Studies on the Characteristics of Nitrogen and Phosphorus Pollution of Natural Outcrop Springs in Wudalianchi

Objective] The research aimed to study the characteristics of nitrogen and phosphorus pollution of 30 natural outcrop springs in Wudalianchi, which provides a theoretical basis for the sustainable development and utilization and protection of Wudalianchi natural mineral resources. [Method] Choosing the 30 natural outcrop spring representatives in different regions, samples were collected in low water period, normal water period, wet period respectively, and the content of nitrogen, phosphorus and other contaminants in the samples were determined. Besides, the pollution characteristics of nitrogen and phosphorus in Wudalianchi natural outcrop spring were analyzed. [Result] The 30 natural outcrop spring in Wudalianchi area were seriously polluted by nitrogen. Total nitrogen and nitrate nitrogen were the main forms of nitrogen pollution. The content of total phosphorus and ammonia nitrogen were low. [Conclusion] The natural outcrop spring is mainly caused by agricultural non-point source pollution.

Agricultural non-point nitrogen pollution control function of dierent vegetation types in riparian wetlands: A case study in the Yellow River wetland in China

Riparian wetland is the major transition zone of matter, energy and information transfer between aquatic and terrestrial ecosystems and has important functions of water purification and non-point pollution control. Using the field experiment method and an isotope tracing technique, the agricultural non-point nitrogen pollution control function of different vegetation types in riparian wetland was studied in the Kouma Section of the Yellow River. The results showed that the retention of agricultural non-point nitrogen pollution by riparian wetland soil occurs mainly in top 0-10 cm layer. The amount of nitrogen retained by surface soils associated with three types of vegetation are 0.045 mg/g for Phragmites communis Trin Linn, 0.036 mg/g for Scirpus triqueter Linn, and 0.032 mg/g for Typha angustifolia Linn, which account for 59.21%, 56.25%, and 56.14% of the total nitrogen interception, respectively. Exogenous nitrogen in 0-10 cm soil layer changes more quickly than in other layers. One month after adding KISNO3 to the tested vegetation, nitrogen content was 77.78% for P communis Trin, 68.75% for T. angustifolia, and 8.33% for S. triqueter in the surface soil. After three months, nitrogen content was 93.33% for P. communis Trin, 72.22% for S. triqueter, and 37.50% for T. Angustifolia. There are large differences among vegetation communities respecting to purification of agricultural non-point nitrogen pollution. The nitrogen uptake amount decreases in the sequence： new shoots ofP. communis Trin （9.731 nag/g） 〉 old P. communis Trin （4.939 mg/g） 〉 S. triqueter （0.620 mg/g） 〉 T. angustifolia （0.186 mg/g）. Observations indicated that the presence of riparian wetlands as buffers on and adjacent to stream banks could be recommended to control agricultural non-point pollution.

Non-Point-Source Nitrogen and Phosphorus Loadings from a Small Watershed in the Three Gorges Reservoir Area

Non-point-source pollution has become a major threat to the water quality of the Three Gorges Reservoir(TGR);however,nutrient loadings from terrestrial sources are unclear due to a lack of in situ monitoring.A representative small watershed in the central part of the TGR area was selected to monitor the loss of nitrogen(N) and phosphorous(P) continuously along with the runoff from 2007 through 2009 to understand the exact sources and loadings.Results show that the non-point-source nitrogen and phosphorus comes mainly from the storm runoff from residential areas,citrus orchards and sloping croplands,which contributes up to 76% of the loadings in this watershed.Thus,a crucial measure for controlling non-point-source pollution is to intercept storm runoff from the three sources.Paddy fields provide a sink for non-point-source N and P by intercepting the runoff and sediment along with their different forms of nitrogen and phosphorus.The N and P removal efficiency by paddy fields from residential areas is within the range of 56% to 98%.Paddy fields are an important land-use option for reducing the non-point-source loading of N and P in the TGR area.

