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Numerical Exploration of Asymmetrical Impact Dynamics: Unveiling Nonlinearities in Collision Problems and Resilience of Reinforced Concrete Structures
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作者 AL-Bukhaiti Khalil Yanhui Liu +1 位作者 Shichun Zhao Daguang Han 《Structural Durability & Health Monitoring》 EI 2024年第3期223-254,共32页
This study provides a comprehensive analysis of collision and impact problems’ numerical solutions, focusing ongeometric, contact, and material nonlinearities, all essential in solving large deformation problems duri... This study provides a comprehensive analysis of collision and impact problems’ numerical solutions, focusing ongeometric, contact, and material nonlinearities, all essential in solving large deformation problems during a collision.The initial discussion revolves around the stress and strain of large deformation during a collision, followedby explanations of the fundamental finite element solution method for addressing such issues. The hourglassmode’s control methods, such as single-point reduced integration and contact-collision algorithms are detailedand implemented within the finite element framework. The paper further investigates the dynamic responseand failure modes of Reinforced Concrete (RC) members under asymmetrical impact using a 3D discrete modelin ABAQUS that treats steel bars and concrete connections as bond slips. The model’s validity was confirmedthrough comparisons with the node-sharing algorithm and system energy relations. Experimental parameterswere varied, including the rigid hammer’s mass and initial velocity, concrete strength, and longitudinal and stirrupreinforcement ratios. Findings indicated that increased hammer mass and velocity escalated RC member damage,while increased reinforcement ratios improved impact resistance. Contrarily, increased concrete strength did notsignificantly reduce lateral displacement when considering strain rate effects. The study also explores materialnonlinearity, examining different materials’ responses to collision-induced forces and stresses, demonstratedthrough an elastic rod impact case study. The paper proposes a damage criterion based on the residual axialload-bearing capacity for assessing damage under the asymmetrical impact, showing a correlation betweendamage degree hammer mass and initial velocity. The results, validated through comparison with theoreticaland analytical solutions, verify the ABAQUS program’s accuracy and reliability in analyzing impact problems,offering valuable insights into collision and impact problems’ nonlinearities and practical strategies for enhancingRC structures’ resilience under dynamic stress. 展开更多
关键词 Geometric nonlinearity contact nonlinearity material nonlinearity collision problems finite element method stress and strain damage criterion RC members asymmetrical impact
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Designing of an all-optical time division multiplexing scheme with the help of nonlinear material based tree-net architecture 被引量:2
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作者 Jitendra Nath Roy Anup Kumar Maiti Sourangshu Mukhopadhyay 《Chinese Optics Letters》 SCIE EI CAS CSCD 2006年第8期483-486,共4页
In the field of optical interconnecting network and in super fast photonic computing system, the tree architecture and optical nonlinear materials can play a significant role. Nonlinear optical material may find impor... In the field of optical interconnecting network and in super fast photonic computing system, the tree architecture and optical nonlinear materials can play a significant role. Nonlinear optical material may find important uses in optical switching. Optical switch using nonlinear material makes it possible for one optical signal to control and switch another optical signal through nonlinear interaction in a material. In this communication such materials have been successfully exploited to design an all-optical tree-net architecture, which can be utilized for time division multiplexing scheme in all-optical domain. 展开更多
关键词 TREE Designing of an all-optical time division multiplexing scheme with the help of nonlinear material based tree-net architecture time NET
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An all-optical comparison scheme between two multi-bit data with optical nonlinear material
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作者 Kuladeep Roy Chowdhury Abhijit Sinha Sourangshu Mukhopadhyay 《Chinese Optics Letters》 SCIE EI CAS CSCD 2008年第9期693-696,共4页
