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Retrieval of Aerosol Optical Depth from Oceansat-2 OCM 被引量:3
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作者 Udaya Lakshmi Sriperambudur Chandralingam Sonnati +1 位作者 Nagamani Pullaiahgari Venkata Preethi Latha Thalathoti 《Open Journal of Marine Science》 2015年第4期443-454,共12页
Aerosols are the tiny suspended particles in the atmosphere playing a major role in influencing the net radiation budget of the earth. The aerosols also affect cloud microphysics and those with land origin, possibly r... Aerosols are the tiny suspended particles in the atmosphere playing a major role in influencing the net radiation budget of the earth. The aerosols also affect cloud microphysics and those with land origin, possibly reduce the monsoon rainfall. Dynamic and diverse nature of the aerosols varies according to different locations. The aerosols originating due to desert dust, rural atmospheric situations, urban pollutants and marine areas have wide variations and display specific characteristics. Routine monitoring of aerosol events and their subsequent dispersal pattern are important in order to understand their role in climatic process. Hence, it is very important to study the aerosols and their retrieval strategy from the ocean colour remote sensing sensors. The satellite sensors provide platform for making observations covering large area as also their short-term and frequent repetivity. Ocean-colour sensors e.g. CZCS, SeaWiFS, MODIS, POLDAR, Oceansat-1?& 2 OCM have been used to study aerosols, apart from being used to study ocean-colour. Most of the ocean-colour sensors are equipped with a few additional near infrared (NIR) bands (λ?> 700 nm), which are helpful in providing vital information on atmospheric aerosols due to strong absorption by water in NIR wavelengths. The present work is an attempt to study the temporal and spatial variations of Aerosol Optical Depth (AOD) over the Bay of Bengal using Oceansat-2 Ocean Colour Monitor (OCM). 展开更多
关键词 AOD ocm-2 ATMOSPHERIC CORRECTION
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Li-Mn/WO_(3)/TiO_(2)固体酸催化剂的制备及其甲烷氧化偶联催化性能研究 被引量:1
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作者 程飞 杨建 +4 位作者 闫亮 赵军 赵华华 宋焕玲 丑凌军 《分子催化》 CAS CSCD 北大核心 2022年第2期109-117,共9页
Li-Mn/WO_(3)/TiO_(2)催化剂具有良好的低温OCM催化性能,采用浸渍法制备Li-Mn/WO_(3)/TiO_(2)催化剂,并详细考察WO_(3)对催化剂物理化学性质及催化性能的影响.利用X射线衍射(XRD)、CO_(2)程序升温脱附(CO_(2)-TPD)、O_(2)程序升温脱附(O... Li-Mn/WO_(3)/TiO_(2)催化剂具有良好的低温OCM催化性能,采用浸渍法制备Li-Mn/WO_(3)/TiO_(2)催化剂,并详细考察WO_(3)对催化剂物理化学性质及催化性能的影响.利用X射线衍射(XRD)、CO_(2)程序升温脱附(CO_(2)-TPD)、O_(2)程序升温脱附(O_(2)-TPD)、H_(2)程序升温还原(H_(2)-TPR)、拉曼光谱(Raman)和X射线光电子能谱(XPS)等表征技术对催化剂进行了研究,发现WO_(3)的添加提高了C_(2)选择性,并有效抑制了深度氧化.XRD与CO_(2)-TPD结果表明,WO_(3)的添加不仅有利于金红石型TiO_(2)的形成而且能够中和催化剂表面的强碱位,从而抑制了深度氧化反应.O_(2)-TPD和H_(2)-TPR结果表明,WO_(3)的添加降低了晶格氧(O^(2-))移动性,进而提高了反应的C_(2)选择性.此外,WO_(3)的添加促使了低温氧化偶联活性物种MnTiO_(3)的形成并提高了活性物种的分散性,因此提高了催化剂甲烷氧化偶联的反应活性和选择性.所有Li-Mn/x%WO_(3)/TiO_(2)催化剂中,Li-Mn/5%WO_(3)/TiO_(2)催化剂显示出最佳的OCM反应性能.在750℃,CH_(4)∶O_(2)∶N_(2)=10∶4∶5,GHSV=2280 mL·g^(-1)·h^(-1)条件下,最高的C_(2)产物收率可达16.3%. 展开更多
关键词 OCM C_(2)选择性 WO_(3) 强碱位