Discussion on the Green Tax Stimulation Measure of Nitrogen Fertilizer Non-Point Source Pollution Control-Taking the Dongting Lake Area in China as a Case

A study on designing the tax of nitrogen fertilizer can provide a new method for controlling nitrogen fertilizer non-point source pollution. The tax design of nitrogen fertilizer was discussed by utilizing the external theory and the demand elasticity theory. The results indicated that the coefficient of price elasticity of nitrogen fertilizer demand is -0.21, which instructed that the market demand is in lack of elasticity in the short period and the impact of nitrogen fertilizer manufacturers is subtle. The 11 counties （cities and boroughs） in the Dongting Lake area in China, where the farmland nitrogen application surpassed the average ecological fertilization dosage, is listed to the taxation scope of nitrogen fertilizer tax. The environment loss will reduce 0.07 hundred million RMB yuan and the revenue will increase 0.89 hundred million RMB yuan in the country after levying on nitrogen fertilizer. The loss, which was brought by the decreasing food supplies production, will be 0.58 hundred million RMB yuan and the net social benefit will be 0.38 hundred million RMB yuan following revenue collection. The variation scope of the increasing expenditure of farmers will range from 0.95 to 1.49%. The variation scope of the income of farmers will range from -8.41 to 6.44%. The 5 areas, Yunxi Borough, Junshan Borough, Hanshou County, Jinshi City, and Ziyang Borough, had an increase in food supplies production after the revenue collection. The environment loss will reduce 0.01 hundred million RMB yuan and the revenue will increase 0.16 hundred million RMB yuan in the country after levying on nitrogen fertilizer. The economic benefits, which was brought by the increasing cereals production, will be 0.67 hundred million RMB yuan and the net social benefit will be 0.84 hundred million RMB yuan after revenue collection. The variation scope of the increasing expenditure of farmers will range from 0.95 to 1.06%. The variation scope of the increasing income of farmers will range from 0.69 to 6.44%. Considering the entire social welfare, taxation of nitrogen fertilizer will have more advantages than disadvantages in the Dongting Lake area.

Investigation and Analysis of Three Nitrogen Pollution in Groundwater in Ledong, Hainan Province

[Objectives]This study was conducted to systematically monitor the contents of "three nitrogen",including ammonia nitrogen (NH4^+-N),nitrate nitrogen (NO3^--N) and nitrite nitrogen (NO2^--N) in groundwater in Ledong and analyze the reasons.[Methods]A total of 30 sampling points were set up in Ledong,including 22 ground waters and 8 surface waters.NO3^--N,NH4^+-N,NO2^--N and pH indicators were detected.[Results]① There is a problem of excessive nitrogen in the groundwater of Ledong,Hainan.NH4^+-N and NO3^--N exceeded the standards severely,and the over-standard rates were 27.27% and 13.64%,respectively.NO2^--N didn't exceed the standard.Among them,the highest concentration of NH4^+-N was up to 2.692 mg/L;and the highest concentration of NO3^--N reached 24.071 mg/L.② The pollution trends of NH4^+-N and NO2^--N in Ledong County were similar,and NO3^--N had no similarity.③ There was a regional difference in the groundwater three nitrogen in Ledong,Hainan.The pollution level near the farmland was greater than that far from the farmland.The pollution level near the farm area was greater than that far from the farm area.In addition,in combination with the layout of the sampling points and the test results,it was not found that the area far from the coastline would be lower than the area near the coastline in the pollution level.④ The main reasons for the excessive nitrogen in the groundwater of Ledong,Hainan are farmland fertilization,random discharge of domestic sewage,discharge of aquaculture wastewater,and discharge of industrial water at will.[Conclusions]This study is of great significance to safe prevention and control of groundwater in Ledong.

Characteristics of diffuse pollution of nitrogen and phosphorous from a small town in the hilly area of the central Sichuan Basin,China