Over the last few decades, several all-optical circuits have been proposed to meet the need of high-speed data processing. In some information processing architectures, the role of various analog and digital data comp... Over the last few decades, several all-optical circuits have been proposed to meet the need of high-speed data processing. In some information processing architectures, the role of various analog and digital data comparisons is very important. In this letter, we proposed a multi-bit data comparison scheme. The scheme is based on the switching property of optical nonlinear material. Ultrafast operational speed larger than gigahertz can be expected from this all-optical scheme. 展开更多
关键词 An all-optical comparison scheme between two multi-bit data with optical nonlinear material DATA than BIBO
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Using modified Mach-Zehnder interferometer to get better nonlinear correction term of an isotropic nonlinear material
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作者 Ashish Pal Sourangshu Mukhopadhyay 《Chinese Optics Letters》 SCIE EI CAS CSCD 2009年第7期624-626,共3页
Nonlinear materials have been well established as photo refractive switching material. Important applica- tions of isotropic nonlinear materials are seen in self-focusing, defocusing phenomena, switching systems, etc.... Nonlinear materials have been well established as photo refractive switching material. Important applica- tions of isotropic nonlinear materials are seen in self-focusing, defocusing phenomena, switching systems, etc. The nonlinear correction term is basically responsible for the optical switches. Mach-Zehnder inter- ferometer (MZI) is a well-known arrangement for determining the above correction term, but there are some major problems for finding out the term by MZI. We propose a new method of finding the nonlinear correction term as well as the second order nonlinear susceptibility of the materials by using a modified MZI system. This method may be used to find out the above parameters for any unknown nonlinear material. 展开更多
关键词 Using modified Mach-Zehnder interferometer to get better nonlinear correction term of an isotropic nonlinear material EOM MZI
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All-optical conversion scheme from binary to its MTN form with the help of nonlinear material based tree-net architecture
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作者 Anup Kumar Maiti Jitendra Nath Roy Sourangshu Mukhopadhyay 《Chinese Optics Letters》 SCIE EI CAS CSCD 2007年第8期480-483,共4页
In the field of optical computing and parallel information processing, several number systems have been used for different arithmetic and algebraic operations. Therefore an efficient conversion scheme from one number ... In the field of optical computing and parallel information processing, several number systems have been used for different arithmetic and algebraic operations. Therefore an efficient conversion scheme from one number system to another is very important. Modified trinary number (MTN) has already taken a significant role towards carry and borrow free arithmetic operations. In this communication, we propose a tree-net architecture based all optical conversion scheme from binary number to its MTN form. Optical switch using nonlinear material (NLM) plays an important role. 展开更多
关键词 TREE All-optical conversion scheme from binary to its MTN form with the help of nonlinear material based tree-net architecture NET
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Geometric and material nonlinear analysis of tensegrity structures 被引量:8
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作者 Hoang Chi Tran Jaehong Lee 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2011年第6期938-949,共12页
A numerical method is presented for the large deflection in elastic analysis of tensegrity structures including both geometric and material nonlinearities.The geometric nonlinearity is considered based on both total L... A numerical method is presented for the large deflection in elastic analysis of tensegrity structures including both geometric and material nonlinearities.The geometric nonlinearity is considered based on both total Lagrangian and updated Lagrangian formulations,while the material nonlinearity is treated through elastoplastic stress-strain relationship.The nonlinear equilibrium equations are solved using an incremental-iterative scheme in conjunction with the modified Newton-Raphson method.A computer program is developed to predict the mechanical responses of tensegrity systems under tensile,compressive and flexural loadings.Numerical results obtained are compared with those reported in the literature to demonstrate the accuracy and efficiency of the proposed program.The flexural behavior of the double layer quadruplex tensegrity grid is sufficiently good for lightweight large-span structural applications.On the other hand,its bending strength capacity is not sensitive to the self-stress level. 展开更多
