Brain cancer is the premier reason for cancer deaths all over the world.The diagnosis of brain cancer at an initial stage is mediocre,as the radiologist is ineffectual.Different experiments have been conducted and dem...Brain cancer is the premier reason for cancer deaths all over the world.The diagnosis of brain cancer at an initial stage is mediocre,as the radiologist is ineffectual.Different experiments have been conducted and demonstrated clearly that the algorithms for nodule segmentation are unsuccessful.Therefore,the research has consolidated incremental clustering focused on superpixel segmentation as an appropriate optimization approach for the accurate segmentation of pulmonary nodules.The key aim of the research is to refine brain CT images to accurately distinguish tumors and the segmentation of small-scale anomalous nodules in the brain region.In the beginning stage,an anisotropic diffusion filters(ADF)method with un-sharp intensification masking is utilized to eliminate the noise discernment in images.In the following stage,within the improved nodule image sequence,a Superpixel Segmentation Based Iterative Clustering(SSBIC)algorithm is proposed for irregular brain tissue prediction.Subsequently,the brain nodule samples are captured using deep learning methods:Advanced Grey Wolf Optimization(AGWO)with ONN(AGWO-ONN)and Advanced GWO with CNN-based(AGWOCNN).The proposed technique indicates that the sensitivity is increased and the calculation time is decreased.Consequently,the proposed methodology manifests that the advanced Computer-Assisted Diagnosis(CAD)system has outstanding potential for automatic brain tumor diagnosis.The average segmentation time of the nodule slice order is 1.06s,and 97%of AGWO-ONN and 97.6%of AGWO-CNN achieve the best classification reliability.展开更多
Ports and jetties complex operations come with various forms of pollutions. The analysis of marine pollution from ports becomes very necessary and complicated due to the various types of pollution, sources, effects an...Ports and jetties complex operations come with various forms of pollutions. The analysis of marine pollution from ports becomes very necessary and complicated due to the various types of pollution, sources, effects and different characteristics. The sources of environmental pollution other than ships and from industrial activities in port and jetties were critically looked at and analyzed. A complete review of the environmental pollution in ports and the tools to assess and minimize such negative environmental impact are analyzed. The instrument of questionnaires was employed and distributed among two seaports and one jetty;Onne, Okrika and Port Harcourt to collect respondents’ opinions on effects, sources and causes of marine pollution. The chi-square test for independence was used with 180 respondents from Onne port, Port Harcourt port and Okrika jetty. Water sample was collected from Onne seaport and pollution contents such as total petroleum hydrocarbon (TPH), bio-chemical oxygen demand (BOD), turbidity, pH and salinity were tested in the laboratory. The result shows that Onne water had a salinity level of 20,790 (mg/l) which under the salinity range of water is considered saline, a turbidity level of 4.00 (NTU) which was considered average comparing with a 5.00 (NTU) bench mark, BOD5 level of 0.48 (mg/l) which was considered pristine because most pristine seawater will have BOD below 1 (mg/l), pH level of 7.77 which falls under the range of sea water being alkaline (7.2 - 8.4), TPH level of 2.98 (mg/l) since all conditions of sampling and sample preservations were observed and the value is less than the DPR limit (10 mg/l). It was concluded that the activities in Onne port are within the acceptable limits. It was also observed from the questionnaire that a larger population of respondents in Onne, Okrika and Port Harcourt ports where conscious of the sources and effects of environmental pollution from their respective ports.展开更多
This contribution describes the synthesis and structural characterization of a triaminoguanidinium (TAG)-based ligand [H6(OMe)3Limin]BF4 (1) containing imine bonds (Limin) and its reduction with a dimethylamino borane...This contribution describes the synthesis and structural characterization of a triaminoguanidinium (TAG)-based ligand [H6(OMe)3Limin]BF4 (1) containing imine bonds (Limin) and its reduction with a dimethylamino borane complex to the corresponding amine compound (Lamin)[H9(OMe)3Lamin]OTs (2). In solution, both ligands are C3-symmetric but crystal structures show the great influence of the reduction on the molecular structure. We show that the planar imine ligand is converted to a highly flexible compound which has nine potential coordination sites, three phenoxy and six amine donors, for binding metal ions. First solid state structures of 1:1 (metal:ligand) coordination compounds with SnIV and ZrIV are presented. SnIV exhibits an octahedral coordination sphere and is bound in a facial [ONN] coordination pocket. ZrIV is pentagonal bipyramidal coordinated and the ligand stabilizes this with its’ [ONNO] binding sites.展开更多
The oxovanadium（IV） complexes of the Schiff base hydrazones, synthesized from 3-hydrazinoquinoxaline-2- one （HQO） with salicylaldehyde （HSHQO）, o-hydroxyacetophenone （HHAHQO）, dehydroacetic acid （HDHAHQO） an...The oxovanadium（IV） complexes of the Schiff base hydrazones, synthesized from 3-hydrazinoquinoxaline-2- one （HQO） with salicylaldehyde （HSHQO）, o-hydroxyacetophenone （HHAHQO）, dehydroacetic acid （HDHAHQO） and o-nitrobenzaldehyde （NBHQO） were synthesized and characterized on the basis of analytical, conductance, magnetic moment, infrared, NMR, ESR and electronic spectral data. The ligands HSHQO, HDHAHQO behaved as monobasic tridentate ONN donors through phenolic oxygen, azomethine nitrogens. The ligand HAHQO acted as a monobasic bidentate ON donor through the phenolic oxygen, azomethine （free） nitrogen and the ligand NBHQO acted as neutral bidentate ON donor through oxygen of the nitro group and azomethine （free） nitrogen.展开更多