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La_2O_3-BaO系复氧化物的现场拉曼光谱研究
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作者 陈笃慧 廖远琰 万惠霖 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 1997年第2期133-139,共7页
对于La0.2Ba0.8-xCax(O,CO3)其中x=0.0、0.2、0.4、0.6氧化物在973K及甲烷氧化偶联(OCM)条件下,无Ca2+的样品可用表面BaCO3和(LaO)2CO3的Raman谱及810cm-... 对于La0.2Ba0.8-xCax(O,CO3)其中x=0.0、0.2、0.4、0.6氧化物在973K及甲烷氧化偶联(OCM)条件下,无Ca2+的样品可用表面BaCO3和(LaO)2CO3的Raman谱及810cm-1附近的O2-2特征峰来表征;含Ca2+的样品,则表现了混合碳酸盐(Ca,Ba)CO3的特征,还有位于1135cm-1(w)和810cm-1(w)的O-2、O2-2瞬时态氧物种;973~1053K发现OCM反应活性随温度和Ca2+含量而增加,C2烃选择性也随OCM反应温度增大;1053K时,Ca2+含量的增加,C2烃选择性略有下降,这些结果指出O-2是OCM反应的活性氧物种,它在较高温度下与CH4作用,且具有较好的C2烃选择性和较大的反应活化能。 展开更多
关键词 现场拉曼光谱 金属复氧化物 催化剂 OCM反应
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甲烷氧化偶联制乙烯Na–W–Mn/SiO_(2)催化剂的研究进展
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作者 高欣 宋佳欣 +2 位作者 范晓强 于学华 赵震 《中国科学:化学》 CAS CSCD 北大核心 2024年第2期231-249,共19页
乙烯产量是衡量一个国家石油化工行业水平的重要指标.因此,将甲烷高效转化为乙烯的甲烷氧化偶联(OCM)反应成为催化工业和能源领域的热门话题,甲烷氧化偶联工艺也已成为世界各国的研究热点.然而OCM反应是同时结合了多相反应和均相反应的... 乙烯产量是衡量一个国家石油化工行业水平的重要指标.因此,将甲烷高效转化为乙烯的甲烷氧化偶联(OCM)反应成为催化工业和能源领域的热门话题,甲烷氧化偶联工艺也已成为世界各国的研究热点.然而OCM反应是同时结合了多相反应和均相反应的复杂反应网络,使得OCM反应高效催化剂的开发面临着重大挑战.其中, Na–W–Mn/SiO_(2)体系催化剂是目前综合性能最好的催化剂,但Na–W–Mn/SiO_(2)催化剂组分复杂,反应所需温度高,活性中心仍存在争议.因此本文主要总结讨论了该体系催化剂上OCM反应机理,以及氧物种和酸碱性对OCM反应的影响.并详细介绍了体系中各活性组分在反应中的作用,以及各种原位表征手段在OCM机理研究中的应用.最后对OCM反应在高温原位表征,低温可控OCM反应以及化学链循环反应方向进行了展望. 展开更多
关键词 甲烷 催化剂 OCM 反应机理 Na–W–Mn/SiO_(2)活性位
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Importance of Aerosol Optical Depth in the Atmospheric Correction of Ocean Colour Remote Sensing Data
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作者 Sriperambudur Udaya Laxmi Sonnati Chandralingam +2 位作者 Pullaiahgari Venkata Nagamani Inaganti Veera Ganga Bhavani Yerramsetti Umamaheswara Rao 《Open Journal of Marine Science》 2017年第1期100-108,共9页
Atmospheric aerosols being an important component of the atmosphere play an important role in global and regional climate change. Aerosols can affect air quality, climate change and human health and have a significant... Atmospheric aerosols being an important component of the atmosphere play an important role in global and regional climate change. Aerosols can affect air quality, climate change and human health and have a significant effect on the solar energy budget. To study their quantitative effect is a challenging task due to their high spatial and temporal variability. This parameter represents one of the extinction coefficients of solar radiation and rate of suspended particles in the atmosphere. Ocean Colour Remote Sensing provides information about the four major geophysical parameters like chlorophyll and total suspended sediment concentration, vertical diffuse attenuation co-efficient and the aerosol optical thickness measured at 865 nm. Aerosol optical depth can be expressed as function of wavelength through Angstrom’s equation ?, where “α” and “β” are known as Angstrom parameters. The Angstrom exponent, “α” is related to the size distribution of the aerosol particles and “β” represents the amount of aerosols present in