Identifying Nonpoint Sources of Phosphorus and Nitrogen: A Case Study of Pollution That Enters a Freshwater Wetland (Laguna Cartagena, Puerto Rico)

Point and nonpoint sources of phosphorus (P) and nitrogen (N) can cause reductions in water quality, including eutrophication. Nonpoint pollution represents a special challenge because of dispersed not easily identifiable sources such as the runoff from soil, nutrients, and other chemicals from agricultural fields and residential areas. Laguna Cartagena is a tropical freshwater wetland, situated in southwestern Puerto Rico. It is a eutrophic ecosystem, and its eutrophication is caused by both external nutrient loading and internal, mainly by phosphorus. This wetland has been affected by phosphorus loading from inorganic agricultural fertilizer in this historically oligotrophic wetland system until the end of subsidized fertilizer use and sugar cane cultivation in the late 1990s. This study identifies: 1) nonpoint sources of phosphorus (SRP, Soluble Reactive Phosphorus and TP, Total Phosphorus) and nitrogen (nitrate, nitrite, and ammonia) that enter Laguna Cartagena;and 2) the role of precipitation events on the contributions of phosphorus and nitrogen loading to ecosystems. Herein we assess water samples from five channelized external sources of P and N that enter Laguna Cartagena at two-week intervals from October 2013 through November 2014. Rainfall data were obtained weekly from a rain gauge. Standard methods were used for all chemical analyses. Results showed that the channelized waterways that carry water to the lagoon can be classified as hypereutrophic (>100 μg/L) for TP concentrations and oligotrophic (<200 μg/L) for nitrogen concentrations. Currently agriculture (rice and cattle) is the predominant land use at the nearby University of Puerto Rico (UPR) Lajas Agricultural Experiment Substation, the predominant nonpoint source of nutrient pollution (SRP, TP and ammonia) in the principal channelized water sources to the lagoon. Current nutrient loads are likely derived from fertilizers applied to the Substation’s rice fields, and a high density livestock. The second important cause of external surface water degradation (SRP, TP and ammonia) is the discharge from rural households in the drainage basin that discharge greywater directly to the environment, as indicated by the results from Cerro Alto hills immediately to the north of the lagoon. Precipitation also was associated with SRP, TP and ammonia loads.

Assessment of Point and Nonpoint Sources Pollution in Songhua River Basin,Northeast China by Using Revised Water Quality Model

Individual participation of pollutants in the pollution load should be estimated even if roughly for the appropriate environmental management of a river basin.It is difficult to identify the sources and to quantify the load, especially in modeling nonpoint source.In this study a revised model was established by integrating point and nonpoint sources into one-dimensional Streeter-Phelps(S-P) model on the basis of real-time hydrologic data and surface water quality monitoring data in the Jilin Reach of the Songhua River Basin.Chemical oxygen demand(COD) and ammonia nitrogen(NH 3-N) loads were estimated.Results showed that COD loads of point source and nonpoint source were 134 958 t/yr and 86 209 t/yr, accounting for 61.02% and 38.98% of total loads, respectively.NH 3-N loads of point source and nonpoint source were 16 739 t/yr and 14 272 t/yr, accounting for 53.98% and 46.02%, respectively.Point source pollution was stronger than nonpoint source pollution in the study area at present.The water quality of upstream was better than that of downstream of the rivers and cities.It is indispensable to treat industrial wastewater and municipal sewage out of point sources, to adopt the best management practices to control diffuse pollutants from agricultural land and urban surface runoff in improving water quality of the Songhua River Basin.The revised S-P model can be successfully used to identify pollution source and quantify point source and nonpoint source loads by calibrating and validating.

Estimation of ammonia nitrogen load from nonpoint sources in the Xitiao River catchment, China

Ammonia nitrogen (NH4+-N) is one of the three main forms of total nitrogen (TN). Most studies have estimated the load of TN from nonpoint sources instead of one specific form. The relationship between land use and concentrations of NH4+-N in runoff was analyzed using the hydraulic analysis functions of a Geographic Information Systems (GIS), and the annual loads of NH4+-N in the Xitiao River catchment were estimated according to model results. The results suggested that the calculated annual loads of NH4+-N...