关键词 nonlinear analysis Tensegrity structures Ge- ometric nonlinearity material nonlinearity Large displacements
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Reliability analysis of circular concrete-filled steel tube with material and geometrical nonlinearity 被引量:1
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作者 Tengfei XU Tianyu XIANG +1 位作者 Yulin ZHAN Renda ZHAO 《Journal of Modern Transportation》 2012年第3期138-147,共10页
Most of the previous research on concrete-filled steel tube is restricted to a deterministic approach. To gain clear insight into the random properties of circular concrete-filled steel tube, reliability analysis is c... Most of the previous research on concrete-filled steel tube is restricted to a deterministic approach. To gain clear insight into the random properties of circular concrete-filled steel tube, reliability analysis is carried out in the present study. To obtain the Structural nonlinear response and ultimate resistance capacity, material and geometrical nonlinear analysis of circular concrete-filled steel tube is performed with a three-dimensional degenerated beam ele- ment. Then we investigate the reliability of concrete-filled steel tube using the first-order reliability method combined with nonlinear finite element analysis. The influences of such parameters as material strength, slenderness, initial geo- metrical imperfection, etc. on the reliability of circular concrete-filled steel tube column are studied. It can be con- cluded that inevitable random fluctuation of those parameters has significant influence on structural reliability, and that stochastic or reliability methods can provide a more rational and subjective evaluation on the safety of CFT structures than a deterministic approach. 展开更多
关键词 concrete-filled steel tube RELIABILITY material nonlinearity geometrical nonlinearity
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NEW ORGANIC NONLINEAR OPTICAL MATERIALS OF CINNAMYLIDENE-ACETOPHENONE DERIVATIVES
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作者 Yang CAO Ai Hua YUAN Xiao Ping SHEN Chemistry Department,Suzhou University,Suzhou,215006Wen Jian CHEN Chang Qing LIU Chemistry Department,Yangzhou Teachers College,Yangshou,225002 《Chinese Chemical Letters》 SCIE CAS CSCD 1993年第8期719-720,共2页
we have synthesised a series of new optically nonlinear organic materials of cinnamylidene-acetophenone derivatives which have large nonl inear optical susceptibilities and short cut-off wavelengths.
关键词 SHG der NEW ORGANIC nonlinear OPTICAL materialS OF CINNAMYLIDENE-ACETOPHENONE DERIVATIVES
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A novel formulation of material nonlinear analysis in structural mechanics
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作者 Himanshu Gaur Anupam Srivastav 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2021年第1期36-49,共14页
This article demonstrates a novel approach for material nonlinear analysis.This analysis procedure eliminates tedious and lengthy step by step incremental and then iterative procedure adopted classically and gives dir... This article demonstrates a novel approach for material nonlinear analysis.This analysis procedure eliminates tedious and lengthy step by step incremental and then iterative procedure adopted classically and gives direct results in the linear as well as in nonlinear range of the material behavior.Use of elastic moduli is eliminated.Instead,stress and strain functions are used as the material input in the analysis procedure.These stress and strain functions are directly derived from the stress-strain behavior of the material by the method of curve fitting.This way,the whole stress-strain diagram is utilized in the analysis which naturally exposes the response of structure when loading is in nonlinear range of the material behavior.It is found that it is an excellent computational procedure adopted so far for material nonlinear analysis which gives very accurate results,easy to adopt and simple in calculations.The method eliminates all types of linearity assumptions in basic derivations of equations and hence,eliminates all types of