Two novel starburst compounds (star arylamines),4,4′,4″ tris(diphenylamino) triphenylamine (TDATA) and 4,4′,4″ tris[3 methyl (phenyl) amino] triphenylamine (MTDATA),were designed and synthesized as hole transport ...Two novel starburst compounds (star arylamines),4,4′,4″ tris(diphenylamino) triphenylamine (TDATA) and 4,4′,4″ tris[3 methyl (phenyl) amino] triphenylamine (MTDATA),were designed and synthesized as hole transport materials with high glass transition temperature ( t g),good film formation and film stability,excellent hole transporting ability.展开更多
It is generally believed that exciplex is formed at the interface between a acceptor and a donor, it is not a new species, and it has a transit excited state. Based on the concept, we discussed the formation process o...It is generally believed that exciplex is formed at the interface between a acceptor and a donor, it is not a new species, and it has a transit excited state. Based on the concept, we discussed the formation process of exciplex in organic electroluminescent (OEL) device with rareearth complex and considered that exciplex is also formed in the mixinglayer and it′s formation is the result from the interaction of singlet state of ligand and the holetransport material. Therefore, exciplex emission and the central ions emission of rareearth complex is an energy competition process. Therefore, it was resonable to understand that elimination of exciplex emission means enhance of the central ion emission of the rareearth complex through adjusting molar ratio of the two molecules.展开更多
This study aims to establish the occupational exposure limit （OEL） in the air for workplace of warfarin based on the available toxicological studies and field investigations by using questionnaire and air monitoring...This study aims to establish the occupational exposure limit （OEL） in the air for workplace of warfarin based on the available toxicological studies and field investigations by using questionnaire and air monitoring. The clinical therapeutic dose was used as lowest observed effect level （LOEL）, and no observed effect level （NOEL） was achieved by using a safety factor. The highest concentration of warfarin monitored in the worksite of centrifuge washing, drying and packing were 0.029 mg/m3, 0.052 mg/m3 respectively, which did not exceed the OEL 0.2 mg/m3 recommended by NIOSH and ACGIH. Considering its feasibility for enforcement and protection for workers, we recommend OEL 0.2 mg/m3 of warfarin in China.展开更多
文摘Two novel starburst compounds (star arylamines),4,4′,4″ tris(diphenylamino) triphenylamine (TDATA) and 4,4′,4″ tris[3 methyl (phenyl) amino] triphenylamine (MTDATA),were designed and synthesized as hole transport materials with high glass transition temperature ( t g),good film formation and film stability,excellent hole transporting ability.
文摘It is generally believed that exciplex is formed at the interface between a acceptor and a donor, it is not a new species, and it has a transit excited state. Based on the concept, we discussed the formation process of exciplex in organic electroluminescent (OEL) device with rareearth complex and considered that exciplex is also formed in the mixinglayer and it′s formation is the result from the interaction of singlet state of ligand and the holetransport material. Therefore, exciplex emission and the central ions emission of rareearth complex is an energy competition process. Therefore, it was resonable to understand that elimination of exciplex emission means enhance of the central ion emission of the rareearth complex through adjusting molar ratio of the two molecules.
基金supported by the Occupational Health Standards Program (20100304) from Ministry of Health of China
文摘This study aims to establish the occupational exposure limit （OEL） in the air for workplace of warfarin based on the available toxicological studies and field investigations by using questionnaire and air monitoring. The clinical therapeutic dose was used as lowest observed effect level （LOEL）, and no observed effect level （NOEL） was achieved by using a safety factor. The highest concentration of warfarin monitored in the worksite of centrifuge washing, drying and packing were 0.029 mg/m3, 0.052 mg/m3 respectively, which did not exceed the OEL 0.2 mg/m3 recommended by NIOSH and ACGIH. Considering its feasibility for enforcement and protection for workers, we recommend OEL 0.2 mg/m3 of warfarin in China.