Calculation of Intercepted Volume of Sewer Overflows: a Model for Control of Nonpoint Pollution Sources in Urban Areas

The authors discovered large differences in the characteristics of overflows by the calculation of 1） intercepting volume of overflows for sewer systems using SWMM model which takes into consideration the runoff and pollutants from rainfalls and 2） the intercepted volume in the total flow at an investigation site. The intercepting rate at the investigation point of CSOs showed higher values than the SSDs. Based on the modeling of the receiving water quality after calculating the intercepting amount of overflows by considering the characteristics of outflows for a proper management of the overflow of sewer systems with rainfalls, it is clear that the BOD decreased by 82.9%-94.0% for the discharge after intercepting a specific amount of flows compared to the discharge from unprocessed overflows.

Reviews on Agricultural Nonpoint Source Pollution Monitoring Techniques and Methods

Farmland nutrient loss has become one of the main reason causing agri- cultural nonpoint source pollution and water nitrogen, phosphorus eutrophication. Agricultural nonpoint source pollution monitoring techniques and methods are very important in agricultural nonpoint source pollution control. This paper reviews the various monitoring techniques of agricultural non-point source pollution, including runoff pollutant monitoring, leaching pollutant monitoring and on-line monitoring. The runoff pollutant monitoring methods are mainly included artificial simulation of rain- fall runoff method, flow meter method, weir method and volumetric method. The leaching pollutant monitoring methods are mainly included leaching plate method, leaching gutter method, leakage pooling method, pumping filter pipe method and simulating soil column method. Although online monitoring of farmland nutrient loss still exists some technical bottlenecks and economic limitations, it is the future di- rection of development.

Analysis on Strategic Future of Application of Agricultural Ecological Source in Control on Agricultural Nonpoint Source Pollution in Xi River Area in Guangxi

Non-point source pollution has become a hot issue on aquatic ecological environment at home and abroad. The research analyzed the challenges confronted by Xi River and proposed to construct agricultural ecological source in middle and upper reaches of the Xi River from the perspectives of scientific layout, legal construction, routine monitoring, technology integration, and coordination system in order to promote sustainable development of eco-environment in Xi River.

Progress in the research on aquatic environmental nonpoint source pollution in China

In this paper, the authors reviewed the development process of China's research on aquatic environmental nonpoint pollution, and the situation of nonpoint source pollution in east China was also analyzed.

Study on Management and Control of Nonpoint Source Pollution from Urban Surface Runoff

Urbanization is the dominant form of land-use change in terms of impacts on water quality, hydrology, physical proper- ties of watersheds and their nonpoint source (NPS) pollution po- tential at present. Urbanization has changed the source, process and sink of urban NPS pollution, especially raised the pollution load of urban runoff NPS in receiving water. Urban runoff pollu- tion is a hot spot of research on NPS. This paper analyzed type, source and harm of the NPS pollutants of urban runoff and its influence on the receiving water. Through estimating NPS pollu- tion load of urban runoff and summarizing the law and character- istics of urban runoff NPS systemically, study on management and control of urban runoff NPS pollution was focused on the applica- tion of BMPs (best management practices). It is a fresh method- ology that management and control on NPS pollution from urban surface runoff was analyzed by methods of landscape ecology, environmental economics and environmental management. The paper provided a scientific reference for mitigating urban water environment pressure and an effective method for management and control of NPS pollution from urban surface runoff..

ECONOMIC APPROACH FOR CONTROL AGRICULTURAL NONPOINT SOURCE POLLUTION IN CHINA

This paper mainly discusses the feasibility to establish economic policy systems for control and management of agricultural nonpoint source pollution in China. The current situation of serious agricultural nonpoint source pollution in China is described firstly. Based on the environmental policy and economics theories, the system of economic policies for control and management of agricultural nonpoint source pollution is designed in this paper. This system includes the policy objective, the designing principle and the methods. The key issues include pollution charge, inputs tax for restriction, subsides for induction and incentive, effluent trading for least cost reduction. The emphases are optimized on inputs tax and agricultural chemical tax permit under complete information, as well as sub-optimized inputs tax under incomplete information, subsides for farm due to positive and negative externality. The functions and suitability of the policies are also analyzed in the paper. According to the field experiment results and other relating economic data in watershed of the Chaohe River, Beijing, some economic approaches to reducing agricultural nonpoint source pollution are proposed. The main idea is to encourage and support the farmers to improve their farming way, and to implement the policy of castigating charge simultaneously. The feasibility of the policies are analyzed with consideration of economy, technology and institution. It is concluded that the economic policies are necessary and feasible.