Hydrological and hydro-chemical monitoring of nitrogen(N) and phosphorus(P) in a small urbanized catchment was conducted in the hilly area of the central Sichuan Basin,China,from 2010 through 2011.The diffuse N and P loadings in different forms of total nitrogen(TN) and phosphorus(TP),dissolved nitrogen(DN) and phosphorus(DP),as well as particulate nitrogen(PN) and phosphorus(PP) were calculated based on runoff discharges and chemical analyses.The results revealed that the diffuse pollution concentrations of TN,DN,PN,TP,DP and PP exhibited large variations during rainfall events,with peak concentrations occurring during the initial period.For all of the measured parameters,the event mean concentrations(EMCs) were observed to clearly vary among rainfall events.The EMCs of TN,DN,PN,TP,DP and PP(for all of the observed rainfall events) were 10.04,6.62,3.42,1.30,0.47 and0.83 mg/L,respectively.The losses of diffuse N and P exhibited clear seasonal patterns and mainly occurred during the period from July through September,when the losses totaled 99.3 and 9.6 kg/ha for TN and TP,respectively,accounting for 75% and 74% of the total annual loadings.The mean annual loadings of TN and TP were 124.6 and 12.9 kg/ha,respectively.The results indicate that residential areas in the hilly areaof the central Sichuan Basin are subject to high diffuse N and P loadings,posing a serious risk to the receiving water quality.Ecological buffering belts are recommended to incorporate into the urbanized catchment to reduce diffuse pollution.

Nitrogen Removal in Wastewater Irrigation Systems and Its Influence on Groundwater Pollution

The experiment included ten soil columns and field investigation in 1 - 2 year duration. Data on the columns continuously flooded with waste water indicated that when total input of NH4-N reached to above 70% of the NH4-N adsorption capacity in soil the breakthrough would appear in the output . Adequate removal of nitrogen from the waste water would require at least 170 cm deep groundwater table . Fine textured soil would promote denitrification . The columns simulating discontinuous waste water irrigation indicated that denitrification existed only in the partial microenvironment of reduction .Groundwater table depth had no strong influence on nitrogen removal . The investigation in field revealed that the groundwater recharged with waste water was not polluted by nitrogen when the aeration profile was in finer textures owing to the combined contribution of nitrification and denitrification .

Long-Term Assessment of Nitrogen Pollution Load Potential for Groundwater by Mass Balance Analysis in the Tedori River Alluvial Fan Area, Japan

To evaluate the nitrogen pollution load in an aquifer, a water and nitrogen balance analysis was conducted over a thirty-five year period at five yearly intervals. First, we established a two-horizon model comprising a channel/soil horizon, and an aquifer horizon, with exchange of water between the aquifer and river. The nitrogen balance was estimated from the product of nitrogen concentration and water flow obtained from the water balance analysis. The aquifer nitrogen balance results were as follows: 1) In the aquifer horizon, the total nitrogen pollution load potential (NPLP) peaked in the period 1981-1990 at 1800 t·yr-1;following this the NPLP rapidly decreased to about 600 t·yr-1 in the period 2006-2010. The largest NPLP input component of 1000 t·yr-1 in the period 1976-1990 was from farmland. Subsequently, farmland NPLP decreased to only 400 t·yr-1 between 2006 and 2010. The second largest input component, 600 t·yr-1, was effluent from wastewater treatment works (WWTWs) in the period 1986-1990;this also decreased markedly to about 100 t·yr-1 between 2006 and 2010;2) The difference between input and output in the aquifer horizon, used as an index of groundwater pollution, peaked in the period 1986-1990 at about 1200 t·yr-1. This gradually decreased to about 200 t·yr-1 by 2006-2010. 3) The temporal change in NPLP coincided with the nitrogen concentration of the rivers in the study area. In addition, nitrogen concentrations in two test wells were 1.0 mg·l-1 at a depth of 150 m and only 0.25 mg·l-1 at 50 m, suggesting gradual percolation of the nitrogen polluted water deeper in the aquifer.

MRIO model-based study on water nitrogen pollution transfer embodied in international trade

This study uses the global pollutant emission databases and global input-output model in 2015 to calculate the impact of international trade on global water nitrogen emission patterns,based on considering the total amount of pollutant transfer and pollutant emission intensity of trade flows The main conclusions are as follows:(1) There are always a large amount of water nitrogen emissions transferring from developed economies to developing economies embodied in their bilateral trade activities.Small amount of transfers are of some areas with similar endowments of agricultural resources or long distances.(2) In 2015,the net import of water nitrogen pollution embodied in China's trade was 160,000 tons,accounting for 2.72% of the global water nitrogen imports.The sharp increases in cereal imports,together with high food storage as well as high pollution intensity embedded in trade are the main reason.It is recommended that through applying alleviations such as agricultural machinery assistance and technical training to accelerate the transfer and spread of agricultural technology in Africa,Asia,and other regions,thus helping increase agricultural production productivity in underdeveloped areas and reducing the pollution intensity embodied in trade flows from underdeveloped areas to developed areas.

