陕西西沟钼矿床辉钼矿Re-Os年代学和同位素地球化学特征及其地质意义

西沟钼矿床是东秦岭黄龙铺地区近些年新发现和勘查的碳酸岩脉型钼矿床。钼矿体主要赋存于新太古界太华群变质岩内的石英方解石碳酸岩脉中,呈脉状、似层状或透镜状产出。辉钼矿主要呈浸染状、薄膜状、团块状分布于石英方解石碳酸岩脉中,成矿有关的围岩蚀变有钾长石化、硅化、黄铁矿化、萤石化、硬石膏化等。为查明西沟钼矿床的成矿时代、成矿物质来源、成矿机制、确定矿床类型,文章开展了辉钼矿Re-Os同位素测年,同位素地球化学分析。6件辉钼矿样品Re-Os同位素测年结果,模式年龄为(222.3±3.4)Ma^(226.6±3.7)Ma;加权平均年龄为(225.1±1.4)Ma;等时线年龄为(224.6±9.1)Ma,表明该矿床形成于晚三叠世。硫化物和硫酸盐的S同位素组成、重晶石和方解石Sr-Nd同位素组成及方解石C-O同位素组成均指示:西沟钼矿的成矿物质可能主要来源于地幔。根据其与华北陆块南缘其他碳酸岩型钼矿床地质特征、成矿时代和成矿物质来源等对比,确定西沟钼矿床属碳酸岩型脉状矿床。成矿作用发生于扬子板块与华北板块碰撞造山的后碰撞伸展环境,由于软流圈物质上涌诱发富集岩石圈地幔发生低程度部分熔融,所形成的碳酸质流体携带钼等成矿物质上升,在NW-NWW向深断裂带沉淀富集成矿。

Petrogenesis of mafic enclaves from the north Taihang Yanshanian intermediate to felsic plutons: Evidence from petrological, geochemical, and zircon Hf-O isotopic data

We report the zircon Hf-O isotopic data for mafic enclaves from the Taihang Yanshanian intermediate to felsic plutons, and use them, along with the petrological, whole-rock chemical and Nd-Sr isotopic data, to reveal the petrogenesis of mafic enclaves. Mafic enclaves show magmatic textures and are finer-grained than host rocks. In places they are highly elongated due to stretching within the partially crystallized, convective felsic magma, but show no solid-state deformation. These data suggest that mafic enclaves and host rocks were co-existing, but compositionally distinct magmas. The mafic enclaves contain abundant hydrous minerals such as hornblende and biotite, with pyroxene relict being surrounded by hornblende reaction rim. Plagioclase xenocrysts from mafic enclaves show a complicated compositional and textural disequilibrium. Comparison between mafic enclaves and the immediate host rocks suggests that the two rock units are compositionally correlated. The εNd values of mafic enclaves are generally higher than the host rocks, though the Sr isotopic ratios of the two rock units are indistinguishable. Zircons from a single enclave sample show a significant variation in Hf isotopic compositions, with εHf = -10―-22, suggesting an origin through magma mixing between mafic and felsic magmas. This is supported by the relatively large variation of zircon O isotopic ratios (δ 18O = 5.5‰- 7.8‰) of the mafic enclaves. The petrogenesis of mafic enclaves could be described as below. Evolved basaltic magma (via fractionation of olivine and pyroxene) first mixed with crustally derived granitic melts in depths, forming a hybrid magma; then the hybrid magma broke up into discrete lumps upon entering the above felsic magma. Subsequently, the enclave-forming magma experienced a double mechanical transfer of plagioclase, and inward chemical transfer of fluid and Na, P, Y, Nb and Pb at the contacts with host felsic magmas.

天山托木尔峰花岗质岩石的同位素地球化学特征

分析了西天山托木尔峰地区花岗质岩石和基底岩石的稀土元素 ,微量元素以及 O、 Pb、 Sr、 Nd同位素组成。本区北部伊犁地块基底岩石的 Nd同位素模式年龄约为 1.9Ga,南部南天山褶皱带的约为 2 .2 Ga。高的 Sr同位素初始比值(87Sr/ 86 Sr(T)约为 0 .70 6到 0 .733)表明本区花岗质岩石主要为地壳熔融产物。 O、Pb、Sr、Nd同位素组成指示位于伊犁地块和南天山褶皱带的花岗岩源区岩石的 Nd模式年龄都相当于伊犁地壳 ,但源区性质不同 ,前者源区δ1 8O低 ,μ值低 ,Th/ U比低 ,后者相反。于 2 90 Ma前后形成的岩体 ,无论产出于伊犁地块或南天山褶皱带 ,其 Nd模式年龄均很低 (1.4～ 1.5 Ga) ,指示一次幔源物质加入事件 。

羌塘盆地那底岗日地区中侏罗世碳酸盐岩碳、氧、锶同位素与古海洋沉积环境

本文首次利用碳酸盐岩 C,O,Sr稳定同位素探讨了羌塘盆地那底岗日地区中侏罗世海洋沉积环境的演变。测试结果表明 ,该区中侏罗世碳酸盐岩δ1 3C,δ1 8O及 N(87Sr) / N(86 Sr)值分别为 - 3.2 5× 10 - 3～ +3.30 4× 10 - 3,- 11.419× 10 - 3～ - 3.2 8× 10 - 3及 0 .70 70 2～ 0 .70 86 2 ,并伴生了多次升降变化。分析认为 ,δ1 3C值主要受沉积环境的水介质盐度、氧化 -还原条件、生物发育程度及有机质埋藏速率的影响 ;δ1 8O值主要与沉积环境的盐度、温度、海平面升降及沉积期后成岩作用等因素有关 ;N(87Sr) / N(86 Sr)值则由三种不同锶源在海水中的组成比例所决定。因此 ,C,O,Sr同位素组成及演化可以直接或间接地反映古环境的变迁 ,从而为那底岗日地区中侏罗世古海洋沉积环境的分析提供了可靠的地质地球化学依据。

西琛一井礁序列锶同位素组分变化

本文首次报道了西沙群岛西琛一井从中新世晚期至更新世末期礁序列的锶同位素组分变化特征、讨论了它与成岩作用、古海洋事件的关系及其意义。