Study on Control Scheme for Nonpoint Source Pollution in Dahe Reservoir Water Source Protection Area of Dianchi Lake Basin

[ Objective] The research aimed to study control scheme for nonpoint source pollution in Dahe Reservoir water source protection area of Dianchi Lake basin.[ Method] On the basis of the SPOT5 satellite remote sensing imagery in 2010 and field investigation of GPS record, ecological design for nonpoint source pollution control in Dahe Reservoir water source protection area of Dianchi Lake basin was conducted. Then, the effects of optimization measures were evaluated by the reductions of N and P outputs on different land-use types. E Resultl Control functions of the water source protection area on soil erosion and the emissions of N, P and other pollutants would be promoted after optimization. The optimization meas- ures had a significant effect for prevention and control of the non-point source pollution in the water source protection area. [ Conclusion] The re- search provided scientific basis for promoting ecological construction of the small green basin in Dahe Reservoir water source protection area of Di- anchi Lake basin.

A Project Plan for Controlling of Nonpoint Source Pollution in China

Nonpoint source pollution is a major cause of remaining water environmental quality problems in China＇s main water bodies, especially is a potential danger for drinking water resource. But in China, nonpoint source pollution control is still at its early stage, many related programs and policies are absent, researches and practices of controlling NPS pollution are scarce. Projects based on BMPs, which were proved successful in controlling nonpoint source pollution in developed countries, are also increasingly utilized in China＇s nonpoint source pollution control. Designing a successful project includes 9 items such as identifying the water quality problems, stating the water quality problems, defining objectives and goals, obtaining funds, involving the community, cooperating and coordinating among agencies, outlining the critical and sensitive areas and so on.

Spatiotemporal characteristics of cultivated land use eco-efficiency and its influencing factors in China from 2000 to 2020

Improving cultivated land use eco-efficiency(CLUE)can effectively promote agricultural sustainability,particularly in developing countries where CLUE is generally low.This study used provincial-level data from China to evaluate the spatiotemporal evolution of CLUE from 2000 to 2020 and identified the influencing factors of CLUE by using a panel Tobit model.In addition,given the undesirable outputs of agricultural production,we incorporated carbon emissions and nonpoint source pollution into the global benchmark-undesirable output-super efficiency-slacks-based measure(GB-US-SBM)model,which combines global benchmark technology,undesirable output,super efficiency,and slacks-based measure.The results indicated that there was an upward trend in CLUE in China from 2000 to 2020,with an increase rate of 2.62%.The temporal evolution of CLUE in China could be classified into three distinct stages:a period of fluctuating decrease(2000-2007),a phase of gradual increase(2008-2014),and a period of rapid growth(2015-2020).The major grain-producing areas(MPAs)had a lower CLUE than their counterparts,namely,non-major grain-production areas(non-MPAs).The spatial agglomeration effect followed a northeast-southwest strip distribution;and the movement path of barycentre revealed a"P"shape,with Luoyang City,Henan Province,as the centre.In terms of influencing factors of CLUE,investment in science and technology played the most vital role in improving CLUE,while irrigation index had the most negative effect.It should be noted that these two influencing factors had different impacts on MPAs and non-MPAs.Therefore,relevant departments should formulate policies to enhance the level of science and technology,improve irrigation condition,and promote sustainable utilization of cultivated land.

Phosphorus removal by the multipond system sediments receiving agricultural drainage in a headstream watershed

Wetland systems in headstream watersheds are important to control the nonpoint source pollutant phosphorus. Experiments were conducted using intact sediment-water columns obtained from the multipond system in Liuchahe watershed of Chaohu Lake to determine its capacity to retain P. It was found that pond sediments had strong P retention ability. For the Hill pond, Village pond and Rice pond, their retention coefficient(A) were 288.3, 279.2 and 260.8 L/m2, respectively. The equilibrium P concentration(EPC_w) were 0.016, 0.028 and 0.018 mg/L, respectively. The Hill pond indicated the highest P retention ability. P retained in the pond sediments indicated high stable degree. P removal from the overlying water column into the pond sediments followed a first-order kinetic model. Under the experimental hydrological conditions, the retention time had a positive correlation with the P loading. The multipond system could provide enough retention time to retain P in drainage runoffs. At the P levels evaluated, the sediments of the multipond system are effective sinks to retain P from nonpoint source runoffs.