Nitrogen forms and pollution load of Dianchi Lake inflow river runoff in rainy season

With the control of point source pollution in Dianchi Lake basin, and the expansion of Kunming city, non-point source pollution has become the main source pollution of urban water environment and Dianchi Lake. To reveal the nitrogen pollution characteristics in watershed, this research selected key monitoring points and sections at Baoxiang river basin in rainy season which is the peak transported time of non-point source pollution, the nitrogen and hydrological indicators are monitored systematically. The different forms of nitrogen are analyzed, the pollution load of nitrogen are calculated and studied at cardinal sections; combined with the literature data, we compared the water nitrogen characteristics of Dianchi basin and Taihu basin, the main results are as follows:(1) In summer, water nitrogen form of Baoxiang river in the Caohe area is dominated by nitrate nitrogen, while in other areas it is dominated by ammonia nitrogen which is accounted for 31%-50% of total nitrogen;(2) The water pollution loads of Baoxiang river tended to increase from upstream to downstream, from June to August the total nitrogen pollution mainly comes from urban areas and the pollution load is 166.408 t;(3) In Dianchi Lake watershed and Taihu Lake watershed nitrogen concentration of inflow river is higher than that of the lake, nitrate nitrogen concentration between inflow river and lake shows a little difference, while ammonia nitrogen concentration of inflow river is higher than that of the lake. The results can provide the theoretical basis for nonpoint source pollution control and urban water environment planning and improvement in Dianchi Lake Basin.

Controlling effects of forest belts on non-point source pollution of agricultural lands in Taihu Lake area, China

Taihu Lake area is one of the most developed areas in agricultural production. Application of fertilizers and pesticides in large quantities greatly aggravate environmental pollution of this area, and water pollution has worsened to an unbearable condition. Two sampling farms (respectively 1 hm2) under rape-rice rotation and wheat-rice rotation were selected as studied ecosystem and a 5-yr-old Poplar forest and 8-yr-old Metasequoia forest were chosen in the selected areas. By collecting samples of Nitrogen, Phosphorus in water, crops and underground of forest, the transfer and loss of N and P (main water pollutants) in faming ecosystem were studied, and the effects of forest belts on non-point source pollution of agricultural lands was analyzed. The results indicated that the transfer and loss of N and P vary with means of rotation, types of crops and the amount of fertilizer application. Buffering forest belts betweens farmlands and ditches can effectively stop and purify such elements as N and P in soil runoffs, thus controlling non-point source pollution of agricultural lands. When the width ratio of farmland to forest belt is 100 to 40, 50.05% losing N, 29.37% losing P can be absorbed by forest under rape-rice rotation and 30.98% N, 86.73% P can be absorbed by forest under wheat-rice rotation. When the width ratio of farmland to forest belt is 150 to 40, 33.37% losing N, 19.58% losing P can be absorbed by the forest under rape-rice rotation, and under wheat-rice rotation 20.65% lost N and 57.82% lost P can be absorbed. There is only some purification effect when the width ration of farmland to forest belt is 200 to 40. Based on model of buffering forest belts, the width ratio of farmland to forest is determined between 100 to 40 and 150 to 40, because it not only can purify water, but also occupy less farmland. It is suggested that Poplars, with the characteristics of fast-growing and high value, are suitable to be planted as shelter-forest in Taihu Lake Watershed.

Validation of an agricultural non-point source(AGNPS)pollution model for a catchment in the Jiulong River watershed,China

This study tested and evaluated the agricultural non-point source （AGNPS） model for the Wuchuan catchment, a typical agricultural area in the Jiulong River watershed, Fujian Province, China. The AGNPS model was calibrated and validated for the study area with observed data on ten storms. The data on eight storms in 2002 were used for calibration while data on two storms were used for validation of the model. Considering the lack of water quality data over a long-term series, a novel method, comparing an internal nested catchment with its surrounding catchment, was used to supplement the less long-term series data. Dual calibration and validation of the AGNPS model was obtained by this comparison. The results indicate that the correlation coefficients were 0.99 and 0.98 for runoff, 0.94 and 0.95 for the peak runoff rate of the large catchment and the small catchment, respectively, and 0.76 for the sediment of the small catchment only. Each pair of correlation coefficients is homogeneous for the same event for the two catchments. With the exception of the sediment yield and particulate phosphorus, the peak runoff rate and other nutrients were well predicted. Sensitivity analysis showed that the Soil Conservation Service curve number and rainfall quantity were the most sensitive parameters, which resulted in high output variations. Erosivity and other parameters had little influence on the hydrological and quality outputs.