possibility of errors in the analysis procedure as well.As it is required to know stress distribution in the structural body by proper modelling and structural idealization,the proposed analysis approach can be regarded as stress-based analysis procedure.Basic problems such as uniaxial problem,beam bending,and torsion problems are solved.It is found that approach is very suitable for solving the problems of fracture mechanics.Energy release rate for plate with center crack and double cantilever beam specimen is also evaluated.The approach solves the fracture problem with relative ease in strength of material style calculations.For all problems,results are compared with the classical displacement-based liner theory. 展开更多
关键词 Computational methods material nonlinear analysis Fracture mechanics Energy release rate etc
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Nonlinear Hall Effect in Antiferromagnetic Half-Heusler Materials
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作者 Cheng Chen Huaiqiang Wang +1 位作者 Zhilong Yang Haijun Zhang 《Chinese Physics Letters》 SCIE CAS CSCD 2021年第5期78-83,共6页
It has recently been demonstrated that various topological states, including Dirac, Weyl, nodal-line, and triplepoint semimetal phases, can emerge in antiferromagnetic(AFM) half-Heusler compounds. However, how to dete... It has recently been demonstrated that various topological states, including Dirac, Weyl, nodal-line, and triplepoint semimetal phases, can emerge in antiferromagnetic(AFM) half-Heusler compounds. However, how to determine the AFM structure and to distinguish different topological phases from transport behaviors remains unknown. We show that, due to the presence of combined time-reversal and fractional translation symmetry, the recently proposed second-order nonlinear Hall effect can be used to characterize different topological phases with various AFM configurations. Guided by the symmetry analysis, we obtain expressions of the Berry curvature dipole for different AFM configurations. Based on the effective model, we explicitly calculate the Berry curvature dipole, which is found to be vanishingly small for the triple-point semimetal phase, and large in the Weyl semimetal phase. Our results not only put forward an effective method for the identification of magnetic orders and topological phases in AFM half-Heusler materials, but also suggest these materials as a versatile platform for engineering the nonlinear Hall effect. 展开更多
关键词 AFM DIRAC HAMILTONIAN nonlinear Hall Effect in Antiferromagnetic Half-Heusler materials
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INCREMENTAL ANALYSIS FOR NONLINEAR RUBBER-LIKE MATERIALS BY HYBRID STRESS FINITE ELEMENT
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作者 范家齐 杨晓翔 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 1989年第6期529-537,共9页
In this paper, on the basis of the incremental Reissner variational principle.a nonlinear finite element analysis has been accomplished and a formulation of hybrid stress element has been presented for incompressible ... In this paper, on the basis of the incremental Reissner variational principle.a nonlinear finite element analysis has been accomplished and a formulation of hybrid stress element has been presented for incompressible Mooney rubber-like materials. The corrected terms of the non-equilibrium force and the incompressibility deviation are considered in the formulation. The computed values of numerical example agree very closely with the exact solution. 展开更多
关键词 INCREMENTAL ANALYSIS FOR nonlinear RUBBER-LIKE materialS BY HYBRID STRESS FINITE ELEMENT
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SYNTHESIS AND CHARACTERIZATION OF NOVEL SOL-GEL DOPED ORGANIC/INORGANIC HYBRID NONLINEAR OPTICAL MATERIALS
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作者 XI Hongxia LIU Guanxin +1 位作者 WANG Huan LI Zhong 《Chinese Journal of Reactive Polymers》 2003年第1期1-9,共9页
hydroxy-4-nitro azobenzene (NHA) and 4-amino-4-nitro azobenzene (DO3) were prepared respectively from p-nitrophenylamine as a precursor compound. Two kinds of doped organic/inorganic hybrid nonlinear optical (NLO) mat... hydroxy-4-nitro azobenzene (NHA) and 4-amino-4-nitro azobenzene (DO3) were prepared respectively from p-nitrophenylamine as a precursor compound. Two kinds of doped organic/inorganic hybrid nonlinear optical (NLO) materials containing NHA and DO3 were synthesized by Sol-Gel process. The preparation and properties of two NLO materials were studied and characterized by FTIR, 1H-NMR, UV-VIS, SEM, DSC and SHG measurements. The results show that the maximum doping amounts of NHA and DO3 in two doped hybrid NLO materials are 7.2(wt)% and 11.3(wt)% respectively, and the corresponding second-order NLO coefficients (d33 values) are 2.91×10 8esu and 6.14×10 8esu. Two doped NLO materials have relatively good RT stability, after 90 days at RT the d33 values can maintain about 85% of their initial values, but after 10h at 100℃ can only maintain about 50% of their initial values. In this report, the reasons for high-temperature instability of doped materials were discussed, and the possible improvements were also suggested. 展开更多
