradation and particles'intrinsic fracture.To tackle the problems,Li_(0.5)La_(2)Al_(0.5)O_(4)in situ coated and Mn compensating doped multilayer LiNi_(0.82)Co_(0.14)Al_(0.04)O_(2)was prepared.XRD refinement indicates that La-Mn co-modifying could realize appropriate Li/Ni disorder degree.Calculated results and in situ XRD patterns reveal that the LLAO coating layer could effectively restrain crack in secondary particles benefited from the suppressed internal strain.AFM further improves as NCA-LM2 has superior mechanical property.The SEM,TEM,XPS tests indicate that the cycled cathode with LLAO-Mn modification displays a more complete morphology and less side reaction with electrolyte.DEMS was used to further investigate cathode-electrolyte interface which was reflected by gas evolution.NCA-LM2 releases less CO_(2)than NCA-P indexing on a more stable surface.The modified material presents outstanding capacity retention of 96.2%after 100 cycles in the voltage range of 3.0-4.4 V at 1C,13%higher than that of the pristine and 80.8%at 1 C after 300 cycles.This excellent electrochemical performance could be attributed to the fact that the high chemically stable coating layer of Li_(0.5)La_(2)Al_(0.5)O_(4)(LLAO)could enhance the interface and the Mn doping layer could suppress the influence of the lattice mismatch and distortion.We believe that it can be a useful strategy for the modification of Ni-rich cathode material and other advanced functional material.

Progress on Transition Metal Ions Dissolution Suppression Strategies in Prussian Blue Analogs for Aqueous Sodium-/Potassium-Ion Batteries

Aqueous sodium-ion batteries(ASIBs)and aqueous potassium-ion batteries(APIBs)present significant potential for large-scale energy storage due to their cost-effectiveness,safety,and environmental compatibility.Nonetheless,the intricate energy storage mechanisms in aqueous electrolytes place stringent require-ments on the host materials.Prussian blue analogs(PBAs),with their open three-dimensional framework and facile synthesis,stand out as leading candidates for aqueous energy storage.However,PBAs possess a swift capacity fade and limited cycle longevity,for their structural integrity is compromised by the pronounced dis-solution of transition metal(TM)ions in the aqueous milieu.This manuscript provides an exhaustive review of the recent advancements concerning PBAs in ASIBs and APIBs.The dissolution mechanisms of TM ions in PBAs,informed by their structural attributes and redox processes,are thoroughly examined.Moreover,this study delves into innovative design tactics to alleviate the dissolution issue of TM ions.In conclusion,the paper consolidates various strategies for suppressing the dissolution of TM ions in PBAs and posits avenues for prospective exploration of high-safety aqueous sodium-/potassium-ion batteries.

A Novel Clutter Suppression Algorithm for Low-Slow-Small Targets Detecting Based on Sparse Adaptive Filtering

Passive detection of low-slow-small(LSS)targets is easily interfered by direct signal and multipath clutter,and the traditional clutter suppression method has the contradiction between step size and convergence rate.In this paper,a frequency domain clutter suppression algorithm based on sparse adaptive filtering is proposed.The pulse compression operation between the error signal and the input reference signal is added to the cost function as a sparsity constraint,and the criterion for filter weight updating is improved to obtain a purer echo signal.At the same time,the step size and penalty factor are brought into the adaptive iteration process,and the input data is used to drive the adaptive changes of parameters such as step size.The proposed algorithm has a small amount of calculation,which improves the robustness to parameters such as step size,reduces the weight error of the filter and has a good clutter suppression performance.

Recent research progress in the mechanism and suppression of fusion welding-induced liquation cracking of nickel based superalloys

Nickel-based superalloys are extensively used in the crucial hot-section components of industrial gas turbines,aeronautics,and astronautics because of their excellent mechanical properties and corrosion resistance at high temperatures.Fusion welding serves as an effective means for joining and repairing these alloys;however,fusion welding-induced liquation cracking has been a challenging issue.This paper comprehensively reviewed recent liquation cracking,discussing the formation mechanisms,cracking criteria,and remedies.In recent investigations,regulating material composition,changing the preweld heat treatment of the base metal,optimizing the welding process parameters,and applying auxiliary control methods are effective strategies for mitigating cracks.To promote the application of nickel-based superalloys,further research on the combination impact of multiple elements on cracking prevention and specific quantitative criteria for liquation cracking is necessary.

Life on Earth Originated Where Later Microbial Oxygenic Photosynthesis Precipitated Banded Iron Formation, Suppressing Life Diversification for 1.4 Ga

The earliest Precambrian microbial structures appear in successions with banded iron formations (BIF) suggesting genetic relationships. The hypothesis of the deep ocean origin of BIFs associated with Mid-Ocean Ridge (MOR) like features seems to have been recently supported by the discovery of peculiar microbial ecosystems with unique faunal assemblages restricted to these volcanic vents. However, new sedimentological evidence points to the accumulation of varved BIF in huge, very shallow lakes of hydrothermal-water situated on continental plates while passing through thePolar Regions, where UV radiation is minimal. The mineral-rich solutions seeped from numerous fumaroles, providing suitable conditions for chemical reactions between inorganic components, incidentally creating organic-like self-multiplying molecules long before the biologically-initiated BIF deposition. Some of these early chemoautotrophic prokaryotes developed oxygenic photosynthesis during half a year of solar illumination. The released oxygen formed iron oxides and carbonates deposited with amorphous silica (geyserite) in laminae as BIF during 3.8 - 1.9 Ga. BIF deposition consumed most of the photosynthetic oxygen for 1.4 billion years. Intensified cyanobacteria oxygenic photosynthesis during 2.4 - 2.2 Ga raised the atmospheric oxygen content (Great Oxidation Event) over the Polar Regions, forming an oxygen-ozone shield against UV radiation. It gradually extended to lower latitudes, enabling prokaryotes to leave their ecologically stable habitat and acclimatize in new ecosystems, where they diversified, leading to eukaryote evolution. The 231/2° inclination of Earth’s rotation axis differentiated the solar effect on the Polar Regions, which controlled life evolution on Earth, as well as on planet Mars (25° inclination), where life probably did not evolve beyond early prokaryotes.