Removal of Nitrogen, Phosphorus, and Organic Pollutants From Water Using Seeding Type Immobilized Microorganisms

Objective To study the possibility of removing nitrogen, phosphorus, and organic pollutants using seeding type immobilized microorganisms. Methods Lakes P and M in Wuhan were chosen as the objects to study the removal of nitrogen, phosphorus, and organic pollutants with the seeding type immobilized microorganisms. Correlations between the quantity of heterotrophic bacteria and the total nitrogen （TN）, total phosphorus （TP）, and total organic carbon （TOC） in the two lakes were studied. The dominant bacteria were detected, inoculated to the sludge and acclimated by increasing nitrogen, phosphorus and decreasing carbon source in an intermittent, time-controlled and fixed-quantity way. The bacteria were then used to prepare the seeding type immobilized microorganisms, selecting diatomite as the adsorbent cartier. The ability and influence factors of removing nitrogen, phosphorus, and organic pollutant from water samples by the seeding type immobilized microorganisms were studied. Results The coefficients of the heterotrophic bacterial quantity correlated with TOC, TP, and TN were 0.9143, 0.8229, 0.7954 in Lake P and 0.9168, 0.7187, 0.6022 in Lake M. Ten strains of dominant heterotrophic bacteria belonging to Pseudomonas, Coccus, Aeromonas, Bacillus, and Enterobateriaceae, separately, were isolated. The appropriate conditions for the seeding type immobilized microorgansims in purifying the water sample were exposure time=24 h, pH=7.0-8.0, and quantity of the immobilized microorganisms=0.75-1g/50 mL. The removal rates of TOC, TP, and TN under the above conditions were 80.2%, 81.6%, and 86.8%, respectively. Conclusion The amount of heterotrophic bacteria in the two lakes was correlated with TOC, TP, and TN. These bacteria could be acclimatized and prepared for the immobilized microorganisms which could effectively remove nitrogen, phosphorus, and mixed organic pollutants in the water sample.

Assessment of Point and Nonpoint Sources Pollution in Songhua River Basin,Northeast China by Using Revised Water Quality Model

Individual participation of pollutants in the pollution load should be estimated even if roughly for the appropriate environmental management of a river basin.It is difficult to identify the sources and to quantify the load, especially in modeling nonpoint source.In this study a revised model was established by integrating point and nonpoint sources into one-dimensional Streeter-Phelps(S-P) model on the basis of real-time hydrologic data and surface water quality monitoring data in the Jilin Reach of the Songhua River Basin.Chemical oxygen demand(COD) and ammonia nitrogen(NH 3-N) loads were estimated.Results showed that COD loads of point source and nonpoint source were 134 958 t/yr and 86 209 t/yr, accounting for 61.02% and 38.98% of total loads, respectively.NH 3-N loads of point source and nonpoint source were 16 739 t/yr and 14 272 t/yr, accounting for 53.98% and 46.02%, respectively.Point source pollution was stronger than nonpoint source pollution in the study area at present.The water quality of upstream was better than that of downstream of the rivers and cities.It is indispensable to treat industrial wastewater and municipal sewage out of point sources, to adopt the best management practices to control diffuse pollutants from agricultural land and urban surface runoff in improving water quality of the Songhua River Basin.The revised S-P model can be successfully used to identify pollution source and quantify point source and nonpoint source loads by calibrating and validating.