关键词 Sol-Gel technology DOPING Organic/inorganic hybrid nonlinear optical materials Second-order NLO coefficients
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Relationships between femoral strength evaluated by nonlinear finite element analysis and BMD,material distribution and geometric morphology
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作者 He Gong1,Linwei Lv1,Rui Zhang1,Dong Zhu3,Ming Zhang2(1.Department of Engineering Mechanics,Jilin University,Changchun 130025,P.R.China 2.Department of Health Technology and Informatics,The Hong Kong Polytechnic University,Hong Kong,China 3.Department of Orthopedic Surgery,No.1 Hospital,Jilin University,Changchun 130021,China) 《医用生物力学》 EI CAS CSCD 2009年第S1期66-66,共1页
Precisely quantifying the strength of the proximal femur and accurately assessing hip fracture risk would enable those at high risk to be identified so that preventive interventions could be taken.Development of bette... Precisely quantifying the strength of the proximal femur and accurately assessing hip fracture risk would enable those at high risk to be identified so that preventive interventions could be taken.Development of better measures of femoral strength using the clinically 展开更多
关键词 BMD Relationships between femoral strength evaluated by nonlinear finite element analysis and BMD material distribution and geometric morphology FEA
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SYNTHESIS AND CHARAOTERIZATION OF NOVEL THERMOTROPIO LIQUID ORYSTALLINE POLYESTERS BEARING NONLINEAR OPTICAL AZOBENZENE SIDE GROUP
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作者 张会旗 张莹 +2 位作者 甘湘萍 阴航明 孙经武 《Transactions of Tianjin University》 EI CAS 1999年第1期93-97,共5页
A series of novel thermotropic liquid crystalline polyesters bearing nonlinear optical azobenzene side group were synthesized by high temperature solution polycondensation and their structures,thermal stability, phas... A series of novel thermotropic liquid crystalline polyesters bearing nonlinear optical azobenzene side group were synthesized by high temperature solution polycondensation and their structures,thermal stability, phase transition behavior and crystallinity were characterized by IR,elemental analysis, TG-DTA, polarizing optical microscope (POM) equipped with a hot stage and X-ray diffraction techniques. The results demonstrate that all the synthesized polyesters exhibit nematic liquid crystalline phases and show relatively high glass transition temperatures and good thermal stability. 展开更多
关键词 AZOBENZENE POLYESTER thermotropic liquid crystalline polymer nematic phase nonlinear optical material
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Group Contribution Method Supervised Neural Network for Precise Design of Organic Nonlinear Optical Materials
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作者 Jinming Fan Bowei Yuan +1 位作者 Chao Qian Shaodong Zhou 《Precision Chemistry》 2024年第6期263-272,共10页
To rationalize the design of D-π-A type organic small-molecule nonlinear optical materials,a theory guided machine learning framework is constructed.Such an approach is based on the recognition that the optical prope... To rationalize the design of D-π-A type organic small-molecule nonlinear optical materials,a theory guided machine learning framework is constructed.Such an approach is based on the recognition that the optical property of the molecule is predictable upon accumulating the contribution of each component,which is in line with the concept of group contribution method in thermodynamics.To realize this,a Lewis-mode group contribution method(LGC)has been developed in this work,which is combined with the multistage Bayesian neural network and the evolutionary algorithm to constitute an interactive framework(LGC-msBNN-EA).Thus,different optical properties of molecules are afforded accurately and efficientlyby using only a small data set for training.Moreover,by employing the EA model designed specifically for LGC,structural search is well achievable.The origins of the satisfying performance of the framework are discussed in detail.Considering that such a framework combines chemical principles and data-driven tools,most likely,it will be proven to be rational and efficient to complete mission regarding structure design in related fields. 展开更多
