优化氮肥施用和秸秆还田技术为途径的农业管理措施被认为是提升农业可持续性的有效手段,然而当前关于氮肥和秸秆还田对小麦产量和N_(2)O排放影响的研究仍十分有限。为此,本研究基于2000—2022年发表的关于长江中下游流域氮肥和秸秆投入...优化氮肥施用和秸秆还田技术为途径的农业管理措施被认为是提升农业可持续性的有效手段,然而当前关于氮肥和秸秆还田对小麦产量和N_(2)O排放影响的研究仍十分有限。为此,本研究基于2000—2022年发表的关于长江中下游流域氮肥和秸秆投入下小麦产量和N_(2)O排放变化的文献,运用随机森林建模,定量分析氮肥和秸秆还田对小麦产量和N_(2)O排放的影响,并结合情景设置进行了特定地点的小麦产量和N_(2)O排放模拟,同时评估了碳排放强度(CEE)和净生态系统经济效益(NEEB)。结果表明,建立的区域尺度小麦产量与N_(2)O排放对氮秸互作响应的随机森林模型,验证结果R^(2)分别为0.66和0.65,RMSE分别为0.70和1.11。结果表明施氮量和土壤有机质是影响小麦产量和N_(2)O排放的重要因素。综合来看,达到最大产量所需的氮肥量为208~212 kg hm^(-2),达到最小CEE所需的氮肥量为113~130 kg hm^(-2),达到最高的NEEB所需的氮肥量为202~205 kg hm^(-2),其中在6.75 t hm^(-2)的秸秆投入下施用202 kg hm^(-2)的氮肥可以获得最高的生态收益1.37万元。优化氮肥和秸秆投入具备减少作物碳排放强度并获得最大净生态环境效益的潜力。展开更多
Salt lake brine is a complex salt-water system under natural environment.Although many models can express the thermodynamic properties and phase equilibrium of electrolyte aqueous solution,the multi-temperature charac...Salt lake brine is a complex salt-water system under natural environment.Although many models can express the thermodynamic properties and phase equilibrium of electrolyte aqueous solution,the multi-temperature characteristics and predictability are still the goals of model development.In this study,a comprehensive thermodynamic model system is re-established based on the eNRTL model and some improvements:(1) new expression of long-range electrostatic term with symmetrical reference state is proposed to handle the electrolyte solution covering entire concentration range;(2) the temperature dependence of the binary interaction parameters is formulated with a Gibbs Helmholtz expression containing three temperature coefficients,the liquid parameters,which associated with Gibbs energy,enthalpy,and heat capacity contribution;and(3) liquid parameters and solid species data are regressed from properties and solubility data at full temperature range.Together the activity coefficient model,property models and parameters of liquid and solid offer a comprehensive thermodynamic model system for the typical bittern of MgCl2-CaCl2-H2 O binary and ternary systems,and it shows excellent agreement with the literature data for the ternary and binary systems.The successful prediction of complete phase diagram of ternary system shows that the model has the ability to deal with high concentration and high non-idealitv system,and the ability to extrapolate the temperature.展开更多
DNDC, a rainfall-driven and process-oriented model of soil carbon and nitrogenbiogeochemistry, is applied t0 simulate the nitrous oxide emissions from agricultural ecosystem inSoutheast China. We simulated the soil N2...DNDC, a rainfall-driven and process-oriented model of soil carbon and nitrogenbiogeochemistry, is applied t0 simulate the nitrous oxide emissions from agricultural ecosystem inSoutheast China. We simulated the soil N2O emission during a whole rice-wheat rotation cycle(from Nov. 1, 1996 to Oct. 31, 1997) under three different conditions, which are A) no fertilizer, B)both chemical fertilizer and manure and, C) chemical fertiliser only. The processes ofN2O emission were discussed in detail by comparing the model outputs with the results from fieldmeasurement. The comparison shows that the model is good at simulating most of theNzO emission pulses and trends. Although the simulated N2O emission fluxes are generally lessthan the measured ones, the model outputs during the dryland period, especially during the wheatreviving and maturing stages in spring, are much better than those during the paddy field period.Some sensitive experiments were made by simulating the N2O emissions in spring, when there is asmallest gap between the simulated fluxes and the measured ones. Meanwhile, the effects of someimportant regulating factors, such as the rainfall N deposition by rainfall, temperature, tillage, nitrogen fertilizer and manure application on N2O emission during this period were analyzed. Fromthe analysis, we draw a conclusion that soil moisture and fertilization are the most important regulating factors while the N2O emission is sensitive to some other factors, such as temperature, manure, tillage and the wet deposition of atmospheric nitrate.展开更多