The river chief system and agricultural non-point source water pollution control in China

As part of their efforts to control water pollution,local governments in China introduced the river chief system,whereby a named individual undertakes responsibility for protecting a specified waterway.As one of the most prominent sources of water pollution,agricultural non-point-source(NPS)pollution is becoming increasingly serious.Determining whether the river chief system,an institutional reform in China's decentralized environmental regulation regime,is effective in alleviating NPS pollution is important for the realization of green development.The effect of the river chief system on reducing agricultural NPS pollution is explored in this study using panel data from 308 Chinese counties during the period from 2004 to 2015.The results reveal that the negative impact of manure output from animal breeding operations on surface water quality is reduced with the implementation of the river chief system.However,the river chief system is ineffective in dealing with the water pollution caused by fertilizer use.Furthermore,in the current system,cooperation among river chiefs only occurs within a province.Local governments should increase their efforts in reducing fertilizer source loads and preventing fertilizer loads from entering surface waters.In addition,the central government should improve cooperation among the river chiefs in upstream and downstream provinces.

N Cycle, N Flow Trends in Japan, and Strategies for Reducing N_2O Emission and NO_3^- Pollution

To feed an increasing population, large amounts of chemical nitrogen fertilizer have been used to produce much of our food, feed and fiber thereby increasing nitrogen levels in soils, natural waters, crop residues, livestock wastes,and municipal and agricultural wastes, with national and international concern about its potential adverse effects on environmental quality and public health. To understand these phenomena and problems, first the nitrogen cycle and the environment are described. Then recent trends for nitrogen cycling through the food and feed system, N2O emissions from fertilized upland and paddy soils, and NO-3 pollution in ground water in Japan are reported. Finally, mitigation strategies in Japan for reducing N2O emission and NO-3 pollution are proposed, including nitrification inhibitors, controlled release fertilizers, utilization of plant species that could suppress nitrification, utilizing the toposequence, government policy, and appropriate agricultural practices. Of all the technologies presented, use of nitrification inhibitors and controlled release fertilizers are deemed the most important with further development of these aspects of technologies being expected. These practices, if employed worldwide, could help reduce the load, or environmental deterioration, on the Earth's biosphere.

The land-sourced pollution in the Jiaozhou Bay

In recent years, natural environment of the Jiaozhou Bay has been changed largely by fast developing industry and agriculture of the cities around, from which wastewaters were generated. The size of the bay has been continuously shrunk with reduced river flows, resulting in serious contamination to the marine lives in the bay. After analyzing the basic historical data, the authors put forward a suggestion of how to protect the bay ecology for sustaining the resources in the Jiaozhou Bay.

Ionic Liquid Assisted Extraction of Nitrogen and Sulphur-Containing Air Pollutants from Model Oil and Regeneration of the Spent Ionic Liquid

Removal of air pollutants, such as nitrogen and sulphur containing compounds from a model oil (dodecane) was studied. An ionic liquid (1-ethyl-3-methylimidazolium chloride [C2mim] [Cl]) was used as an extractant. Liquid-liquid extraction by using 1-ethyl-3-methylimidazolium chloride [C2mim] [Cl] was found to be a very promising method for the removal of N- and S-compounds. This was evaluated by using a model oil (dodecane) with indole as a neutral nitrogen compound and pyridine as a basic nitrogen compound. Dibenzothiophene (DBT) was used as a sulphur compound. An extraction capacity of up to 90 wt% was achieved for the model oil containing pyridine, while only 76 wt% of indole in the oil was extracted. The extraction capacity of a model sulphur compound DBT was found to be up to 99 wt%. Regeneration of the spent ionic liquid was carried out with toluene back-extraction. A 1:1 toluene-to-IL wt ratio was performed at room temperature. It was observed that, for the spent ionic liquid containing DBT as a model compound more than 85 wt% (corresponding 3852 mg/kg) could be removed from the oil. After the second regeneration cycle, 86 wt% of the DBT was recovered from the ionic liquid to toluene. In the case of indole as the nitrogen containing species, more than 99 wt%, (corresponding to 2993 mg/kg) of the original indole was transferred from the model oil to the ionic liquid. After the first-regeneration cycle of the spent ionic liquid, 54 wt% of the indole–in-IL was transferred to toluene. Thus, both extractions of nitrogen and sulphur model compounds were successfully carried out from model oil and the back-extraction of these compounds from the ionic liquids to toluene demonstrated the proved the concept of the regeneration point of view.