the atmosphere. In this present study, an attempt is made to study the impact of these two parameters by changing values from 0 to 0.05 for “α” and from 0.0 to 0.6 for “β” in SeaDAS processing for estimating the aerosol optical depth. From this study, it is clear that for most of the applications either in the coastal or open ocean waters, alpha value varies from 0.0 to 0.3 over the north Indian Ocean. However, this has been further evaluated by various combinations for retrieving the AOD using OCM-2 data. 展开更多
关键词 AEROSOL Optical Depth SeaDAS NORTH INDIAN OCEAN ocm-2
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甲烷在金属氧化物上催化脱氢的从头计算 被引量:6
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作者 孟辉 周泰锦 +2 位作者 林梦海 赖伍江 万惠霖 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 1998年第5期450-455,共6页
用G94的从头计算方法对甲烷在金属氧化镁及氧化锂表面上不同氧物种O-、O2-2、O-2、O2-催化脱氢进行了理论研究,确定了过渡态的几何构型、集居分布和反应活化能.结果表明,氧物种的催化脱氢的活性顺序为,其中O-2物... 用G94的从头计算方法对甲烷在金属氧化镁及氧化锂表面上不同氧物种O-、O2-2、O-2、O2-催化脱氢进行了理论研究,确定了过渡态的几何构型、集居分布和反应活化能.结果表明,氧物种的催化脱氢的活性顺序为,其中O-2物种由于对甲烷具有较低的氧化能力而可能是OCM活性和高C2选择性的氧物种。另外,还讨论了氧物种对CH4脱氧活性与其电子结构的联系。 展开更多
关键词 甲烷氧化偶联 脱氢 催化剂 氧化镁 氧化锂
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Impact of Cyclone PHAILIN on Chlorophyll-a Concentration and Productivity in the Bay of Bengal
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作者 T. Preethi Latha K. H. Rao +4 位作者 P. V. Nagamani E. Amminedu S. B. Choudhury C. B. S. Dutt V. K. Dadhwal 《International Journal of Geosciences》 2015年第5期473-480,共8页
Ocean colour remote sensing is one of the conventional methods in satellite oceanography used to study the biological response of the upper ocean to the tropical cyclones. This paper aims to study the impact of the Ve... Ocean colour remote sensing is one of the conventional methods in satellite oceanography used to study the biological response of the upper ocean to the tropical cyclones. This paper aims to study the impact of the Very Severe Cyclonic storm PHAILIN, and its consequence on the surface chlorophyll-aconcentration distribution in the Bay of Bengal using Oceansat-2 Ocean Colour Monitor (OCM). The impact of this cyclone on ocean primary productivity has been studied using MODIS-A data. Sea surface temperature (SST) plays an important role in the generation of primary productivity along with the other oceanographic parameters;SST patterns in the Bay of Bengal during the cyclone period were studied. From the analysis, it is observed that the chlorophyll-aconcentration has increased from 1.08 (before) to 7.06 mg/m3 after the cyclone with an SST drop of ~3°C (29.19°C to 26°C). The primary productivity has increased from 410.0506 to 779.9814 mg/C/m2/day after the cyclone. In addition to the above analysis, an attempt has also been made to study the impact of cyclone intensity on the chlorophyll concentration. The study shows that the comparison between cyclone intensity (CI) and chlorophyll concentration shows a positive relationship. 展开更多
关键词 Oceansat-2 OCM CYCLONE CHLOROPHYLL-A Primary PRODUCTIVITY CYCLONE Intensity SST
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