In order to numerically simulate daily nitrous oxide （N2O） emission from a rice-winter wheat rotation cropping system, a process-based site model was developed （referred to as IAP-N-GAS） to track the movement and ...In order to numerically simulate daily nitrous oxide （N2O） emission from a rice-winter wheat rotation cropping system, a process-based site model was developed （referred to as IAP-N-GAS） to track the movement and transformation of several forms of nitrogen in the agro-eeosystem, which is affected by climate, soil, crop growth and management practices. The simulation of daily N2O fluxes, along with key daily environmental variables, was validated with three-year observations conducted in East China. The validation demonstrated that the model simulated well daily solar radiation, soil temperature and moisture, and also captured the dynamics and magnitude of accumulated rice aboveground biomass and mineral nitrogen in the soil. The simulated daily N2O emissions over all three years investigated were generally in good agreement with field observations. Particularly well simulated were the peak N2O emissions induced by fertilizations, rainfall events or mid-season drainages. The model simulation also represented closely the inter-annuM variation in N2O emission. These validations imply that the model has the capability to capture the general characteristics of N2O emission from a typical rice-wheat rotation agro-ecosystem. Sensitivity analyses revealed that the simulated N2O emission is most sensitive to the fertilizer application rate and the soil organic matter content, but it is much less sensitive to variations in soil pH and texture, temperature, precipitation and crop residue incorporation rate under local conditions.展开更多
A sub-regular solution model SELF-SReM4 used to evaluate activity of the components in a homogeneous region of a quaternary system has been developed in Shanghai Enhanced Laboratory of Ferrometallurgy.The application ...A sub-regular solution model SELF-SReM4 used to evaluate activity of the components in a homogeneous region of a quaternary system has been developed in Shanghai Enhanced Laboratory of Ferrometallurgy.The application of SELF-SReM4 in C-Mn-Fe-Si system without the SiC formation has been introduced in previous paper.It’s application for molten slag of MnO-SiO2-Al2O3-CaO was introduced in this paper.They provide a basis for the prediction of the metal-slag equilibrium conditions.展开更多
The strain effect on the critical current is one of the most important properties for polycrystalline YBa2 Cu3O7-δ （REBCO, RE： rare earth） films, in which the reversible effect is intrinsic in the range of strain ...The strain effect on the critical current is one of the most important properties for polycrystalline YBa2 Cu3O7-δ （REBCO, RE： rare earth） films, in which the reversible effect is intrinsic in the range of strain 0 and the irreversible strain εirr. By introducing the applied strain, a modified grain boundaries （GBs） in the REBCO film is developed. lattice model combining the strain and misorientation of A good agreement of the calculation on the lattice model with the experimental