Phosphorus sorption capacities in a headstream landscape—The pond chain structure

Understanding phosphorus sorption phenomena in different wetland sediments is important in controlling the P output in headstream watersheds. The pond chain structure （PCS） is widespread in the headstream agricultural watersheds in the southeast of China. Phosphorus sorption characteristics were determined for pond surface sediments （0-12 cm） along a pond chain structure in Liuchahe watershed of Chaohu Lake. Results showed that P sorption capacities （expressed by P sorption index （PSI）） varied both with the landscape position of the ponds and sediment depth. From foothill ponds to riverside ponds the P sorption capacities indicated a significant gradient variability. The higher elevation ponds showed greater sorption capacities, and with the pond elevation decline, P sorption capacities gradually decreased. Some physico-chemical properties, such as pH, oxalate-extractable Fe （Feox）, organic matter （TOC） and Mehlich l-extractable Ca, Mg of pond sediments also indicated significant gradient variability from high elevation ponds to low elevation ponds. Feox was the sediment parameters most highly positively correlated with PSI and was the key factor in controlling P sorption capacity in the pond chain structure （r=0.92, p〈0.001）. Long-term hydrologic and sediment inputs can affect the distribution of sediment constituents and further affect the P sorption capacity. Making the best of the spatial difference of sorption capacities of ponds in watersheds to control nonpoint source P pollutant is necessary.

URBAN STORMWATER MANGEMENT-AN MS4 SUCCESS STORY FOR WESTERN MICHIGAN UNIVERSITY

Regulation of stormwater runoff is increasing throughout the United States.The Environmental Protection Agency(EPA)and state agencies are beginning to move toward effluent and/or load limits for pollutants in stormwater.Compliance costs for treating urban stormwater runoff,especially in highly-developed areas where retrofits are required,will only continue to increase.

Modeling the effects of constructed wetland on nonpoint source pollution control and reservoir water quality improvement

This article describes the integrated modeling approach for planning the size and the operation of constructed wetlands for maximizing retention of nonpoint source pollutant loads and reservoir water-quality improvement at a catchment scale. The experimental field-scale wetland systems （four sets, 0.88 ha each） have been in operation since 2002, where water depth was maintained at 30-50 cm and hydraulic loading rate was at 6.3-18.8 cm/day. The wetland system was found to be adequate for treating polluted stream water with stable removal efficiency even during the winter. The integrated modeling system （modified-BASINS） was applied to the Seokmoon estuarine reservoir watershed and calibrated with monitoring data from constructed wetland, stream, and reservoir. The calibrated integrated modeling system estimated that constructing wetlands on 0.5% （about 114 ha） of the watershed area at the mouth of reservoir could reduce 11.61% and 13.49% of total external nitrogen and phosphorus loads, respectively. It also might improve the nitrogen and phosphorus concentration of the reservoir by 9.69% and 16.48%, respectively. The study suggested that about 0.1%-1.0% of the watershed area should be allocated for constructed wetland to meet specified water-quality standards for the estuarine reservoir at the polder area where land use planning is relatively less complicated.

Impact of Agricultural Labor Transfer on Agricultural Nonpoint Source Pollution: A Case Study of Jiangxi, China

A large proportion of the rural labor force in China will continue to transfer to non-agricultural sectors in the near future, which will inevitably lead to the transformation of the agricultural production mode and the structure of the farmers’ livelihood. The Chinese government is making great efforts to govern agricultural nonpoint source pollution(ANSP), and farmers’ environmental behavior is a key factor that must be considered in the formulation of agricultural environmental policies. Based on a set of micro survey data on farmers in the study area and econometric methods, this study investigates the impact of agricultural labor transfer on ANSP by considering the substitution effect of agricultural factors and the effect of agricultural economies of scale. The results show that the increase of the agricultural labor force will not be conducive to reducing ANSP, while the income increase brought by agricultural labor transfer will improve the input structure of agricultural factors and have a positive impact on ANSP reduction. Government departments should provide subsidies or incentive measures to help agricultural social service organizations to expand their coverage and increase the frequency of socialized agricultural services, in order to guide farmers in the use of environment-friendly agricultural technology to reduce the ANSP caused by agricultural factors at the source. Furthermore, it is necessary to facilitate the development of small-sized agricultural machinery suitable for small-area land cultivation.

