A series of nickel-doped copper tungstate/oxygen-rich TiO_(2) heterojunction-constructed composites of xNi-CuWO_(4)/OTiO_(2) were successfully prepared to demonstrate the enhancement of the visible-light photoactivity...A series of nickel-doped copper tungstate/oxygen-rich TiO_(2) heterojunction-constructed composites of xNi-CuWO_(4)/OTiO_(2) were successfully prepared to demonstrate the enhancement of the visible-light photoactivity through promoting the photogenerated charge carrier separation efficiency.Of all these composites,0.2Ni-CuWO_(4)/OTiO_(2) exhibits excellent and stable visible light photoactivity for the photooxidative coupling of benzylamine to the corresponding N-benzyl-1-phenymethanimine(BPMI)in air atmosphere.The conversion of benzylamine and the selectivity to BPMI reach 97%and 99%,respectively.The catalyst shows good cyclability with the conversion of benzylamine decreasing just by 22%after being repeated six times with the well-maintained selectivity of BPMI.The composite also exhibits excellent photo-bactericidal ability,which greatly inhibits the reproducing of both the Gram-positive bacteria(e.g.,S.epidermidis)and Gram-negative bacteria(e.g.,E.coli).展开更多
基金financially supported by NSFC(52063026,21563026)the Program for Changjiang Scholars and Innovative Research Team in University(IRT15R56)+2 种基金the Innovation Team Basic Scientific Research Project of Gansu Province(1606RJIA324)the Science,Technology Program of GansuProvince(19JR2RA020)Education Department of Gansu Province:Excellent Graduate Student"lnnovation Star"Project(2021CXZX001).
文摘A series of nickel-doped copper tungstate/oxygen-rich TiO_(2) heterojunction-constructed composites of xNi-CuWO_(4)/OTiO_(2) were successfully prepared to demonstrate the enhancement of the visible-light photoactivity through promoting the photogenerated charge carrier separation efficiency.Of all these composites,0.2Ni-CuWO_(4)/OTiO_(2) exhibits excellent and stable visible light photoactivity for the photooxidative coupling of benzylamine to the corresponding N-benzyl-1-phenymethanimine(BPMI)in air atmosphere.The conversion of benzylamine and the selectivity to BPMI reach 97%and 99%,respectively.The catalyst shows good cyclability with the conversion of benzylamine decreasing just by 22%after being repeated six times with the well-maintained selectivity of BPMI.The composite also exhibits excellent photo-bactericidal ability,which greatly inhibits the reproducing of both the Gram-positive bacteria(e.g.,S.epidermidis)and Gram-negative bacteria(e.g.,E.coli).