data shows that the lattice model is able to well describe the reversible effect of axial strain on the critical current of the REBCO film, and provides a good understanding of the mechanism of the reversible effect of the strain. Moreover, the effects of the crystallographic texture of the REBCO film and the residual strain εr on the variation of the critical current with the applied strain are extensively investigated. Furthermore by using the developed lattice model, the irreversible strain εirr of the REBCO film can be theoretically determined by comparing the calculation of the critical current-strain curve with the experimental data.展开更多
【目的】研究施用有机肥对农田土壤固碳及温室气体排放的综合影响,为减缓全球气候变暖提供理论指导。【方法】基于长期定位试验点观测数据,利用验证后的机理过程模型——SPACSYS,结合区域数据库及ArcGIS,模拟2010-2050年华北平原旱地3...【目的】研究施用有机肥对农田土壤固碳及温室气体排放的综合影响,为减缓全球气候变暖提供理论指导。【方法】基于长期定位试验点观测数据,利用验证后的机理过程模型——SPACSYS,结合区域数据库及ArcGIS,模拟2010-2050年华北平原旱地3种施肥情景(等氮量)即单施化肥情景(NPK)、50%化肥配施50%有机肥情景(NPKM(5﹕5))和30%化肥配施70%有机肥情景(NPKM(3﹕7))下,土壤年均固碳速率(SOC_(SR))、土壤N_(2)O年均排放量和年均净全球增温潜势(NGWP)的空间格局。【结果】华北平原旱地SOC_(SR)表现为东部较高、西部较低,较高的地区主要包括江苏省和山东省。相关分析结果表明,SOC_(SR)与初始土壤有机碳含量呈显著负相关,逐步线性回归分析进一步表明,初始土壤有机碳含量、年均温和土壤pH是影响SOC_(SR)的3个重要因子,共解释其变异的24%。土壤N_(2)O年均排放量表现为中部较高、北部和南部较低,较高的地区主要包括山东省部分地区和江苏省。相关分析结果表明,土壤N_(2)O年均排放量与初始土壤有机碳含量呈显著正相关。总体来看,与NPK情景相比,NPKM(5﹕5)和NPKM(3﹕7)两种情景均增加华北平原旱地SOC_(SR)、降低土壤N_(2)O年均排放量,其中SOC_(SR)(233和236 kg C·hm^(-2)·a^(-1))分别增加了79%和82%,土壤N_(2)O年均排放量(15.8和14.4 kg N·hm^(-2)·a^(-1))分别降低了21%和28%,NGWP(6.6和5.9 t CO_(2)-eq·hm^(-2)·a^(-1))分别降低了26%和34%。【结论】长期来看,相比传统的单施化肥模式,化肥配施有机肥有利于华北平原旱地土壤固碳、土壤N_(2)O减排和减缓温室效应。展开更多
文摘优化氮肥施用和秸秆还田技术为途径的农业管理措施被认为是提升农业可持续性的有效手段,然而当前关于氮肥和秸秆还田对小麦产量和N_(2)O排放影响的研究仍十分有限。为此,本研究基于2000—2022年发表的关于长江中下游流域氮肥和秸秆投入下小麦产量和N_(2)O排放变化的文献,运用随机森林建模,定量分析氮肥和秸秆还田对小麦产量和N_(2)O排放的影响,并结合情景设置进行了特定地点的小麦产量和N_(2)O排放模拟,同时评估了碳排放强度(CEE)和净生态系统经济效益(NEEB)。结果表明,建立的区域尺度小麦产量与N_(2)O排放对氮秸互作响应的随机森林模型,验证结果R^(2)分别为0.66和0.65,RMSE分别为0.70和1.11。结果表明施氮量和土壤有机质是影响小麦产量和N_(2)O排放的重要因素。综合来看,达到最大产量所需的氮肥量为208~212 kg hm^(-2),达到最小CEE所需的氮肥量为113~130 kg hm^(-2),达到最高的NEEB所需的氮肥量为202~205 kg hm^(-2),其中在6.75 t hm^(-2)的秸秆投入下施用202 kg hm^(-2)的氮肥可以获得最高的生态收益1.37万元。优化氮肥和秸秆投入具备减少作物碳排放强度并获得最大净生态环境效益的潜力。
基金financial support of the National Natural Science Foundation of China(U1407204,U1707602)the Yangtze Scholars and Innovative Research Team in University of Education of China+1 种基金the Innovative Research Team of Tianjin Municipal Education Commission(TD12-5004)Foundation of Tianjin Key Laboratory of Marine Resources and Chemistry(201602)。
文摘Salt lake brine is a complex salt-water system under natural environment.Although many models can express the thermodynamic properties and phase equilibrium of electrolyte aqueous solution,the multi-temperature characteristics and predictability are still the goals of model development.In this study,a comprehensive thermodynamic model system is re-established based on the eNRTL model and some improvements:(1) new expression of long-range electrostatic term with symmetrical reference state is proposed to handle the electrolyte solution covering entire concentration range;(2) the temperature dependence of the binary interaction parameters is formulated with a Gibbs Helmholtz expression containing three temperature coefficients,the liquid parameters,which associated with Gibbs energy,enthalpy,and heat capacity contribution;and(3) liquid parameters and solid species data are regressed from properties and solubility data at full temperature range.Together the activity coefficient model,property models and parameters of liquid and solid offer a comprehensive thermodynamic model system for the typical bittern of MgCl2-CaCl2-H2 O binary and ternary systems,and it shows excellent agreement with the literature data for the ternary and binary systems.The successful prediction of complete phase diagram of ternary system shows that the model has the ability to deal with high concentration and high non-idealitv system,and the ability to extrapolate the temperature.