文摘Brain cancer is the premier reason for cancer deaths all over the world.The diagnosis of brain cancer at an initial stage is mediocre,as the radiologist is ineffectual.Different experiments have been conducted and demonstrated clearly that the algorithms for nodule segmentation are unsuccessful.Therefore,the research has consolidated incremental clustering focused on superpixel segmentation as an appropriate optimization approach for the accurate segmentation of pulmonary nodules.The key aim of the research is to refine brain CT images to accurately distinguish tumors and the segmentation of small-scale anomalous nodules in the brain region.In the beginning stage,an anisotropic diffusion filters(ADF)method with un-sharp intensification masking is utilized to eliminate the noise discernment in images.In the following stage,within the improved nodule image sequence,a Superpixel Segmentation Based Iterative Clustering(SSBIC)algorithm is proposed for irregular brain tissue prediction.Subsequently,the brain nodule samples are captured using deep learning methods:Advanced Grey Wolf Optimization(AGWO)with ONN(AGWO-ONN)and Advanced GWO with CNN-based(AGWOCNN).The proposed technique indicates that the sensitivity is increased and the calculation time is decreased.Consequently,the proposed methodology manifests that the advanced Computer-Assisted Diagnosis(CAD)system has outstanding potential for automatic brain tumor diagnosis.The average segmentation time of the nodule slice order is 1.06s,and 97%of AGWO-ONN and 97.6%of AGWO-CNN achieve the best classification reliability.
文摘Ports and jetties complex operations come with various forms of pollutions. The analysis of marine pollution from ports becomes very necessary and complicated due to the various types of pollution, sources, effects and different characteristics. The sources of environmental pollution other than ships and from industrial activities in port and jetties were critically looked at and analyzed. A complete review of the environmental pollution in ports and the tools to assess and minimize such negative environmental impact are analyzed. The instrument of questionnaires was employed and distributed among two seaports and one jetty;Onne, Okrika and Port Harcourt to collect respondents’ opinions on effects, sources and causes of marine pollution. The chi-square test for independence was used with 180 respondents from Onne port, Port Harcourt port and Okrika jetty. Water sample was collected from Onne seaport and pollution contents such as total petroleum hydrocarbon (TPH), bio-chemical oxygen demand (BOD), turbidity, pH and salinity were tested in the laboratory. The result shows that Onne water had a salinity level of 20,790 (mg/l) which under the salinity range of water is considered saline, a turbidity level of 4.00 (NTU) which was considered average comparing with a 5.00 (NTU) bench mark, BOD5 level of 0.48 (mg/l) which was considered pristine because most pristine seawater will have BOD below 1 (mg/l), pH level of 7.77 which falls under the range of sea water being alkaline (7.2 - 8.4), TPH level of 2.98 (mg/l) since all conditions of sampling and sample preservations were observed and the value is less than the DPR limit (10 mg/l). It was concluded that the activities in Onne port are within the acceptable limits. It was also observed from the questionnaire that a larger population of respondents in Onne, Okrika and Port Harcourt ports where conscious of the sources and effects of environmental pollution from their respective ports.
文摘This contribution describes the synthesis and structural characterization of a triaminoguanidinium (TAG)-based ligand [H6(OMe)3Limin]BF4 (1) containing imine bonds (Limin) and its reduction with a dimethylamino borane complex to the corresponding amine compound (Lamin)[H9(OMe)3Lamin]OTs (2). In solution, both ligands are C3-symmetric but crystal structures show the great influence of the reduction on the molecular structure. We show that the planar imine ligand is converted to a highly flexible compound which has nine potential coordination sites, three phenoxy and six amine donors, for binding metal ions. First solid state structures of 1:1 (metal:ligand) coordination compounds with SnIV and ZrIV are presented. SnIV exhibits an octahedral coordination sphere and is bound in a facial [ONN] coordination pocket. ZrIV is pentagonal bipyramidal coordinated and the ligand stabilizes this with its’ [ONNO] binding sites.
文摘The oxovanadium（IV） complexes of the Schiff base hydrazones, synthesized from 3-hydrazinoquinoxaline-2- one （HQO） with salicylaldehyde （HSHQO）, o-hydroxyacetophenone （HHAHQO）, dehydroacetic acid （HDHAHQO） and o-nitrobenzaldehyde （NBHQO） were synthesized and characterized on the basis of analytical, conductance, magnetic moment, infrared, NMR, ESR and electronic spectral data. The ligands HSHQO, HDHAHQO behaved as monobasic tridentate ONN donors through phenolic oxygen, azomethine nitrogens. The ligand HAHQO acted as a monobasic bidentate ON donor through the phenolic oxygen, azomethine （free） nitrogen and the ligand NBHQO acted as neutral bidentate ON donor through oxygen of the nitro group and azomethine （free） nitrogen.