Predicting the impacts of climate change on nonpoint source pollutant loads from agricultural small watershed using artificial neural network

This study described the development and validation of an artificial neural network （ANN） for the purpose of analyzing the effects of climate change on nonpoint source （NPS） pollutant loads from agricultural small watershed. The runoff discharge was estimated using ANN algorithm. The performance of ANN model was examined using observed data from study watershed. The simulation results agreed well with observed values during calibration and validation periods. NPS pollutant loads were calculated from load-discharge relationship driven by long-term monitoring data. LARS-WG （Long Ashton Research Station-Weather Generator） model was used to generate rainfall data. The calibrated ANN model and load-discharge relationship with the generated data from LARS-WG were applied to analyze the effects of climate change on NPS pollutant loads from the agricultural small watershed. The results showed that the ANN model provided valuable approach in estimating future runoff discharge, and the NPS pollutant loads.

Nanomaterials for environmental burden reduction,waste treatment,and nonpoint source pollution control:a review

Nanomaterials are applicable in the areas of reduction of environmental burden,reduction/treatment of industrial and agricultural wastes,and nonpoint source(NPS)pollution control.First,environmental burden reduction involves green process and engineering,emissions control,desulfurization/denitrification of nonrenewable energy sources,and improvement of agriculture and food systems.Second,reduction/treatment of industrial and agricultural wastes involves converting wastes into products,groundwater remediation,adsorption,delaying photocatalysis,and nanomembranes.Third,NPS pollution control involves controlling water pollution.Nanomaterials alter physical properties on a nanoscale due to their high specific surface area to volume ratio.They are used as catalysts,adsorbents,membranes,and additives to increase activity and capability due to their high specific surface areas and nano-sized effects.Thus,nanomaterials are more effective at treating environmental wastes because they reduce the amount of material needed.

Characteristics of nonpoint source pollution load from crop farming in the context of livelihood diversification

Based on objective data collected from interviews in typical villages of the Three Gorges Reservoir Area, the present study devised three livelihood scenarios related to rural transformation development： agriculturally dominant livelihood, multiple-type livelihood and non-agriculturally dominant livelihood. Moreover, the present study reports the trend characteristics of nonpoint source pollution load of crop farming in relation to the transformation of dominant livelihood types, and discussed the primary factors which affect livelihood type transformations. Results indicated the following：（1） The current farmland pattern shows a trend of diversification as self-cultivation, cropland transfer and fallow in the sample region. Dynamic characteristics of cultivated land present a special feature that is more ＂transfer-into＂ than ＂transfer-out＂. Various scales of planting are represented among the various households, according to the following decreasing order： half-labor household ＆gt; non-labor household ＆gt; adequate labor household.（2） The highest pollution loading produced by crop farming occurs in half-labor households while the lowest occurs in non-labor households. With increasing labor, the pollution load per unit area tends to first increase and then decrease within families with enough labor.（3） As the type of livelihood transitions from agriculturally dominant to non-agriculturally dominant, the maximum reduction of total pollution loading produced by the agricultural industry can reach 72.01%. Compared to agriculturally dominant livelihoods, multiple-type livelihoods produce a pollution load reduction yield of 19.61%-29.85%, and non-agriculturally dominant livelihoods reduce the pollution load yield by 35.20%-72.01%. However, the rate of reduction of total nitrogen is not the same as total phosphorus.（4） The non-agricultural characteristics of labor allocation and income promote the transformation from dominant livelihood types to non-agricultural livelihoods, while potential revenue conversion follows a similar trend. In addition, different household types do not display identical conversion rates, according to the following decreasing order： enough labor household ＆gt; half-labor household ＆gt; non-labor household.（5） During rapid urbanization and the building of new industrial systems, the livelihood types of rural households have been further transformed to off-farm household types in the mountainous region; this process will lead to the further reduction of pollution load generated by planting and agriculture. Hence, significant decreases in the planting pollution load necessitate the development of control measures to enhance transformations from agricultural to off-farm livelihoods.