文摘DNDC, a rainfall-driven and process-oriented model of soil carbon and nitrogenbiogeochemistry, is applied t0 simulate the nitrous oxide emissions from agricultural ecosystem inSoutheast China. We simulated the soil N2O emission during a whole rice-wheat rotation cycle(from Nov. 1, 1996 to Oct. 31, 1997) under three different conditions, which are A) no fertilizer, B)both chemical fertilizer and manure and, C) chemical fertiliser only. The processes ofN2O emission were discussed in detail by comparing the model outputs with the results from fieldmeasurement. The comparison shows that the model is good at simulating most of theNzO emission pulses and trends. Although the simulated N2O emission fluxes are generally lessthan the measured ones, the model outputs during the dryland period, especially during the wheatreviving and maturing stages in spring, are much better than those during the paddy field period.Some sensitive experiments were made by simulating the N2O emissions in spring, when there is asmallest gap between the simulated fluxes and the measured ones. Meanwhile, the effects of someimportant regulating factors, such as the rainfall N deposition by rainfall, temperature, tillage, nitrogen fertilizer and manure application on N2O emission during this period were analyzed. Fromthe analysis, we draw a conclusion that soil moisture and fertilization are the most important regulating factors while the N2O emission is sensitive to some other factors, such as temperature, manure, tillage and the wet deposition of atmospheric nitrate.
基金supported by the Chinese Academy of Sciences (KZCX2-YW-204, KSCX3-SW-440, KZCX1-SW-01)the National Natural Science Foundation of China (40425010, 40331014)+1 种基金the European Union (NitroEurope IP 017841)the Helmholtz Society via the Sino-German Joint Laboratory project ENTRANCE
文摘In order to numerically simulate daily nitrous oxide （N2O） emission from a rice-winter wheat rotation cropping system, a process-based site model was developed （referred to as IAP-N-GAS） to track the movement and transformation of several forms of nitrogen in the agro-eeosystem, which is affected by climate, soil, crop growth and management practices. The simulation of daily N2O fluxes, along with key daily environmental variables, was validated with three-year observations conducted in East China. The validation demonstrated that the model simulated well daily solar radiation, soil temperature and moisture, and also captured the dynamics and magnitude of accumulated rice aboveground biomass and mineral nitrogen in the soil. The simulated daily N2O emissions over all three years investigated were generally in good agreement with field observations. Particularly well simulated were the peak N2O emissions induced by fertilizations, rainfall events or mid-season drainages. The model simulation also represented closely the inter-annuM variation in N2O emission. These validations imply that the model has the capability to capture the general characteristics of N2O emission from a typical rice-wheat rotation agro-ecosystem. Sensitivity analyses revealed that the simulated N2O emission is most sensitive to the fertilizer application rate and the soil organic matter content, but it is much less sensitive to variations in soil pH and texture, temperature, precipitation and crop residue incorporation rate under local conditions.
