An ensemble-based assimilation method is proposed for correcting the subsurface temperature field when nudging the sea surface temperature(SST) observations into the Max Planck Institute(MPI) climate model,ECHAM5/MPI-...An ensemble-based assimilation method is proposed for correcting the subsurface temperature field when nudging the sea surface temperature(SST) observations into the Max Planck Institute(MPI) climate model,ECHAM5/MPI-OM. This method can project SST directly to subsurface according to model ensemble-based correlations between SST and subsurface temperature. Results from a 50 year(1960–2009) assimilation experiment show the method can improve the subsurface temperature field up to 300 m compared to the qualitycontrolled subsurface ocean temperature objective analyses(EN4), through reducing the biases of the thermal states, improving the thermocline structure, and reducing the root mean square(RMS) errors. Moreover, as most of the improvements concentrate over the upper 100 m, the ocean heat content in the upper 100 m(OHT100 m)is further adopted as a property to validate the performance of the ensemble-based correction method. The results show that RMS errors of the global OHT100 m convergent to one value after several times iteration,indicating this method can represent the relationship between SST and subsurface temperature fields well, and then improve the accuracy of the simulation in the subsurface temperature of the climate model.展开更多
A facile, rapid and sensitive spectrophotometric method was developed for the determination of carbaryl in its formulations, water and grain （rice and wheat） samples with newly synthesised reagent. The proposed meth...A facile, rapid and sensitive spectrophotometric method was developed for the determination of carbaryl in its formulations, water and grain （rice and wheat） samples with newly synthesised reagent. The proposed method was based on the alkaline hydrolysis of carbaryl pesticide and thus resulted 1-naphthol was coupled with diazotised 4,4＇-methylene-bis-m-nitroaniline in basic medium （pH 9） to give red colored product having λmax 480 nm for diazonium method （DM） or 1-naphthol reacts with 4,4＇-methylene-bis-m-nitroaniline in the presence of oxidising agent potassium dichromate （K2Cr2O7） to give red colored product having λmax 510 nm for oxidation method （OM）. The formation of colored derivatives with the coupling agent is instantaneous and stable for 48 h （DM） and 32 h （OM） respectively. Beer＇s law was obeyed in the concentration range of 0.2--10.0 μg·mL ^-1 for DM and 0.2--0.150 μg·mL^-1 for OM. The proposed methods are sensitive, easy to operate and permitted for the determination of carbaryl with detection limits of 0.028 μg·mL^-1 for DM and 0.024 μg·mL^-1 for OM respectively. The experimental results indicate that the procedure can eliminate the fundamental interferences caused by other pesticides and non-target ions, which made the methods more sensitive and selective. The method was applicable to the determination of carbaryl residue in water and food grain samples up to μg level.展开更多
基金The National Key R&D Program of China under contract No. 2017YFA0604201the National Natural Science Foundation of China under contract Nos 41876012 and 41861144015.
文摘An ensemble-based assimilation method is proposed for correcting the subsurface temperature field when nudging the sea surface temperature(SST) observations into the Max Planck Institute(MPI) climate model,ECHAM5/MPI-OM. This method can project SST directly to subsurface according to model ensemble-based correlations between SST and subsurface temperature. Results from a 50 year(1960–2009) assimilation experiment show the method can improve the subsurface temperature field up to 300 m compared to the qualitycontrolled subsurface ocean temperature objective analyses(EN4), through reducing the biases of the thermal states, improving the thermocline structure, and reducing the root mean square(RMS) errors. Moreover, as most of the improvements concentrate over the upper 100 m, the ocean heat content in the upper 100 m(OHT100 m)is further adopted as a property to validate the performance of the ensemble-based correction method. The results show that RMS errors of the global OHT100 m convergent to one value after several times iteration,indicating this method can represent the relationship between SST and subsurface temperature fields well, and then improve the accuracy of the simulation in the subsurface temperature of the climate model.
文摘A facile, rapid and sensitive spectrophotometric method was developed for the determination of carbaryl in its formulations, water and grain （rice and wheat） samples with newly synthesised reagent. The proposed method was based on the alkaline hydrolysis of carbaryl pesticide and thus resulted 1-naphthol was coupled with diazotised 4,4＇-methylene-bis-m-nitroaniline in basic medium （pH 9） to give red colored product having λmax 480 nm for diazonium method （DM） or 1-naphthol reacts with 4,4＇-methylene-bis-m-nitroaniline in the presence of oxidising agent potassium dichromate （K2Cr2O7） to give red colored product having λmax 510 nm for oxidation method （OM）. The formation of colored derivatives with the coupling agent is instantaneous and stable for 48 h （DM） and 32 h （OM） respectively. Beer＇s law was obeyed in the concentration range of 0.2--10.0 μg·mL ^-1 for DM and 0.2--0.150 μg·mL^-1 for OM. The proposed methods are sensitive, easy to operate and permitted for the determination of carbaryl with detection limits of 0.028 μg·mL^-1 for DM and 0.024 μg·mL^-1 for OM respectively. The experimental results indicate that the procedure can eliminate the fundamental interferences caused by other pesticides and non-target ions, which made the methods more sensitive and selective. The method was applicable to the determination of carbaryl residue in water and food grain samples up to μg level.