关键词 supervised Bayesian neural network Lewis-type group contribution method nonlinear optical material molecule design evolutionary algorithm
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Low-threshold bistable reflection assisted by oscillating wave interaction with Kerr nonlinear medium
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作者 Yingcong Zhang Wenjuan Cai +5 位作者 Xianping Wang Wen Yuan Cheng Yin Jun Li Haimei Luo Minghuang Sang 《Chinese Physics B》 SCIE EI CAS CSCD 2021年第8期364-369,共6页
Owing to the enormously enhanced oscillating wave,a minute variation of the incident light intensity will give rise to a change in the dielectric constant of the Kerr nonlinear medium and lead to a bistable reflection... Owing to the enormously enhanced oscillating wave,a minute variation of the incident light intensity will give rise to a change in the dielectric constant of the Kerr nonlinear medium and lead to a bistable reflection with an ultra-low threshold intensity,which is closely related to the angle of incidence and the thickness of the Kerr nonlinear medium.The criterion for the existence of optical bistability is derived.Our bistability scheme is simple and not limited to the TM-polarization. 展开更多
关键词 optical bistability WAVEGUIDE nonlinear optics Kerr nonlinear material
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An improved dynamic model for a silicone material beam with large deformation 被引量:8
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作者 Qiping Xu Jinyang Liu 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2018年第4期744-753,共10页
Dynamic modeling for incompressible hyperelastic materials with large deformation is an important issue in biomimetic applications. The previously proposed lower-order fully parameterized absolute nodal coordinate for... Dynamic modeling for incompressible hyperelastic materials with large deformation is an important issue in biomimetic applications. The previously proposed lower-order fully parameterized absolute nodal coordinate formulation(ANCF) beam element employs cubic interpolation in the longitudinal direction and linear interpolation in the transverse direction, whereas it cannot accurately describe the large bending deformation. On this account, a novel modeling method for studying the dynamic behavior of nonlinear materials is proposed in this paper. In this formulation, a higher-order beam element characterized by quadratic interpolation in the transverse directions is used in this investigation. Based on the Yeoh model and volumetric energy penalty function, the nonlinear elastic force matrices are derived within the ANCF framework. The feasibility and availability of the Yeoh model are verified through static experiment of nonlinear incompressible materials. Furthermore,dynamic simulation of a silicone cantilever beam under the gravity force is implemented to validate the superiority of the higher-order beam element. The simulation results obtained based on the Yeoh model by employing three different ANCF beam elements are compared with the result achieved from a commercial finite element package as the reference result. It is found that the results acquired utilizing a higher-order beam element are in good agreement with the reference results,while the results obtained using a lower-order beam element are different from the reference results. In addition, the stiffening problem caused by volumetric locking can be resolved effectively by applying a higher-order beam element. It is concluded that the proposed higher-order beam element formulation has satisfying accuracy in simulating dynamic motion process of the silicone beam. 展开更多
关键词 Dynamic modeling nonlinear incompressible hyperelastic materials Novel modeling method Yeoh model Absolute nodal coordinate formulation
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MoS_2 saturable absorber prepared by chemical vapor deposition method for nonlinear control in Q-switching fiber laser 被引量:3
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作者 Meng-Li Liu Yu-Yi OuYang +3 位作者 Huan-Ran Hou Ming Lei Wen-Jun Liu Zhi-Yi Wei 《Chinese Physics B》 SCIE EI CAS CSCD 2018年第8期7-12,共6页