文摘A sub-regular solution model SELF-SReM4 used to evaluate activity of the components in a homogeneous region of a quaternary system has been developed in Shanghai Enhanced Laboratory of Ferrometallurgy.The application of SELF-SReM4 in C-Mn-Fe-Si system without the SiC formation has been introduced in previous paper.It’s application for molten slag of MnO-SiO2-Al2O3-CaO was introduced in this paper.They provide a basis for the prediction of the metal-slag equilibrium conditions.
基金Supported by the National Natural Science Foundation of China under Grant No 11372096the Research Fund for the Doctoral Program of Higher Education of China
文摘The strain effect on the critical current is one of the most important properties for polycrystalline YBa2 Cu3O7-δ （REBCO, RE： rare earth） films, in which the reversible effect is intrinsic in the range of strain 0 and the irreversible strain εirr. By introducing the applied strain, a modified grain boundaries （GBs） in the REBCO film is developed. lattice model combining the strain and misorientation of A good agreement of the calculation on the lattice model with the experimental data shows that the lattice model is able to well describe the reversible effect of axial strain on the critical current of the REBCO film, and provides a good understanding of the mechanism of the reversible effect of the strain. Moreover, the effects of the crystallographic texture of the REBCO film and the residual strain εr on the variation of the critical current with the applied strain are extensively investigated. Furthermore by using the developed lattice model, the irreversible strain εirr of the REBCO film can be theoretically determined by comparing the calculation of the critical current-strain curve with the experimental data.
文摘【目的】研究施用有机肥对农田土壤固碳及温室气体排放的综合影响,为减缓全球气候变暖提供理论指导。【方法】基于长期定位试验点观测数据,利用验证后的机理过程模型——SPACSYS,结合区域数据库及ArcGIS,模拟2010-2050年华北平原旱地3种施肥情景(等氮量)即单施化肥情景(NPK)、50%化肥配施50%有机肥情景(NPKM(5﹕5))和30%化肥配施70%有机肥情景(NPKM(3﹕7))下,土壤年均固碳速率(SOC_(SR))、土壤N_(2)O年均排放量和年均净全球增温潜势(NGWP)的空间格局。【结果】华北平原旱地SOC_(SR)表现为东部较高、西部较低,较高的地区主要包括江苏省和山东省。相关分析结果表明,SOC_(SR)与初始土壤有机碳含量呈显著负相关,逐步线性回归分析进一步表明,初始土壤有机碳含量、年均温和土壤pH是影响SOC_(SR)的3个重要因子,共解释其变异的24%。土壤N_(2)O年均排放量表现为中部较高、北部和南部较低,较高的地区主要包括山东省部分地区和江苏省。相关分析结果表明,土壤N_(2)O年均排放量与初始土壤有机碳含量呈显著正相关。总体来看,与NPK情景相比,NPKM(5﹕5)和NPKM(3﹕7)两种情景均增加华北平原旱地SOC_(SR)、降低土壤N_(2)O年均排放量,其中SOC_(SR)(233和236 kg C·hm^(-2)·a^(-1))分别增加了79%和82%,土壤N_(2)O年均排放量(15.8和14.4 kg N·hm^(-2)·a^(-1))分别降低了21%和28%,NGWP(6.6和5.9 t CO_(2)-eq·hm^(-2)·a^(-1))分别降低了26%和34%。【结论】长期来看,相比传统的单施化肥模式,化肥配施有机肥有利于华北平原旱地土壤固碳、土壤N_(2)O减排和减缓温室效应。
