The first stereoselective total synthesis of (-)-3β, 4α-dihydrocy-β-dihydroagarofuran (1) and 3α, 4α-oxidoagarofuran (2) has been described. The key step is the expoxidation of α-agarofuran (6)with dimethyldioxi...The first stereoselective total synthesis of (-)-3β, 4α-dihydrocy-β-dihydroagarofuran (1) and 3α, 4α-oxidoagarofuran (2) has been described. The key step is the expoxidation of α-agarofuran (6)with dimethyldioxirane.展开更多
文摘The first stereoselective total synthesis of (-)-3β, 4α-dihydrocy-β-dihydroagarofuran (1) and 3α, 4α-oxidoagarofuran (2) has been described. The key step is the expoxidation of α-agarofuran (6)with dimethyldioxirane.