Due to the remarkable carrier mobility and nonlinear characteristic, MoS2 is considered to be a powerful competitor as an effective optical modulated material in fiber lasers. In this paper, the MoS2 films are prepare... Due to the remarkable carrier mobility and nonlinear characteristic, MoS2 is considered to be a powerful competitor as an effective optical modulated material in fiber lasers. In this paper, the MoS2 films are prepared by the chemical vapor deposition method to guarantee the high quality of the crystal lattice and uniform thickness. The transfer of the films to microfiber and the operation of gold plated films ensure there is no heat-resistant damage and anti-oxidation. The modulation depth of the prepared integrated microfiber-MoS2 saturable absorber is 11.07%. When the microfiber-MoS2 saturable absorber is used as a light modulator in the Q-switching fiber laser, the stable pulse train with a pulse duration of 888 ns at 1530.9 nm is obtained. The ultimate output power and pulse energy of output pulses are 18.8 mW and 88 nJ, respectively. The signal-to-noise ratio up to 60 dB indicates the good stability of the laser. This work demonstrates that the MoS2 saturable absorber prepared by the chemical vapor deposition method can serve as an effective nonlinear control device for the Q-switching fiber laser. 展开更多
关键词 nonlinear optical materials fiber laser Q-SWITCHING
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Synthesis of AgGa_(1-x)In_(x)Se_(2) Polycrystalline Materials 被引量:2
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作者 Liu Juan Zhao Beijun +7 位作者 Zhu Shifu Huang Yi Zhang Jianjun Zhu Weilin Xu Chengfu Chen Baojun Li Ming He Zhiyu 《Journal of Rare Earths》 SCIE EI CAS CSCD 2006年第z1期269-271,共3页
AgGa_(1-x)In_(x)Se_(2)polycrystals were synthesized by the method of mechanical oscillation and temperature oscillation.X-ray diffraction spectra of polycrystal powder are conformable with the JCPDS cards.Lattice cons... AgGa_(1-x)In_(x)Se_(2)polycrystals were synthesized by the method of mechanical oscillation and temperature oscillation.X-ray diffraction spectra of polycrystal powder are conformable with the JCPDS cards.Lattice constants a and c calculated from the XRD were found to obey Vegard's law.The melting point of AgGa_(0.8)In_(0.2)Se_(2)obtained by means of differential scanning calorimetry(DSC)is 796.53℃.The DSC curve also show that there are no other transformation points below the melting point.The results indicate that polycrystalline materials synthesized by the method mentioned above are high-quality and can be used to grow single crystals by the vertical Bridgman technology. 展开更多
关键词 nonlinear optical materials AgGa_(1-x)In_(x)Se_(2) polycrystal synthesis lattice constants
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SYNTHESIS AND OPTICAL PROPERTIES OF A NOVEL ORGANIC/INORGANIC HYBRID NONLINEAR OPTICAL POLYMER VIA SOL-GEL PROCESS 被引量:1
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作者 Hong-xia Xi Zhong Li Zhao-xi Liang The Institute of Chemical Engineering South China University Guangzhou 510640 China The Institute of Polymer Science, Zhongshan University Guangzhou 510275, China 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2001年第4期421-427,共7页
A new organic/inorganic hybrid nonlinear optical (NLO) material was developed by the sol-gel process of an alkoxysilane dye with tetraethoxysilane. A NLO moiety based on 4-nitro-4 ' -hydroxy azobenzene was covalen... A new organic/inorganic hybrid nonlinear optical (NLO) material was developed by the sol-gel process of an alkoxysilane dye with tetraethoxysilane. A NLO moiety based on 4-nitro-4 ' -hydroxy azobenzene was covalently bonded to the triethoxysilane derivative, i.e, gamma -isocyanatopropyl triethoxysilane. The preparation process and properties of the sol-gel derived NLO polymer were studied and characterized by SEM, FTIR,H-1-NMR, UV-Vis, DSC and second harmonic generation (SHG) measurement. The results indicated that the chemical bonding of the chromophores to the inorganic SiO2 networks induces low dipole alignment relaxation and preferable orientational stability. The SHG measurements also showed that the bonded polymer film containing 75 wt% of the akoxysilane dye has a high electro-optic coefficient (r(33)) of 7.1 pm/V at 1.1 mum wavelength, and exhibit good SHG stability, the r(33) values can maintain about 92.7% of its initial value at room temperature for 90 days, and can maintain about 59.3% at 100 degreesC for 300 min. 展开更多
关键词 sol-gel process nonlinear optical material alkoxysilane dye dipole alignment relaxation CHROMOPHORE
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